Equation of state density models for hydrocarbons in ultradeep reservoirs at extreme temperature and pressure conditions

2013 ◽  
Author(s):  
Yue Wu ◽  
Babatunde A. Bamgbade ◽  
Ward A. Burgess ◽  
Deepak Tapriyal ◽  
Hseen O. Baled ◽  
...  
Keyword(s):  
Equation Of State ◽  
Extreme Temperature ◽  
State Density ◽  
Temperature And Pressure

scholarly journals Equation of state in form which relates mol fraction and molarity of two (or more) component thermodynamic system consisted of ideal gases, and it’s applications

2010 ◽  
Vol 14 (3) ◽  
pp. 859-863
Author(s):  
Marko Popovic
Keyword(s):  
Equation Of State ◽  
Special Relativity ◽  
Mole Fraction ◽  
Relativistic Effects ◽  
Thermodynamic System ◽  
Ideal Gases ◽  
Other Substances ◽  
Temperature And Pressure ◽  
Insight Into

Most people would face a problem if there is a need to calculate the mole fraction of a substance A in a gaseous solution (a thermodynamic system containing two or more ideal gases) knowing its molarity at a given temperature and pressure. For most it would take a lot of time and calculations to find the answer, especially because the quantities of other substances in the system aren?t given. An even greater problem arises when we try to understand how special relativity affects gaseous systems, especially solutions and systems in equilibrium. In this paper formulas are suggested that greatly shorten the process of conversion from molarity to mole fraction and give us a better insight into the relativistic effects on a gaseous system.

AN EQUATION OF STATE FOR GASES AT LOW DENSITIES

1932 ◽  
Vol 6 (6) ◽  
pp. 596-604 ◽  
Author(s):  
D. LeB. Cooper ◽  
O. Maass
Keyword(s):  
Carbon Dioxide ◽  
Equation Of State ◽  
Equations Of State ◽  
Absolute Temperature ◽  
Viscosity Function ◽  
Temperature And Pressure ◽  
New Equation ◽  
Molecular Radius ◽  
Expanded Form ◽  
Density Results

An equation of state for gases at low densities is developed, using a new function for the change in viscosity with temperature, also developed herein.The gas law equation takes the form[Formula: see text]or V(1 + KT)(PV − RT) = λT − a where a and b are constants corresponding to those of the Van der Waals' equation, and K is a constant derived from the proposed viscosity function which is, for carbon dioxide,[Formula: see text]where K is a constant and η is the viscosity at an absolute temperature T.In the case of carbon dioxide the equation was found to follow density results with an accuracy of from 0.01% to within experimental limits, and the viscosity function was found to agree with Sutherland's (10) results between −78.5 and 20 °C.Comparisons with several other equations of state are made. These show that the new equation is probably more accurate than any other.An expanded form of the new equation, namely:[Formula: see text]permits calculations of the slopes of isothermals for any temperature. Comparisons are made with experimental data.The expanded form of the equation may be solved for K, giving the expression:[Formula: see text]where [Formula: see text] and [Formula: see text] and ξ = Rb0, and since the equation enables the calculation of the molecular radius r, the viscosity may be calculated for any temperature and pressure over which the equation holds.

Study of High-Pressure Physical Properties of Marine Heavy Oil

2016 ◽  
Vol 693 ◽  
pp. 411-418
Author(s):  
S.Q. Kang ◽  
Y.P. You ◽  
M.Y. Feng
Keyword(s):  
Mathematical Model ◽  
High Pressure ◽  
Equation Of State ◽  
Physical Properties ◽  
Bulk Modulus ◽  
Heavy Oil ◽  
Dynamic Viscosity ◽  
Correlation Coefficients ◽  
Temperature And Pressure ◽  
The Mathematical Model

This paper obtains the formula for calculating fuel dynamic viscosity based on the Barus formula and Eying formula from both macroscopic and microscopic perspectives, studies the mathematical model of fuel bulk modulus changing with temperature and pressure based on equation of state for gases and solids, and computes the fitting formula and correlation coefficients of dynamic viscosity and bulk modulus based on IFO 180 test data. The result indicates that the calculation models for fuel dynamic viscosity and bulk modulus are effective.

On the Equation of State of an Ionised Gas

1930 ◽  
Vol 26 (1) ◽  
pp. 107-114
Author(s):  
W. H. McCrea
Keyword(s):  
Equation Of State ◽  
Total Energy ◽  
Unit Volume ◽  
Physical Factors ◽  
Relative Importance ◽  
Temperature And Pressure

The equation of state of an ionised gas has been discussed from time to time by various writers*. It is of importance chiefly in astrophysical applications. The simplest form of the problem, and the only form considered in this note, is to find the pressure in a gas of given temperature in which the numbers of atoms per unit volume at the different possible stages of ionisation are supposed known. In describing the ionisation an electron is counted as “free” when its total energy is positive. If this problem can be solved we should have a good estimate of the relative importance of the various physical factors at work, without tackling the more difficult, though more natural, problem of finding the ionisation for given temperature and pressure.

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