Accurate temperature measurement by temperature field analysis in diamond anvil cell for thermal transport study of matter under high pressures

2018 ◽  
Vol 112 (8) ◽  
pp. 081901 ◽  
Author(s):  
Donghui Yue ◽  
Tingting Ji ◽  
Tianru Qin ◽  
Jia Wang ◽  
Cailong Liu ◽  
...  
2019 ◽  
Vol 116 (39) ◽  
pp. 19324-19329 ◽  
Author(s):  
Rajkrishna Dutta ◽  
Eran Greenberg ◽  
Vitali B. Prakapenka ◽  
Thomas S. Duffy

Neighborite, NaMgF3, is used as a model system for understanding phase transitions in ABX3 systems (e.g., MgSiO3) at high pressures. Here we report diamond anvil cell experiments that identify the following phases in NaMgF3 with compression to 162 GPa: NaMgF3 (perovskite) → NaMgF3 (post-perovskite) → NaMgF3 (Sb2S3-type) → NaF (B2-type) + NaMg2F5 (P21/c) → NaF (B2) + MgF2 (cotunnite-type). Our results demonstrate the existence of an Sb2S3-type post-post-perovskite ABX3 phase. We also experimentally demonstrate the formation of the P21/c AB2X5 phase which has been proposed theoretically to be a common high-pressure phase in ABX3 systems. Our study provides an experimental observation of the full sequence of phase transitions from perovskite to post-perovskite to post-post-perovskite followed by 2-stage breakdown to binary compounds. Notably, a similar sequence of transitions is predicted to occur in MgSiO3 at ultrahigh pressures, where it has implications for the mineralogy and dynamics in the deep interior of large, rocky extrasolar planets.


2020 ◽  
Author(s):  
Kenji Ohta ◽  
Kei Hirose

Abstract Precise determinations of the thermal conductivity of iron alloys at high pressures and temperatures are essential for understanding the thermal history and dynamics of the metallic cores of the Earth. We review relevant high-pressure experiments using a diamond-anvil cell and discuss implications of high core conductivity for its thermal and compositional evolution.


1973 ◽  
Vol 27 (5) ◽  
pp. 377-381 ◽  
Author(s):  
D. M. Adams ◽  
S. J. Payne ◽  
K. Martin

A new design of diamond anvil high pressure cell suitable for use in infrared and Raman spectroscopy is described. Its performance is demonstrated with particular reference to the pressure dependence of the infrared spectrum of K2PtCl6 and the Raman spectrum of W(CO)6. In contrast to earlier reports, in which forward scattering geometry was used, this design of cell is shown to be very suitable for Raman use in the 180° excitation mode. However, severe limitations are imposed by the fluorescence emission of diamond and of sapphire. Conditions under which the cell can be used for Raman work are summarized. New fluorescence and Raman features are reported for diamond. In particular, a band at 1730 cm−1 is characteristic of type I stones and may be due to C to N bond stretching at defect centers.


2014 ◽  
Vol 2014 (0) ◽  
pp. _J0420306--_J0420306-
Author(s):  
Shu SEKIGUCHI ◽  
Nobutomo NAKAMURA ◽  
Mari EINAGA ◽  
Katsuya SHIMIZU ◽  
Atsushi MIYAKE ◽  
...  

2008 ◽  
Vol 573-574 ◽  
pp. 35-43 ◽  
Author(s):  
Nicolaas Stolwijk ◽  
Ludmila Lerner ◽  
Axel Giese ◽  
Wilfried Lerch

The study of fast diffusion processes in materials requires short isothermal annealing treatments combined with an accurate temperature measurement. The paper discusses the special demands on rapid thermal annealing (RTA) devices in diffusion research and how these can be met in practice. The scientific impact of RTA for diffusion research in semiconductors is demonstrated by several examples dealing with fast impurities in Ge and Si.


2020 ◽  
Vol 91 (4) ◽  
pp. 045121 ◽  
Author(s):  
J. Immoor ◽  
H. Marquardt ◽  
L. Miyagi ◽  
S. Speziale ◽  
S. Merkel ◽  
...  

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