Impurity Defect Induced Ferromagnetism Investigation of SiO2-Supported NiO Particles

This study examines amorphous SiO2-supported NiO particles by nickel concentration and calcination temperature arrangement to determine photoluminescence emission peaks and magnetic properties. Conventional co-precipitation with thermal calcination was used to produce NiO nanoparticles. Cubic NiO crystallization with single phase was improved by doubling the nickel concentration by calcination at 500 ºC and 600 ºC. Average crystalline size of 72 nm was obtained in the samples where double nickel concentration with calcination temperature at 600 ºC. Granular forms have been observed in all samples, and nickel clusters were shown in the samples where the nickel concentration is twice as high. Green band emission intensity increases with improved NiO crystallinity due to surface oxygen vacancies at 505 nm. It is interesting to observe ferrimagnetism for SiO2-supported NiO particles calcined at 500 ºC. From these results, optimal synthesis procedure and reduction in nucleation growth of NiO nanoparticles was achieved by double nickel concentration with calcination temperature at 600 ºC. Resumen. Este estudio examina partículas de NiO soportadas en SiO2. El estudio comprende la variación de la concentración de níquel y la temperatura de calcinación para determinar los picos de emisión de fotoluminiscencia y las propiedades magnéticas. Se utilizó la coprecipitación convencional con calcinación para producir nanopartículas de NiO. Se mejoró la cristalización cúbica de NiO con fase única al duplicar la concentración de níquel y calcinación a 500 ºC y 600 ºC. Se obtuvo un tamaño cristalino promedio de 72 nm en las muestras donde se duplicó la concentración de níquel con temperatura de calcinación a 600 ºC. Se observaron formas granulares en todas las muestras, y se encontraron agregados de níquel en las muestras donde la concentración de níquel fue el doble. La intensidad de la banda de emisión aumenta con la cristalinidad de NiO debido a las vacantes de oxígeno en la superficie. Es interesante observar el ferrimagnetismo de las partículas de NiO soportadas en SiO2 calcinadas a 500 ºC. A partir de estos resultados, se logró un procedimiento de síntesis óptimo y la reducción del crecimiento de nucleación de nanopartículas de NiO mediante una concentración doble de níquel con una temperatura de calcinación de 600 ºC.

Hypercubes of AGN Tori (HYPERCAT). II. Resolving the Torus with Extremely Large Telescopes

Recent infrared interferometric observations revealed sub-parsec scale dust distributions around active galactic nuclei (AGNs). Using images of Clumpy torus models and NGC 1068 as an example, we demonstrate that the near- and mid-infrared nuclear emission of some nearby AGNs will be resolvable in direct imaging with the next generation of 30 m telescopes, potentially breaking degeneracies from previous studies that used integrated spectral energy distributions of unresolved AGN tori. To that effect we model wavelength-dependent point spread functions from the pupil images of various telescopes: James Webb Space Telescope, Keck, Giant Magellan Telescope, Thirty Meter Telescope, and Extremely Large Telescope. We take into account detector pixel scales and noise, and apply deconvolution techniques for image recovery. We also model 2D maps of the 10 μm silicate feature strength, S 10, of NGC 1068 and compare with observations. When the torus is resolved, we find S 10 variations across the image. However, to reproduce the S 10 measurements of an unresolved torus a dusty screen of A V > 9 mag is required. We also fit the first resolved image of the K-band emission in NGC 1068 recently published by the GRAVITY Collaboration, deriving likely model parameters of the underlying dust distribution. We find that both (1) an elongated structure suggestive of a highly inclined emission ring, and (2) a geometrically thin but optically thick flared disk where the emission arises from a narrow strip of hot cloud surface layers on the far inner side of the torus funnel, can explain the observations.

Competitive X-Ray and Optical Cooling in the Collisionless Shocks of WR 140

The long-period, highly eccentric Wolf-Rayet star binary system WR 140 has exceptionally well-determined orbital and stellar parameters. Bright, variable X-ray emission is generated in shocks produced by the collision of the winds of the WC7pd+O5.5fc component stars. We discuss the variations in the context of the colliding-wind model using broadband spectrometry from the RXTE, Swift, and NICER observatories obtained over 20 yr and nearly 1000 observations through three consecutive 7.94 yr orbits, including three periastron passages. The X-ray luminosity varies as expected with the inverse of the stellar separation over most of the orbit; departures near periastron are produced when cooling shifts to excess optical emission in C iii λ5696 in particular. We use X-ray absorption to estimate mass-loss rates for both stars and to constrain the system morphology. The absorption maximum coincides closely with the inferior conjunction of the WC star and provides evidence of the ion-reflection mechanism that underlies the formation of collisionless shocks governed by magnetic fields probably generated by the Weibel instability. Comparisons with K-band emission and He i λ10830 absorption show that both are correlated after periastron with the asymmetric X-ray absorption. Dust appears within a few days of periastron, suggesting formation within shocked gas near the stagnation point. The X-ray flares seen in η Car have not occurred in WR 140, suggesting the absence of large-scale wind inhomogeneities. Relatively constant soft emission revealed during the X-ray minimum is probably not from recombining plasma entrained in outflowing shocked gas.

Enhancing the conversion efficiency of extreme ultraviolet light sources using a 2 µm-wavelength laser

In this study, we use the FLASH radiation hydrodynamic code and the FLYCHK atomic code to investigate the energy conversion and spectra associated with laser–Sn target interactions with 1 µm and 2 µm wavelength lasers. We found that the conversion efficiency (CE) reached as much as 3.38% with the 2 µm laser, which is 1.48 percentage points higher than the 1 µm laser (CE = 1.9%). In addition, we analyzed the contribution of dominant ionization states to the emission spectrum for both lasers. We observed that the growths of the out-of-band emission eventually led to a broadening of the spectrum, resulting in a reduction of SP for the 1 µm laser. By contrast, the emission main peaks were all centered near 13.5nm for the 2 µm laser, which is beneficial for efficient emission of light with a 13.5 nm wavelength (relevant for nanolithographic applications).

All-inorganic perovskite quantum dots-based electrospun polyacrylonitrile fiber for ultra-sensitive trace-recording

All-inorganic dual-phase CsPbBr3-Cs4PbBr6 quantum dots (CPB QDs)-based polyacrylonitrile (PAN) fiber synthesized by supersaturated recrystallization and electrospinning technique possesses characteristics of homogeneous morphology, high crystallinity and solution sensitivity. Under 365 nm laser excitation, CPB@PAN fiber exhibits surprising trace-recording capability attributing to the splash-enhanced fluorescence (FL) performance with a narrow-band emission at 477-515 nm. In the process of ethanol-anhydrous (EA) and water splashing, the CPB@PAN fiber presents conspicuous blue and green emission when contacting with EA and water, and maintains intense blue and green FL for more than 4 months. These experimental and theoretical findings provide a facile technology for the development of biological protection display, biotic detection and moisture-proof forewarning based on the trace-recording performance of CPB@PAN fiber.

Strain Compensation and Trade-Off Design Result in Exciton Emission at 306 nm from AlGaN LEDs at Temperatures up to 368 K

In this study, we suppressed the parasitic emission caused by electron overflow found in typical ultraviolet B (UVB) and ultraviolet C (UVC) light-emitting diodes (LEDs). The modulation of the p-layer structure and aluminum composition as well as a trade-off in the structure to ensure strain compensation allowed us to increase the p-AlGaN doping efficiency and hole numbers in the p-neutral region. This approach led to greater matching of the electron and hole numbers in the UVB and UVC emission quantum wells. Our UVB LED (sample A) exhibited clear exciton emission, with its peak near 306 nm, and a band-to-band emission at 303 nm. The relative intensity of the exciton emission of sample A decreased as a result of the thermal energy effect of the temperature increase. Nevertheless, sample A displayed its exciton emission at temperatures of up to 368 K. In contrast, our corresponding UVC LED (sample B) only exhibited a Gaussian peak emission at a wavelength of approximately 272 nm.