Concentrations and speciation of lead, zinc and cadmium in seawater-like smelter effluent and adjacent marine environments, Port Pirie, South Australia

1983 ◽  
Vol 34 (3) ◽  
pp. 375 ◽  
Author(s):  
J Ferguson
Keyword(s):  
South Australia ◽  
Tidal Channel ◽  
Significant Extent ◽  
Dissolved Metals ◽  
Metal Concentrations ◽  
Near Surface ◽  
Unicellular Algae ◽  
Particulate Metal ◽  
Lead Zinc ◽  
High Concentrations

High concentrations of particulate and dissolved lead, zinc and cadmium (total dissolved Pb, 750�g l-1; Zn, 4300�g 1-1; Cd, 64 �g l-1; particulate Pb, 236 �g l-1; Zn, 64 �g l-1; Cd, < 1 �g l-1) occur in seawater- like effluent from a lead-zinc smelting complex at Port Pirie. This effluent is discharged through a silled tidal channel into the offshore marine environment, where dilution by seawater eventually reduces the metal concentrations to values similar to those in near-surface seawater in Spencer Gulf, remote from centres of industrial activity (average total dissolved Pb, 0 4 �g 1-1; Zn, < 10 μg l-1; Cd, 0 3 �g l-1; average particulate Pb, <0.05 �g l-1; Zn, 0 21 �g I-1). Precipitation of dissolved metals or conversion of originally weakly complexed dissolved metals to more strongly complexed species does not occur to a significant extent. Particulate metal concentrations are influenced by resuspension of metal-rich sediments and by uptake of dissolved cadmium by unicellular algae that grow in the tidal channel.

scholarly journals Lead, zinc, and chromium concentrations in acidic headwater streams in Sweden explained by chemical, climatic, and land-use variations

2012 ◽  
Vol 9 (11) ◽  
pp. 4323-4335 ◽  
Author(s):  
B. J. Huser ◽  
J. Fölster ◽  
S. J. Köhler
Keyword(s):  
Land Use ◽  
Predictive Power ◽  
Prediction Models ◽  
Headwater Streams ◽  
Data Series ◽  
Seasonal Differences ◽  
Metal Concentrations ◽  
Lead Zinc ◽  
Term Data

Abstract. Long-term data series (1996–2009) for eleven acidic headwater streams (< 10 km2) in Sweden were analyzed to determine factors controlling concentrations of trace metals. In-stream chemical data as well climatic, flow, and deposition chemistry data were used to develop models predicting concentrations of chromium (Cr), lead (Pb), and zinc (Zn). Data were initially analyzed using partial least squares to determine a set of variables that could predict metal concentrations across all sites. Organic matter (as absorbance) and iron related positively to Pb and Cr, while pH related negatively to Pb and Zn. Other variables such as conductivity, manganese, and temperature were important as well. Multiple linear regression was then used to determine minimally adequate prediction models which explained an average of 35% (Cr), 52% (Zn), and 72% (Pb) of metal variation across all sites. While models explained at least 50% of variation in the majority of sites for Pb (10) and Zn (8), only three sites met this criterion for Cr. Investigation of variation between site models for each metal revealed geographical (altitude), chemical (sulfate), and land-use (silvaculture) influences on predictive power of the models. Residual analysis revealed seasonal differences in the ability of the models to predict metal concentrations as well. Expected future changes in model variables were applied and results showed the potential for long-term increases (Pb) or decreases (Zn) for trace metal concentrations at these sites.

scholarly journals Physico-chemical properties and heavy metal contents of a tropical estuarine ecosystem, Nigeria

2018 ◽  
Vol 5 (11) ◽  
pp. 781-797
Author(s):  
Paul Chinedu Echi ◽  
Daberechi Ndudim Okpechi ◽  
Janet Azu Urum ◽  
Izuchukwu Samson Arukwe
Keyword(s):  
Heavy Metal ◽  
Chemical Properties ◽  
Oxygen Demand ◽  
International Standards ◽  
Anthropogenic Pressure ◽  
Estuarine Ecosystem ◽  
Metal Concentrations ◽  
Metal Contents ◽  
Zinc Cadmium ◽  
Lead Zinc

Ibaka Estuarine in Mbo, Nigeria, has little or no information on its basic properties, therefore its water samples were studied from March to June 2018 in three different stations and compared with International Standards to evaluate its physic-chemical properties as well as heavy metal contents. The physic-chemical properties studied include pH, salinity (g/L), EC (μs/cm), turbidity (NTU), total suspended solids (mg/L), total dissolved solids (mg/L), dissolved oxygen (mg/L), BOD5 (mg/L), and chemical oxygen demand (mg/L). In addition, some metal concentrations of manganese, iron, copper, lead, zinc, cadmium, chloride and magnesium were determined by atomic absorption spectroscopy (AAS). The range of metal concentrations manganese (0.08-0.12 mg/L), copper (0.05-0.09 mg/L), lead (0.01-0.03 mg/L), iron (1.86-4.66 mg/L), zinc (0.68-1.16 mg/L), cadmium (0.04-0.08 mg/L), chloride (675.0-791.25 mg/L), magnesium (10.66-14.30 mg/L). The study infers that anthropogenic pressure plays damaging role to its properties in addition to general health implication of high values for Fe, Zn, Cd, Cl and Mg which exceeded international standard.

A Review of Technologies Used in Handling The Acid Mine Drainage Challenge: Perspectives on Using Green Liquor Dregs As a Sustainable Option For Treatment of Acid Mine Drainage

2021 ◽  
Vol 47 (1) ◽  
pp. 1-18
Author(s):  
Keolebogile R. Sebogodi ◽  
Jonas K. Johakimu ◽  
B. Bruce Sithole
Keyword(s):  
Acid Mine Drainage ◽  
Mine Drainage ◽  
Current Trend ◽  
Dissolved Metals ◽  
Green Liquor ◽  
Acid Mine ◽  
Treatment And Prevention ◽  
Green Liquor Dregs ◽  
High Concentrations ◽  
By Products

Acid mine drainage (AMD) is one of the repercussions that result from earth-moving activities around the sulfide-bearing mineral hosts. The detrimental effects associated with this AMD are driven by its characteristics, which include low pH and high concentrations of sulfate and toxic dissolved metals. Traditionally, the prevention and treatment of AMD are achieved by using technologies that use, amongst other, naturally occurring soils and carbonates. However, the continual use of these materials may eventually lead to their depletion. On the other hand, industrial by-products have been proven to occupying land that could have otherwise been used for profitable businesses. Additionally, the handling and maintenance of landfills are costly. In this current trend of a circular economy that is driven by industrial symbiosis, scientists are concerned with valorizing industrial by-products. One such by-product is the green liquor dregs (GLD) from Kraft mills. The neutralizing and geotechnical properties of these wastes have prompted the research pioneers to seek their potential use in handling the challenges associated with AMD. In this review, the formation AMD, trends in technologies for treatment and prevention of AMD are critically analyzed. This includes the feasibility of using GLD as an alternative, promising sustainable material.

scholarly journals On the role of tropopause folds in summertime tropospheric ozone over the eastern Mediterranean and the Middle East

2016 ◽  
Vol 16 (21) ◽  
pp. 14025-14039 ◽  
Author(s):  
Dimitris Akritidis ◽  
Andrea Pozzer ◽  
Prodromos Zanis ◽  
Evangelos Tyrlis ◽  
Bojan Škerlak ◽  
...  
Keyword(s):  
Middle East ◽  
Atmospheric Chemistry ◽  
Tropospheric Ozone ◽  
Eastern Mediterranean ◽  
Stratospheric Ozone ◽  
Surface Ozone ◽  
Free Troposphere ◽  
Near Surface ◽  
Grid Points ◽  
High Concentrations

Abstract. We study the contribution of tropopause folds in the summertime pool of tropospheric ozone over the eastern Mediterranean and the Middle East (EMME) with the aid of the ECHAM5/MESSy Atmospheric Chemistry (EMAC) model. Tropopause fold events in EMAC simulations were identified with a 3-D labeling algorithm that detects folds at grid points where multiple crossings of the dynamical tropopause are computed. Subsequently the events featuring the largest horizontal and vertical extent were selected for further study. For the selection of these events we identified a significant contribution of the stratospheric ozone reservoir to the high concentrations of ozone in the middle and lower free troposphere over the EMME. A distinct increase of ozone is found over the EMME in the middle troposphere during summer as a result of the fold activity, shifting towards the southeast and decreasing altitude. We find that the interannual variability of near-surface ozone over the eastern Mediterranean (EM) during summer is related to that of both tropopause folds and ozone in the free troposphere.

The geophysical signature of the Paleoproterozoic Menninnie Dam lead-zinc-silver prospect, South Australia

2003 ◽  
Vol 2003 (3) ◽  
pp. 59-66
Author(s):  
Nigel Hungerford ◽  
Jovan Silic ◽  
Mike Dentith
Keyword(s):  
South Australia ◽  
Lead Zinc

Changes in Cu, Ni, and Zn availability following simulated conversion of biosolids-amended forest soils back to agricultural use

Soil Research ◽  
2010 ◽  
Vol 48 (3) ◽  
pp. 286 ◽  
Author(s):  
R. G. McLaren ◽  
A. Black ◽  
L. M. Clucas
Keyword(s):  
Soil Solution ◽  
Forest Soils ◽  
Mineral Soil ◽  
Forest Litter ◽  
Metal Availability ◽  
Metal Concentrations ◽  
Organic Complexes ◽  
Agricultural Use ◽  
High Concentrations ◽  
Wheat Germination

In this study we examined the bioavailability and chemistry of Cu, Ni, and Zn in metal-spiked, biosolids-amended forest (Pinus radiata) soils that had undergone a simulated conversion back to agricultural use. Mixing of the biosolids-treated forest litter into the underlying mineral soil resulted in high concentrations of each metal in easily extractable and soil solution forms. There was also very little change in these concentrations during a subsequent 2-year incubation period of the samples. Chemical speciation of the soil solutions using WHAM 6 showed that Cu was dominated by organic complexes, whereas most Ni and Zn was present as Ni2+ and Zn2+, with generally <5% of these elements present as organic complexes. Addition of lime to the soils substantially decreased both readily extractable and soil solution metal concentrations. However, even in their unlimed state, although plant metal concentrations were increased by the original biosolids treatments, there were no adverse effects due to the metals on plant growth as determined in a wheat germination and seedling growth test. In this study, the DGT technique showed considerable promise for assessing metal availability to plants. However, the study suggests that conversion of biosolids-treated forest soils back for agricultural use is unlikely to result in any substantial problems related to the metal loadings built up in the forest litter layer.

Discharge of metals from the St. Lawrence River

1982 ◽  
Vol 19 (5) ◽  
pp. 982-992 ◽  
Author(s):  
P. A. Yeats ◽  
J. M. Bewers
Keyword(s):  
Water Flow ◽  
Weak Acid ◽  
Dissolved Metals ◽  
Monthly Basis ◽  
Crustal Rocks ◽  
Coastal Marine ◽  
Suspended Particulate ◽  
Particulate Metal ◽  
Metal Aluminum ◽  
St Lawrence River

The concentrations of dissolved and total Al, Fe, Mn, Co, Ni, Cu, Zn, and Cd in St. Lawrence River water have been measured on a monthly basis over a 2 year period. Riverine suspended particulate matter was also analyzed for nondetrital Mg, Ca, Si, Al, Fe, Mn, Co, Ni, Cu, Zn, and Cd and detrital Mg, Ca, Si, Al, Fe, and Mn. Variability in the concentration of dissolved metals is unrelated to changes in water flow or suspended load. Particulate Al, Fe, Mn, and Zn concentrations are related to water flow. The metal/aluminum ratios of particulate Mn, Cu, Zn, and Cd are elevated with respect to crustal rocks or coastal marine sediments, with the enrichment occurring in the nondetrital, or weak acid soluble, fraction.Annual dissolved metal discharges and nondetrital and total particulate metal discharges that take into account monthly variations in metal concentrations have been calculated for the St. Lawrence River. These discharges have been used to estimate global annual river discharges of metals to the ocean. The calculated discharges are compared with estimates based upon other rivers. The importance of nondetrital particulate metal fluxes is emphasized.

An overview of silicification in Cainozoic landscapes of arid central and southern Australia

Soil Research ◽  
1983 ◽  
Vol 21 (4) ◽  
pp. 387 ◽  
Author(s):  
AR Milnes ◽  
CR Twidale
Keyword(s):  
Chemical Compositions ◽  
Moisture Regime ◽  
Drainage Basins ◽  
Near Surface ◽  
Base Level ◽  
Silica Diagenesis ◽  
Local Fluctuations ◽  
Soluble Silica ◽  
High Concentrations ◽  
Acid Weathering

Silica diagenesis in the near-surface zones of subdued Tertiary drainage basins in the arid interior of central and southern Australia produced a mosaic of silcretes now exposed as relic duricrust on mesas that are significantly higher than the contemporary base-level of erosion. The silcretes comprise a variety of silica-cemented sediments and possibly soils that exhibit a range of textures and chemical compositions. Acid-weathering conditions in pedogenic environments near the margins of the Tertiary drainage basins are likely to have provided soluble silica for soil waters and groundwater moving slowly through the regolith into depositional zones in the lower reaches of the basins. The silica cement in silcretes ranges from ordered forms of opal to quartz overgrowths, and the existence of incomplete transformations between structural states and between textural forms suggests heterogeneous precipitation and recrystallization in response to local fluctuations in properties such as pH and moisture regime. High concentrations of titanium were precipitated from solution in bedrock fractures as well as in sediments in the piedmont of the ancient drainage basins, but as yet there is no unequivocal explanation for its occurrence. Apart from zircon, enrichment of zirconium and aluminium in areas of high titanium concentration is evident from electron probe microanalyses and X-ray scanning images, but the mineral phase or phases responsible for this distribution are unidentified.

Trace Elements Geochemistry of Soil-Plant System in Puxiong Lead-Zinc Mining Area, Yunnan, China

2013 ◽  
Vol 726-731 ◽  
pp. 239-244
Author(s):  
Juan Wang ◽  
Zheng Hai Wang
Keyword(s):  
Trace Elements ◽  
Correlation Coefficients ◽  
Mining Area ◽  
High Concentration ◽  
Transition Area ◽  
Lead Zinc ◽  
Measured Ratio ◽  
Concentration Factors ◽  
High Concentrations ◽  
The Relationship

This study aims to obtain an overview of trace elements concentrations in rocks, soils and plants from Puxiong lead-zinc mining area in Yunnan, China, and analyze the connection as well. Concentrations of Ba, Cd, Co, Cu, Mn, Pb, Zn, As, Sb, Hg, Sn, Ni and Sr among soils, rocks and three dominant plants in mining area, transition area and background were measured. Ratio parameter, bioconcentration factors (BF) and Pearson's correlation coefficients were used to analyze the relationship between these elements in different feature. The results indicate that rocks, soils and plants samples are all characterized by high concentrations of Pb, Zn and other associated elements in Puxiong lead-zinc mining area. Geochemistry of trace elements concentrations from rocks to soils, then to plants presents obvious characters of inheritance and variability. Whats more, three dominant plants are same in high concentration of Mn and low concentration of Cd, Hg, Co, but are huge different in bio-concentration factors.

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