Intensity‐dependent photoluminescence spectra of semiconductor‐doped glasses

1988 ◽  
Vol 53 (8) ◽  
pp. 643-645 ◽  
Author(s):  
J. P. Zheng ◽  
L. Shi ◽  
F. S. Choa ◽  
P. L. Liu ◽  
H. S. Kwok
2019 ◽  
Vol 27 (1) ◽  
pp. 51-56
Author(s):  
O. V. Ohiienko ◽  
V. N. Moiseienko ◽  
M. D. Volnyanskij

The work is devoted to the study of photoluminescence spectra of weakly polar ferroelectric crystals Li2Ge7O15 and Li2O – 7GeO2 glasses. For all initial samples was observed the wide intensive luminescence band with maximum in the region of 525–550 nm. The spectral distribution of intensity and the position of the maximum of the band for a Li2Ge7O15 crystal depended on the excitation wavelength (λex=405 nm or 365nm were used). The spectral profile of the luminescence band was broadened in glass containing of 0.67% copper. The intensity of the luminescence band was decreased 6 times for glass doped with Cr3+ ions (0.01%) as compared with glass containing Cu2+ ions. The intense luminescence band of Cr3+ ions with λmax=659nm was appeared starting from 600. The assumption about the nature of the broad luminescence band observed in both nominally pure and doped glasses and crystals was made: the source of luminescence can be germanium - oxygen complexes [GeO4] and [GeO6] of the tetrahedral and octahedral configuration in the material structure.


2018 ◽  
Vol 19 (4) ◽  
pp. 331-335
Author(s):  
V.V. Halyan ◽  
I.A. Ivashchenko ◽  
A.H. Kevshyn ◽  
I.D. Olekseyuk ◽  
P.V. Tishchenko

Glasses of the composition (70–X) mol.% Ga2S3 - 30 mol.% La2S3 - X Er2S3 (at X = 0, 1, 3) were synthesized  and the optical absorption spectra at room temperature were studied. Photoluminescence spectra in the 2.53 - 0.73eV range at 300 and 80K were investigated. Intense PL maxima at 2.25, 1.88, 1.45, 1.26, 1.13, 0.81 eV were found which correspond to transitions in the f-shell of erbium ions. The redistribution of the intensity of PL peaks with temperature was analyzed based on the energy transition diagram of erbium ions.


2019 ◽  
Vol 2019 ◽  
pp. 1-11 ◽  
Author(s):  
M. A. Marzouk ◽  
H. A. ElBatal ◽  
Y. M. Hamdy ◽  
F. M. Ezz-Eldin

Glasses with the Na2O–ZnO–P2O5 composition and doped with single CeO2, Sm2O3, or mixed dopants were melted and studied. Collective optical, photoluminescence, and FT-infrared spectral studies were carried out. CeO2-doped glasses show two extra UV absorption bands due to Ce4+ and Ce3+ ions while Sm2O3-doped samples reveal pronounced peaks collected into two segments from 367 to 472 nm and from 950 to 1623 nm which are characteristic of absorption from Sm3+ ions. The mixed dopants glasses show combined UV-visible–near-IR absorption peaks due to cerium (Ce4+, Ce3+) ions and samarium (Sm3+) ions. The photoluminescence spectra (PL) of the single CeO2-doped and Sm2O3-doped glasses and even the mixed dopant sample reveal luminescence spectra after excitation which are characteristic of the rare-earth ions. The intensities for both excited or emitted peaks are found to increase with the increase of the rare-earth percent. FTIR spectra of the glasses show pronounced vibrational peaks related to phosphate groups (Q2 and Q3 units) in accordance with the P2O5 percent (70 mol %).


1994 ◽  
Vol 04 (C4) ◽  
pp. C4-277-C4-280 ◽  
Author(s):  
B. HYDE ◽  
D. BARBIER ◽  
J. HUBNER ◽  
J.-M. JOUANNO ◽  
A. KEVORKIAN ◽  
...  

2017 ◽  
Vol 68 (6) ◽  
pp. 1188-1192
Author(s):  
Daniela Avram ◽  
Nicolae Angelescu ◽  
Dan Nicolae Ungureanu ◽  
Ionica Ionita ◽  
Iulian Bancuta ◽  
...  

The study in vitro of the glass powders bioactivity was performed by soaking them in simulated body fluid for 3 to 21 days at a temperature of 37�C and pH = 7.20. The synthesis de novo of hydroxyapatite, post soaking was confirmed by Fourier Transform Infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The study of the antimicrobial activity was performed by microbiological examination on two strains of pathogenic bacteria involved in postoperative nosocomial infections.


Nanomaterials ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 1023 ◽  
Author(s):  
Ashish Chhaganlal Gandhi ◽  
Chia-Liang Cheng ◽  
Sheng Yun Wu

We report the synthesis of room temperature (RT) stabilized γ–Bi2O3 nanoparticles (NPs) at the expense of metallic Bi NPs through annealing in an ambient atmosphere. RT stability of the metastable γ–Bi2O3 NPs is confirmed using synchrotron radiation powder X-ray diffraction and Raman spectroscopy. γ–Bi2O3 NPs exhibited a strong red-band emission peaking at ~701 nm, covering 81% integrated intensity of photoluminescence spectra. Our findings suggest that the RT stabilization and enhanced red-band emission of γ‒Bi2O3 is mediated by excess oxygen ion vacancies generated at the octahedral O(2) sites during the annealing process.


1989 ◽  
Vol 39 (5) ◽  
pp. 3138-3144 ◽  
Author(s):  
Katsuhiro Akimoto ◽  
Takao Miyajima ◽  
Yoshifumi Mori

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