scholarly journals Effect of bentonite modified by silane on rubber blends properties

2018 ◽  
Vol 157 ◽  
pp. 07006 ◽  
Author(s):  
Zuzana Mičicová ◽  
Slavomíra Božeková ◽  
Mariana Pajtášová ◽  
Darina Ondrušová
Keyword(s):  
Partial Replacement ◽  
Rubber Matrix ◽  
Solution Ph ◽  
Optimum Time ◽  
Maximum Torque ◽  
Rubber Blends ◽  
Propyl Methacrylate ◽  
Curing Characteristics ◽  
Minimum Torque

The presented paper deals with the preparation of bentonite modified by silane and its application into polymer matrix. Natural bentonite was modified with 3-(Trimethoxysilyl) propyl-methacrylate in two different solutions. These two solutions had the same composition (ethanol, water and 3-(Trimethoxysilyl) propyl-methacrylate) but in one solution, pH was modified. These bentonites modified by silane were characterized by Fourier transform infrared spectroscopy. The modified bentonites were mixed into rubber matrix as partial replacement of commonly used filler – carbon black of the N339 type. The polymer blends were investigated from the aspect of the rheological and curing characteristics (minimum torque ML, maximum torque MH, optimum time of cure t(c90), processing safety of blend ts,). Moreover, the quality of the silanization reactions was investigated. Measurements were done using PRPA 2000.

scholarly journals Curing characteristics and rheological properties of bentonite- filled rubber blends

2021 ◽  
Vol 1199 (1) ◽  
pp. 012037
Author(s):  
Z Mičicová ◽  
S Božeková ◽  
M Pajtášová ◽  
D Ondrušová
Keyword(s):  
Fine Fraction ◽  
Rheological Behaviour ◽  
Complex Viscosity ◽  
Partial Replacement ◽  
Optimum Time ◽  
Maximum Torque ◽  
Rubber Blends ◽  
Filled Rubber ◽  
Curing Characteristics ◽  
Strain Sweep

Abstract The study deals with the examination of the rheological behaviour of rubber blends which were filled with bentonite. The filler - polymer as well as the filler - filler interactions were studied and determined from the frequency sweep and strain sweep rheological measurements. The used natural bentonite was extracted from the locality called Jelsovy Potok. The natural bentonite had a fine fraction with a particle size of 15μm a 45 μm and it was added into rubber blends as a partial replacement of commonly used filler. The rubber blends were characterised on the basis of curing characteristics (minimum torque ML, maximum torque MH, optimum time of cure t(c90), processing safety of blend ts,). Moreover, the complex viscosity and Payne effect were also specified. The required measurements were done by using PRPA 2000.

scholarly journals Study of clay minerals effect on curing characteristics of polymer blends and physical-mechanical properties of prepared vulcanizates

2018 ◽  
Vol 157 ◽  
pp. 07010
Author(s):  
Beáta Pecušová ◽  
Mariana Pajtášová ◽  
Zuzana Mičicová ◽  
Darina Ondrušová ◽  
Andrea Feriancová ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Polymer Blends ◽  
Clay Minerals ◽  
Structural Type ◽  
Partial Replacement ◽  
Curing Characteristics ◽  
Dioctahedral Smectite ◽  
The Common ◽  
The Given

The given paper deals with the study of the properties of clay minerals, namely montmorillonite and moreover, it is focused on effect of these clay minerals on the curing characteristics of the polymer blends and the physical-mechanical properties of prepared vulcanizates. Montmorillonite is a major clay mineral which has a wide application in many industrial branches. It belongs to the group of dioctahedral smectite minerals with structural type in the ratio of 2:1. Characteristics of prepared modified and organomodified clay minerals are based on sulphur vulcanisation accelerators which are used for the preparation of real polymer blend where they represent a partial replacement of the common carbon black filler and then, the effect on the curing characteristics of polymer blends as well as physical-mechanical properties of the prepared vulcanizates are investigated. The results exhibit that the clay-based filler (modified and organomodified clay minerals) can be used as a partial replacement while the quality of the prepared blends is preserved.

Natural Rubber/Styrene Butadiene Rubber/Recycled Nitrile Glove (NR/SBR/rNBRg) Ternary Blend: Curing Characteristics and Swelling Test

2013 ◽  
Vol 594-595 ◽  
pp. 634-638 ◽  
Author(s):  
N.Z. Nik Yahya ◽  
N.Z. Noimam ◽  
Hanafi Ismail ◽  
Mohd Arif Anuar Mohd Salleh ◽  
Santiagoo Ragunathan
Keyword(s):  
Natural Rubber ◽  
Swelling Behavior ◽  
Styrene Butadiene Rubber ◽  
Ternary Blend ◽  
Butadiene Rubber ◽  
Maximum Torque ◽  
Curing Characteristics ◽  
Cure Time ◽  
Styrene Butadiene ◽  
Minimum Torque

Curing characteristics and swelling behavior of natural rubber/styrene butadiene rubber/recycled nitrile glove (NR/SBR/rNBRg) blends were investigated. Eleven composition ratio; 50/50/0, 50/40/10, 50/30/20, 50/20/30, 50/10/40, 50/0/50, 40/50/10, 30/50/20, 20/50/30, 10/50/40, and 0/50/50 of SMRL/SBR/rNBRg with the size of rNBRg ; 2.5 3.0 cm2 were prepared by using two roll mill at room temperature. Cure characteristics such as scorch time,t2, cure time,t90, minimum torque, ML, maximum torque, MH, and swelling behavior of SMRL/SBR/rNBRg ternary blends were examined. Results indicated that the scorch time and maximum torque of the NR/SBR/rNBRg blends decreased with increasing rNBRg content. The minimum torque of the blends increased as rNBRg content increased. The cure time of NR/SBR/rNBRg blends show a unique trend, which are depending on the domain rubber content. The increment in rNBRg content decreased the crosslink density of NR/SBR/rNBRg blends.

The Effect of Chitosan Loading on the Properties of Chitosan Filled Epoxidized Natural Rubber Compounds

2011 ◽  
Vol 471-472 ◽  
pp. 851-856 ◽  
Author(s):  
S.M. Shaari ◽  
Hanafi Ismail ◽  
Nadras Othman
Keyword(s):  
Natural Rubber ◽  
Tensile Modulus ◽  
Epoxidized Natural Rubber ◽  
Rubber Matrix ◽  
Curing Time ◽  
Maximum Torque ◽  
Elongation At Break ◽  
Rubber Compounds ◽  
Curing Characteristics ◽  
Roll Mill

The study of chitosan loading onto epoxidized natural rubber compounds were prepared by incorporation of chitosan into epoxidised natural rubber matrix using a two-roll mill. The effects of chitosan loading on the curing characteristics, tensile properties and morphology of the compounds were investigated. Results indicated that slight changes in curing time (t90), and scorch time (tS2) of the compounds with the incorporation of chitosan. An increment is observed in the maximum torque, tensile modulus and durometer hardness of the compounds while tensile strength and elongation at break declines with chitosan loading.

Curing Characteristics and Dynamic Mechanical Behaviour of Reinforced Acrylonitrile-Butadiene/Chlorosulfonated Polyethylene Rubber Blends

2005 ◽  
Vol 494 ◽  
pp. 475-480 ◽  
Author(s):  
G. Marković ◽  
M. Marinović-Cincović ◽  
H. Valentova ◽  
M. Ilavsky ◽  
B. Radovanović ◽  
...  
Keyword(s):  
Adhesion Strength ◽  
Primary Particle ◽  
Rubber Matrix ◽  
Butadiene Rubber ◽  
Rubber Composites ◽  
Rubber Blends ◽  
Chlorosulfonated Polyethylene ◽  
Dynamic Mechanical ◽  
Curing Characteristics ◽  
Average Size

This paper deals with the control of the adhesion strength in metal-elastomer joints by fillers and the use of rubber blends to produce advanced high performance adhesive systems. The curing behavior of rubber compounds and dynamic mechanical properties of crosslinked rubber composites were considered in this technologically applicable study. The effects of two types of reinforcing filler, used to increase the adhesion strength between steel and rubber matrix based on acrylonitrile-butadiene rubber (NBR) and chlorosulfonated polyethylene rubber (CSM) was investigated. Precipitated silica (with the average size of primary particle 15 nm) and diatomaceous earth (with the average size of primary particle 28 µm) were used for both rubber and its blend (NBR/CSM). The filler loading range was from 0 to 35 phr. The determination of curing characteristics was estimated by Monsanto Rheometer. The crosslink density of the rubber composites was determined by swelling measurement. Dynamic mechanical behavior was measured by mechanical spectroscopy (in a single cantilever bending mode).

Properties of Natural Rubber/Styrene Butadiene Rubber/Recycled Nitrile Glove (NR/SBR/rNBRg) Blends: The Effects of Recycled Nitrile Glove (rNBRg) Particle Sizes

2016 ◽  
Vol 673 ◽  
pp. 151-160 ◽  
Author(s):  
N.Z. Nik Yahya ◽  
Nik Noriman Zulkepli ◽  
Hanafi Ismail ◽  
Sam Sung Ting ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
...  
Keyword(s):  
Particle Size ◽  
Crosslink Density ◽  
Styrene Butadiene Rubber ◽  
Particle Sizes ◽  
Butadiene Rubber ◽  
Maximum Torque ◽  
Curing Characteristics ◽  
Cure Time ◽  
Styrene Butadiene ◽  
Minimum Torque

The effects of different particle sizes of recycled nitrile glove (rNBRg) on curing characteristics and physical properties of natural rubber/styrene butadiene rubber/recycled nitrile glove (NR/SBR/rNBRg) blends were investigated. The particle sizes of rNBRg were differentiated by the method of sizing. S1 was obtained by cutting the rNBRg into smaller sheets; S2 was obtained by passing rNBRg through 2 rolls mill for 10 times; and S3 was obtained by passing rNBRg through 2 rolls mill for 10 times and then mechanically grinded. NR/SBR/rNBRg blends were prepared at 50/30/20 composition using two roll mill at room temperature, with different particle sizes, rNBRg (S1), rNBRg (S2) and rNBRg (S3). Curing characteristics (scorch time, cure time, minimum torque and maximum torque), tensile properties and physical properties (crosslink density, resilience and hardness) of the blends were investigated. Results indicated that scorch time, cure time and minimum torque decreased as the rNBRg particle size decreased, while maximum torque and crosslink density increased. Tensile strength of the blends decreased as the rNBRg particle size reduced, which explained the formation of holes on the surfaces of tensile fracture, observed by scanning electron microscope. The rigidity of NR/SBR/rNBRg blends increased when smaller rNBRg particles were used, which explained the increased in hardness and decreased in resilience of the blends.

Properties of Ethylene Propylene Diene Monomer/Recycled Acrylonitrile – Butadiene Rubber Blends (EPDM/rNBR): Effect of the Addition of Bamboo Fillers

2015 ◽  
Vol 815 ◽  
pp. 19-23
Author(s):  
Z. Norhafizah ◽  
N.Z. Noriman ◽  
H. Kamarudin ◽  
S.T. Sam ◽  
Hanafi Ismail ◽  
...  
Keyword(s):  
Physical Properties ◽  
Crosslink Density ◽  
Butadiene Rubber ◽  
Ethylene Propylene Diene Monomer ◽  
Maximum Torque ◽  
Blend Ratio ◽  
Ethylene Propylene ◽  
Rubber Blends ◽  
Cure Time ◽  
Minimum Torque

Cure characteristics and physical properties of EPDM/rNBR filled bamboo fillers were studied. Results indicated that the addition of bamboo fillers has significant effects on EPDM/rNBR blends. The scorch time, t2decreased up to 25 phr fillers loading but increased further to 50 phr fillers loading. Cure time, t90increases as the increase in bamboo fillers in the blends. At a similar blend ratio fine sizes bamboo fillers in EPDM/rNBR (S1: ≤125μm) exhibited higher value of t2ad t90compared to EPDM/rNBR (S2: 125-250μm & S3: 250-500μm). The minimum torque, MLalso increases with increasing bamboo fillers in the blend. Meanwhile, the maximum torque, MHof the EPDM/rNBR filled bamboo fillers were in contrast. The hardness and degree of crosslink density of the blends increased with the increase in bamboo fillers and reduce percentage of resilience at all blends. The fine sizes of bamboo fillers contributed to the better properties compared to the coarse sizes and medium sizes.

Cure Characteristics and Ageing Resistance of Recovered Waste Pre-Vulcanized Nitrile/Epoxidized Natural Rubber Latex Blends in Nitrile Butadiene Rubber Compounds

2015 ◽  
Vol 1119 ◽  
pp. 347-351
Author(s):  
A.I.H. Dayang Habibah ◽  
V. Devaraj ◽  
H. Kamarularifin ◽  
Ibrahim Suhawati
Keyword(s):  
Natural Rubber ◽  
Physical Properties ◽  
Natural Rubber Latex ◽  
Butadiene Rubber ◽  
Rubber Latex ◽  
Maximum Torque ◽  
Rubber Compounds ◽  
Curing Characteristics ◽  
Control Compound ◽  
Minimum Torque

Waste pre-vulcanized nitrile latex (WPNL), obtained from nitrile glove dipping tank was blended at different ratios with concentrated ENR latex processed via ultrafiltration and designated as ENRLC-SP20 and ENRLC-SP50, respectively, with the number indicating, the percentage of WPNL incorporated into the blend. The blends were prepared in the latex stage and subsequently processed into dry rubber. The rubbers were then blended with virgin nitrile rubber (NBR) at various ratios and the curing characteristics and physical properties of the blends were evaluated. The results showed the maximum torque (MH) decreases while the minimum torque (ML) increases with increasing level of SP 50 rubber. Using higher concentrations of SP-50, the results showed slight reductions in the cure (t90) and scorch time (ts2), respectively. It was also found that by increasing ratio of ENRLC-SP20 and ENRLC-SP50 improves the heat ageing resistance of NBR blends at 100°C as evidenced by the higher percentages in retention of the blends, compared to the control compound.

Effect of Recycled Nitrile Glove (rNBRg) Particle Sizes on Curing Characteristics and Physical Properties of Natural Rubber/Styrene Butadiene Rubber/Recycled Nitrile Glove (NR/SBR/rNBRg) Blends

2015 ◽  
Vol 815 ◽  
pp. 54-58 ◽  
Author(s):  
N.Z. Nik Yahya ◽  
Nik Noriman Zulkepli ◽  
Hussin Kamarudin ◽  
Hanafi Ismail ◽  
Sam Sung Ting ◽  
...  
Keyword(s):  
Natural Rubber ◽  
Crosslink Density ◽  
Styrene Butadiene Rubber ◽  
Particle Sizes ◽  
Butadiene Rubber ◽  
Maximum Torque ◽  
Curing Characteristics ◽  
Cure Time ◽  
Styrene Butadiene ◽  
Minimum Torque

Effects of different particle sizes of recycled nitrile glove (rNBRg) on curing characteristics and physical properties of natural rubber/styrene butadiene rubber/recycled nitrile glove (NR/SBR/rNBRg) blends were studied. The particle sizes of rNBRg were differentiated by the method of producing. S1 was obtained by cutting the rNBRg (whole glove) into smaller sheet; S2 was obtained by passing rNBRg through 2 rolls mill for 10 times; S3 was obtained by passing rNBRg through 2 rolls mill for 10 times and then mechanically grinded. NR/SBR/rNBRg blends were prepared at 50/30/20 composition using two roll mill at room temperature, with different particle sizes, rNBRg (S1), rNBRg (S2) and rNBRg (S3). Scorch time, cure time, minimum torque, maximum torque, crosslink density and hardness of the blends were examined. Results indicated that scorch time, cure time and minimum torque decreased as the rNBRg particle size decreased, while maximum torque and crosslink density increased. The rigidity of NR/SBR/rNBRg blends increased when smaller rNBRg particles were used, which explained the increased in hardness and decreased in resilience of the blends.

COMPARATIVE PERFORMANCE EVALUATION OF PMB and CRMB WITH PARTIAL REPLACEMENT OF BITUMEN (VG-30) USING MARSHALL MIX DESIGN METHOD-A REVIEW

2018 ◽  
Vol 5 (02) ◽  
Author(s):  
N. SATHEESHKANNA
Keyword(s):  
Performance Evaluation ◽  
Design Method ◽  
Mix Design ◽  
Partial Replacement ◽  
Comparative Performance

Waste generated from industries and from various places around us not only contains rubber or plastics but contains lot many harmful pollutants whichare hazardous if disposed continuously in open and leftto degrade in our environment.Our project aims to study properties of different materials which may help in utilising the waste as well as improve the quality of roads and make them efficient, stable, durable and long lasting. Some of the materials that we have studied and considered to be tested in the partial replacement of bitumen are PMB and CRMB.

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