Preparation and characterization activated carbon from rice husk and oil palm empty fruit bunches for removal of Zn2+ in aqueous solution

2016 ◽  
Author(s):  
Nur Enzati Afwana Ismail ◽  
Mohd F. Taha ◽  
Anita Ramli
2014 ◽  
Vol 225 (10) ◽  
Author(s):  
Riry Wirasnita ◽  
Tony Hadibarata ◽  
Abdull Rahim Mohd Yusoff ◽  
Zulkifli Yusop

2014 ◽  
Vol 875-877 ◽  
pp. 196-201 ◽  
Author(s):  
Mohd Faisal Taha ◽  
Ahmad S. Rosman ◽  
Maizatul S. Shaharun

The potential of rice husk-based activated carbon as an alternative low-cost adsorbent for the removal of Pb (II) ion from aqueous solution was investigated. Rice husk-based activated carbon was preparedviachemical activation process using NaOH followed by the carbonization process at 500°C. Morphological analysis was conducted using field-emission scanning electron microscope /energy dispersive X-ray (FESEM/EDX) on three samples, i.e. raw rice husk, rice husk treated with NaOH and rice husk-based activated carbon. These three samples were also analyzed for their C, H, N, O and Si contents using CHN elemental analyzer and FESEM/EDX. The textural properties of rice husk-based activated carbon, i.e. surface area (253 m2/g) and pore volume (0.17 cm2/g), were determined by N2adsorption. The adsorption studies using rice husk-based activated carbon as an adsorbent to remove Pb (II) ion from aqueous solution were carried out at a fixed initial concentration of Pb (II) ion (150 ppm) with varying adsorbent dose as a function of contact time at room temperature. The concentration of Pb (II) ion was determined by atomic absorption spectrophotometer (AAS). The removal of Pb (II) ion from aqueous solution increased from 35 % to 82 % when the amount of rice husk-based activated carbon was increased from 0.05 g to 0.30 g. The equilibrium data obtained from adsorption studies was found to fit both Langmuir and Freundlich adsorption isotherms.


2019 ◽  
Vol 14 (4) ◽  
pp. 897-907 ◽  
Author(s):  
Hosseinali Asgharnia ◽  
Hamidreza Nasehinia ◽  
Roohollah Rostami ◽  
Marziah Rahmani ◽  
Seyed Mahmoud Mehdinia

Abstract Phenol and its derivatives are organic pollutants with dangerous effects, such as poisoning, carcinogenicity, mutagenicity, and teratogenicity in humans and other organisms. In this study, the removal of phenol from aqueous solution by adsorption on silica and activated carbon of rice husk was investigated. In this regard, the effects of initial concentration of phenol, pH, dosage of the adsorbents, and contact time on the adsorption of phenol were investigated. The results showed that the maximum removal of phenol by rice husk silica (RHS) and rice husk activated carbon (RHAC) in the initial concentration of 1 mgL−1 phenol, 2 gL−1 adsorbent mass, 120 min contact time, and pH 5 (RHS) or pH 6 (RHAC) were obtained up to 91% and 97.88%, respectively. A significant correlation was also detected between increasing contact times and phenol removal for both adsorbents (p < 0.01). The adsorption process for both of the adsorbents was also more compatible with the Langmuir isotherm. The results of this study showed that RHS and RHAC can be considered as natural and inexpensive adsorbents for water treatment.


2010 ◽  
Vol 81 (2) ◽  
pp. 593-599 ◽  
Author(s):  
N.S. Awwad ◽  
H.M.H. Gad ◽  
M.I. Ahmad ◽  
H.F. Aly

2015 ◽  
Vol 754-755 ◽  
pp. 950-954
Author(s):  
Mohd Faisal Taha ◽  
Anis Suhaila Shuib ◽  
Maizatul Shima Shaharun ◽  
Azry Borhan

An attempt was made to study the potential of rice husk as an alternative cheap precursor for activated carbon to remove Ni2+ from aqueous solution. Rice husk was treated chemically (with NaOH) and physically (carbonization) to prepare rice husk based activated carbon (RHAC). The textural properties of RHAC, i.e. surface area (255 m2/g) and pore volume (0.17 cm2/g), were determined by N2 adsorption using Brunauer-Emmett-Teller (BET) surface analyzer. RHAC was also characterized for its morphology and its elemental compositions. The adsorption studies for the removal of Ni2+ from aqueous solution were carried out using different dosage of RHAC as adsorbent as a function of varied contact time. The concentration of Ni2+ was determined by atomic absorption spectrometer (AAS). The results obtained from adsorption studies indicate good potential of rice husk as a cheap precursor to produce activated carbon for the removal of Ni2+ from aqueous solution. The equilibrium data from adsorption studies fitted well the of Langmuir and Freundlich isotherm models.


Author(s):  
Kurnia Sandi ◽  
Ricky Andi Syahputra ◽  
Moondra Zubir

Research on metal adsorption isotherms with activated carbon oil palm empty fruit bunches in liquid waste. Oil palm empty fruit bunches are used as adsorbent for metal absorption. Oil palm empty fruit bunches are prepared at 105O C for 24 hours to get a constant weight then are characterized by SEM. Oil palm empty fruit bunches are heated at temperatures (400O C – 700O C) to get activated carbon. Re-characterization using SEM at optimum conditions shows that the pore surface is expanding. Then with a batch method for metal absorption (Cu, Pb, Hg) and analyzed using AAS. The most common absorption of activated carbon of oil palm empty fruit bunches is Cu (II). Based on the Langmuir and Freundlich R2 models close to 1, which means that multi-layer adsorption occurs.


2020 ◽  
Vol 8 (2) ◽  
pp. 2653-2660
Author(s):  
M Mardhiana ◽  
Dwi Apriyani ◽  
Muh Adiwena ◽  
Ankardiansyah Pandu Pradana

On acid soils, maize growth cannot be optimal because of the high content of Al, Fe, Mg, and Zn, which has the potential to poison plants. Several nutrients such as P, Cu, and S are also available in small quantities for plants, thus inhibiting growth. This study aimed to determine the effectiveness of oil palm empty fruit bunches compost and rice husk charcoal in increasing the growth and yield of maize on red-yellow podzolic acid soils. Bonanza F1 varieties were planted and treated with (T1) 5 t ha-1 of oil palm empty fruit bunches compost; (T2) 10 t ha-1 of oil palm empty fruit bunches compost; (T3) 5 t ha-1 rice husk charcoal; (T4) 10 t ha-1 rice husk charcoal; and (T5) 5 t ha-1 of oil palm empty fruit bunches compost + 5 t ha-1 of rice husk charcoal, and control plants were not given any treatment. The results showed that all treatments had a better and significantly different effect than the control plants. The application of oil palm empty fruit bunches compost and rice husk charcoal could boost plants height (149.75% - 289.88%), stems diameter (124.10% - 204.62%), number of leaves (131.01% - 223.26%), plants fresh weight (204.14% - 342.25 %), plants dry weight (136.77% - 165.76%), weight of maize cobs (178.77% - 292.72%), weight of maize cobs without maize husks (158.27% - 233.03%), maize cobs length (112.44% - 147.14%), maize cobs diameter (117.16% - 187.79%), and the weight of 100 maize kernels (110.92% - 201.72%). Among all treatments, the T5 treatment (5 t ha-1 of oil palm empty fruit bunches compost + 5 t ha-1 rice husk charcoal) was the best because it consistently gave the highest yields on all observed variables.


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