Star-shaped Poly(2-oxazoline)s by Dendrimer Endcapping
Keyword(s):
The synthesis of star-shaped poly(2-ethyl-2-oxazoline) is reported by direct end-capping of the living polymer chains with dendritic multiamines. The end-capping kinetics after addition of a first generation polypropylenimine dendrimer are discussed based on monitoring by size exclusion chromatography, revealing less efficient end-capping with larger poly(2-ethyl-2-oxazoline) chains and increasing dendrimer generation. In addition, it is demonstrated that the solution viscosity and cloud point temperature of the star-shaped polymers are much less affected by chain length compared with their linear analogues.
2012 ◽
Vol 291
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pp. 919-925
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2000 ◽
Vol 15
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pp. 387-394
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2013 ◽
Vol 84
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pp. 075118
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2013 ◽
Vol 117
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pp. 11830-11835
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2019 ◽
Vol 43
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pp. 439-456
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2019 ◽
Vol 33
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pp. 10390-10390
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2017 ◽
Vol 295
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pp. 1343-1349
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