scholarly journals Geochemical conditions of hydrocarbon accumulation in low-permeability shale sequences

2019 ◽  
Vol 98 ◽  
pp. 02005
Author(s):  
Vagif Kerimov ◽  
Rustam Mustaev ◽  
Uliana Serikova ◽  
Javidan Ismailov

The report is devoted to the study of conditions for the formation of organic porosity–void spaces of organic origin formed during transformation of the organic matter into hydrocarbons, and their role in the formation of hydrocarbon accumulation in low-permeability shale strata. The experience of studying and developing known shale formations of the world testifies to the fact that such strata are hybrid phenomena, that is, they are both oiland gas-bearing strata containing traditional and non-traditional accumulations of hydrocarbons. Based on the results of the programmed pyrolysis by the Rock-Eval-6 method, an estimate has been performed to quantify organic (kerogen) porosity. This estimate allows for determining the forecast retention volume of HCs generated during catagenesis.

2011 ◽  
Vol 31 (5) ◽  
pp. 135-146
Author(s):  
Yuhai FAN ◽  
Hongjun QU ◽  
Gongcheng ZHANG ◽  
Yangwei FENG ◽  
Liqun GUAN ◽  
...  
Keyword(s):  
Oil Gas ◽  

1981 ◽  
Vol 21 (1) ◽  
pp. 137
Author(s):  
B. Wilkinson ◽  
L. Barro

Vast reserves of gas-bearing coal deposits are located in Queensland. Owing to the extremely low permeability and porosity of the coal, very low gas flow rates are normally encountered. In an effort to enhance the gas production to economic quantities and to degasify the coal to provide a safer mining environment, four experimental wells were drilled into coal seams near Blackwater, Queensland.Based on extensive laboratory testing of coal samples, computerised fracture design calculations were performed to determine a suitable stimulation programme. The wells were hydraulically fractured with up to 15 000 US gal of foamed stimulation fluid containing 75 per cent nitrogen. To prop open the induced fracture system, 15 000 lb of sand was pumped with the foam. The maximum concentration was eight pounds of 20-40 mesh sand per gallon of fluid. Gas production from the unstimulated wells was too low to measure. Early production data soon after the fracturing suggested a gas flow rate of approximately 50 Mcf/D.


Author(s):  
Bruno Herlin ◽  
Kent von Maubeuge

Geosynthetic Clay Liner’s (GCLs) are an established sealing product in the geoenvironmental industry. They are used in landfill applications as caps and base liners, secondary containment for fuel storage facilities, as well as within various other containment structures such as dams, canals, rivers, and lakes. Rolled out like a carpet to provide a durable impermeable liner, Geosynthetic Clay Liners consist of a layer of high swelling sodium bentonite sandwiched between two geotextiles. Manufactured around the world in different techniques, the Canadian manufactured GCL, is mechanically bonded by needlepunching from one nonwoven geotextile through the bentonite to the other nonwoven or woven geotextile. The low hydraulic conductivity of the GCLs are used mainly as a replacement to thick, difficult to build compacted clay liners to provide a barrier to liquids and gases, offering both a technical and economical advantage. GCLs, with an average thickness of 7mm, offer a volume advantage over Compacted Clay Liners. They are more capable of withstanding freeze-thaw and wet-dry cycles; offer substantial construction cost savings in reduced on-site QC/QA and a quicker installation. Furthermore, GCLs offer equivalent or lower rates of release of fluids and chemicals than Compacted Clay Liners (CCLs). Bentonite is a clay mineral with expansive characteristics and low permeability, where montmorillonite is the chief mineral. Montmorillonite, swells when contacted with water approximately 900% by volume or 700% by weight. When hydrated under confinement, the bentonite swells to form a low permeability clay liner, the equivalent hydraulic protection of several feet of compacted clay. A relatively new engineering material for some, geosynthetic clay liners have been used extensively over the past two decades, and are finding increasing use in every sector of the environmental industry. This paper will review the technical properties of these materials, their documentation at the research level, their integrity as a sealing barrier and recent field applications in the pipeline industry. Further, because these materials are factory produced, their properties are predictable, assisting the engineer to design with a high confidence level. Technical properties and economical benefits are sure to further increase GCL installations around the world to protect our environment and more importantly our groundwater.


Geofluids ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-14
Author(s):  
Krzysztof Sowiżdżał ◽  
Tomasz Słoczyński ◽  
Weronika Kaczmarczyk

The paper discusses the issue of oil-in-place estimation for liquid-saturated shales in Lower Paleozoic (Silurian and Ordovician) organic-rich formations of the Baltic Basin in North Poland. The authors adopted a geochemical method based on Rock Eval results which directly measure hydrocarbon content present in rock samples. Its application on a real data set required the implementation of correction procedures to consider also those oil compounds which were lost before Rock Eval measurements were taken or are not recorded in S1 parameter. It was accomplished through the introduction of two correction coefficients: c1—for evaporation loss and c2—for heavier compounds underestimation. The first one was approximated on the basis of published results and known properties of crude oil, while the second one was addressed with laboratory experimental procedure which combines Rock Eval pyrolysis and rock sample extraction with organic solvents. The calculation formulas were implemented in the 3D geological model of shale formations reproducing their geometry as well as the spatial variability of the petrophysical and geochemical properties. Consequently, the results of oil-in-place estimation were also available as 3D models, ready for visualization and interpretation in terms of delineation of most favorable zones or well placement. The adopted geochemical method and the results of oil-in-place estimation it produced were confronted with standard volumetric method. Although both of them are volumetric methods, the results depend on different sets of rock properties, which is an advantage for result comparison reasons. The study revealed that the geochemical method of oil-in-place estimation in liquid-rich shales after appropriate adjustment, considering shale formation and reservoir fluid dependent conditions, could provide reliable results and be implemented on the early stage of shale exploration process in a condition of production data inaccessibility.


1973 ◽  
Vol 25 (10) ◽  
pp. 1125-1129
Author(s):  
Charles R. Boardman ◽  
Gregory W. Hammack ◽  
Walter H. Fertl ◽  
Charles H. Atkinson
Keyword(s):  

2019 ◽  
pp. 13-18
Author(s):  
V. Yu. Kerimov ◽  
◽  
V. A. Kosyanov ◽  
R. N. Mustaev ◽  
D. D. Ismailov ◽  
...  

Energies ◽  
2018 ◽  
Vol 11 (6) ◽  
pp. 1406 ◽  
Author(s):  
Seyedalireza Khatibi ◽  
Mehdi Ostadhassan ◽  
David Tuschel ◽  
Thomas Gentzis ◽  
Humberto Carvajal-Ortiz

Vitrinite maturity and programmed pyrolysis are conventional methods to evaluate organic matter (OM) regarding its thermal maturity. Moreover, vitrinite reflectance analysis can be difficult if prepared samples have no primary vitrinite or dispersed widely. Raman spectroscopy is a nondestructive method that has been used in the last decade for maturity evaluation of organic matter by detecting structural transformations, however, it might suffer from fluorescence background in low mature samples. In this study, four samples of different maturities from both shale formations of Bakken (the upper and lower members) Formation were collected and analyzed with Rock-Eval (RE) and Raman spectroscopy. In the next step, portions of the same samples were then used for the isolation of kerogen and analyzed by Raman spectroscopy. Results showed that Raman spectroscopy, by detecting structural information of OM, could reflect thermal maturity parameters that were derived from programmed pyrolysis. Moreover, isolating kerogen will reduce the background noise (fluorescence) in the samples dramatically and yield a better spectrum. The study showed that thermal properties of OM could be precisely reflected in Raman signals.


Sign in / Sign up

Export Citation Format

Share Document