scholarly journals Crystals Springing Into Action: Metal-Organic Framework CUK-1 as a Pressure-Driven Molecular Spring

2021 ◽  
Author(s):  
Paul Iacomi ◽  
Ji Sun Lee ◽  
Louis Vanduyfhuys ◽  
Kyung-Ho Cho ◽  
Pierre Fertey ◽  
...  
Keyword(s):  
High Pressure ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Mercury Porosimetry ◽  
Crystalline Material ◽  
X Ray Diffraction ◽  
Mechanical Pressure ◽  
X Ray ◽  
Metal Organic

Mercury porosimetry and in situ high pressure single crystal X-ray diffraction revealed the wine-rack CUK-1 MOF as a unique crystalline material capable of a fully reversible mechanical pressure-triggered structural contraction....

scholarly journals High pressure effects on hydrate Cu-BTC investigated by vibrational spectroscopy and synchrotron X-ray diffraction

RSC Advances ◽  
2017 ◽  
Vol 7 (87) ◽  
pp. 55504-55512 ◽  
Author(s):  
Zhaohui Dong ◽  
Zhongying Mi ◽  
Weiguang Shi ◽  
Hui Jiang ◽  
Yi Zheng ◽  
...  
Keyword(s):  
High Pressure ◽  
Vibrational Spectroscopy ◽  
Powder Diffraction ◽  
Metal Organic Framework ◽  
Pressure Effects ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
High Pressure Effects

The high pressure behaviors of hydrate Cu-BTC metal–organic framework (MOF) in terms of phase stability, compressibility and reversibility were investigated in situ by synchrotron X-ray powder diffraction as well as vibrational spectroscopy.

scholarly journals Guest-Mediated Phase Transitions in a Flexible Pillared-Layered Metal-Organic Framework under High-Pressure

2021 ◽  
Author(s):  
Gemma Turner ◽  
Scott C. McKellar ◽  
David Robert Allan ◽  
Anthony K. Cheetham ◽  
Sebastian Henke ◽  
...  
Keyword(s):  
High Pressure ◽  
Phase Transitions ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Structural Phase ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

The guest-dependent flexibility of the pillared-layered metal-organic framework (MOF), Zn2bdc2dabco·X(guest), where guest = EtOH, DMF or benzene, has been examined by high-pressure single crystal X-ray diffraction. A pressure-induced structural phase...

scholarly journals Structural characterization of framework–gas interactions in the metal–organic framework Co2(dobdc) by in situ single-crystal X-ray diffraction

2017 ◽  
Vol 8 (6) ◽  
pp. 4387-4398 ◽  
Author(s):  
Miguel I. Gonzalez ◽  
Jarad A. Mason ◽  
Eric D. Bloch ◽  
Simon J. Teat ◽  
Kevin J. Gagnon ◽  
...  
Keyword(s):  
Single Crystal ◽  
Structural Characterization ◽  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Gas Interactions ◽  
Organic Framework

In situ single-crystal X-ray diffraction experiments enable the direct observation of weak metal–gas interactions in a metal–organic framework.

Single Crystal X-ray Diffraction Studies of Carbon Dioxide and Fuel-Related Gases Adsorbed on the Small Pore Scandium Terephthalate Metal Organic Framework, Sc2(O2CC6H4CO2)3

Langmuir ◽  
2009 ◽  
Vol 25 (6) ◽  
pp. 3618-3626 ◽  
Author(s):  
Stuart R. Miller ◽  
Paul A. Wright ◽  
Thomas Devic ◽  
Christian Serre ◽  
Gérard Férey ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Small Pore ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Exceptional adsorption-induced cluster and network deformation in the flexible metal–organic framework DUT-8(Ni) observed by in situ X-ray diffraction and EXAFS

2015 ◽  
Vol 17 (26) ◽  
pp. 17471-17479 ◽  
Author(s):  
Volodymyr Bon ◽  
Nicole Klein ◽  
Irena Senkovska ◽  
Andreas Heerwig ◽  
Jürgen Getzschmann ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Gate Opening ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

The “gate opening” mechanism in flexible MOF Ni2(2,6-ndc)2dabco was elucidated in detail.

A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand

2013 ◽  
Vol 275-277 ◽  
pp. 2367-2370
Author(s):  
Qing Yu Ma ◽  
Rui Fang Guan ◽  
Guo Zhong Li ◽  
Deng Xu Wang
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
Diffusion Method ◽  
X Ray Diffraction ◽  
X Ray ◽  
Slow Diffusion ◽  
Sheet Structure ◽  
Metal Organic ◽  
1D Chains ◽  
Organic Framework

A novel metal-organic framework, MnCl2(BIPS)2•2CH3OH•2H2O (1) were synthesized from MnCl2 and a tetrahedral silicon-cored ligand, Me2Si(p-C6H4-imdazol-1-yl)2 (BIPS) under the slow diffusion method. The structure was determined by single-crystal X-ray diffraction. Complex 1 is a 2D sheet structure constructed from 1D chains with 34-atom metallamacrocycles.

Compressibility trends of the clinopyroxenes, and in-situ high-pressure single-crystal X-ray diffraction study of jadeite

2008 ◽  
Vol 93 (1) ◽  
pp. 198-209 ◽  
Author(s):  
A. C. McCarthy ◽  
R. T. Downs ◽  
R. M. Thompson
Keyword(s):  
High Pressure ◽  
Single Crystal ◽  
Diffraction Study ◽  
X Ray Diffraction ◽  
X Ray
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