Evaluation of an integrated hydrocarbon sensor array system for the detection of dissolved oil components in sea water and its potential application in seepage exploration
Marine surveys for the detection of naturally seeping hydrocarbons require a wide range of complementary remote sensing and geochemical techniques in order to achieve reliable data interpretation and prediction. Compared with current geochemical techniques such as sniffers and sea bed head space gas analysis, oil-in-water hydrocarbon sensors can provide real-time chemical information. The use of these sensors, in combination with current methods, offers a potentially important aid in achieving an integrated approach. In this study, CSIRO Petroleum has constructed a hydrocarbon sensors array that is composed of three groups of sensors that target volatile mono-aromatic hydrocarbons, poly-aromatic hydrocarbons at low concentration and oil films, respectively. This configuration allows us to have a comprehensive map of hydrocarbon distribution in water samples in real time. The variety of response times, sensitivities and operating conditions of the sensing devices has been considered, in order to design a flow tank and develop suitable monitoring and control software for the array. Chemometric tools such as principle component analysis (PCA) are used for data analysis and prediction model creation.Results will be presented from the evaluation measurements carried out in three stages. These include: laboratory evaluation of the sensor array to the dissolved oil components of a series of crude oil samples in synthetic sea water; sensor responses to natural sea water samples; and, initial field studies during surveys in Australian sea waters. To our knowledge, there have been no previously recorded instances of using such a hydrocarbon sensor array for oil and gas exploration.