scholarly journals Acoustic Vibrational Properties and Fractal Bond Connectivity of Praseodymium Doped Glasses

2000 ◽  
Vol 53 (6) ◽  
pp. 805
Author(s):  
H. B. Senin ◽  
H. A. A. Sidek ◽  
G. A. Saunders

The velocities of longitudinal and shear ultrasonic waves propagated in the (Pr2O3)x(P2O5)1-x glass system, where x is the mole fraction of Pr2O3 and (1 - x) is the mole fraction of P2O5, have been measured as functions of temperature and hydrostatic pressure. The temperature dependencies of the second order elastic stiffness tensor components (SOEC) CS IJ , which have been determined from the velocitydata between 10 and 300 K, show no evidence of phonon mode softening throughout the whole temperature range. The elastic stiffnesses increased monotonically, the usual behaviour associated with the effect of the phonon anharmonicityof atomic vibration. At low temperatures, strong phonon interactions with two-level systems have been observed. The ultrasonic wave attenuation of longitudinal and shear waves is dominated bya broad acoustic loss peak whose height and peak position are frequencydependent. This behaviour is consistent with the presence of thermally activated structural relaxation of the two-level systems in these glasses. The fractal bond connectivity of these glasses, obtained from the elastic stiffnesses determined from ultrasonic wave velocities, has a value between 2.32 to 2.55, indicating that their connectivitytends towards having a threedimensional character. The hydrostatic pressure dependencies of longitudinal ultrasonic waves show a slight increase with pressure. As a consequence, the hydrostatic pressure derivatives ( CS11/ P)P=0 of the elastic stiffness CS11/ and (BS/P)P=0 of the bulk modulus BS of (Pr2O3)x(P2O5)1-x glasses are positive. The bulk modulus increases with pressure, and thus these glasses stiffen under pressure, which is associated with the normal elastic behaviour. The GrÜneisen parameter approach has been used to quantifythe vibrational anharmonicityof the long-wavelength acoustic phonons in these glasses.

1994 ◽  
Vol 47 (6) ◽  
pp. 795 ◽  
Author(s):  
HB Senin ◽  
HAA Sidek ◽  
GA Saunders

The elastic and nonlinear acoustic vibrational properties of terbium metaphosphate glasses (Tb2O3)x(P2O5)1?x with x = 0�226,0�247,0�263 and 0�271 (x is the mole fraction) have been determined from measurements of the effects of temperature, hydrostatic pressure, and uniaxial stress on' ultrasonic wave velocity. At temperatures below about 140 K, the elastic stiffness of' (Tb2O3)x(P2O5)1?x glasses becomes anomalously dependent upon temperature, a behaviour usually associated with interactions between acoustic phonons and two-level systems. Except for the (Tb2O3)0�271(P205)0�729 glass, the hydrostatic pressure derivatives of the elastic stiffness and also of the bulk modulus BS of terbium metaphosphate glasses are small and negative. The third-order elastic stiffness tensor components CIJK of the (Tb2O3)0�247(P2O5)0�753 glass between 77 K and 400 K have also been determined. At room temperature, C112, C123 and C144 are positive while C111, C155 and C456 are negative. Both longitudinal and shear acoustic mode Gr�neisen parameters are small and negative: the application of pressure softens the long-wavelength acoustic phonon mode frequencies. The mode softening is enhanced as the temperature is reduced.


Geophysics ◽  
2019 ◽  
Vol 84 (5) ◽  
pp. MR153-MR171 ◽  
Author(s):  
Linsen Zhan ◽  
Jun Matsushima

The nonintuitive observation of the simultaneous high velocity and high attenuation of ultrasonic waves near the freezing point of brine was previously measured in partially frozen systems. However, previous studies could not fully elucidate the attenuation variation of ultrasonic wave propagation in a partially frozen system. We have investigated the potential attenuation mechanisms responsible for previously obtained laboratory results by modeling ultrasonic wave transmission in two different partially frozen systems: partially frozen brine (two phases composed of ice and unfrozen brine) and unconsolidated sand (three phases composed of ice, unfrozen brine, and sand). We adopted two different rock-physics models: an effective medium model for partially frozen brine and a three-phase extension of the Biot model for partially frozen unconsolidated sand. For partially frozen brine, our rock-physics study indicated that squirt flow caused by unfrozen brine inclusions in porous ice could be responsible for high P-wave attenuation around the freezing point. Decreasing P-wave attenuation below the freezing point can be explained by the gradual decrease of squirt flow due to the gradual depletion of unfrozen brine. For partially frozen unconsolidated sand, our rock-physics study implied that squirt flow between ice grains is a dominant factor for P-wave attenuation around the freezing point. With decreasing temperature lower than the freezing point, the friction between ice and sand grains becomes more dominant for P-wave attenuation because the decreasing amount of unfrozen brine reduces squirt flow between ice grains, whereas the generation of ice increases the friction. The increasing friction between ice and sand grains caused by ice formation is possibly responsible for increasing the S-wave attenuation at decreasing temperatures. Then, further generation of ice with further cooling reduces the elastic contrast between ice and sand grains, hindering their relative motion; thus, reducing the P- and S-wave attenuation.


Geophysics ◽  
2008 ◽  
Vol 73 (2) ◽  
pp. N9-N18 ◽  
Author(s):  
Jun Matsushima ◽  
Makoto Suzuki ◽  
Yoshibumi Kato ◽  
Takao Nibe ◽  
Shuichi Rokugawa

Often, the loss mechanisms responsible for seismic attenuation are unclear and controversial. We used partially frozen brine as a solid-liquid coexistence system to investigate attenuation phenomena. Ultrasonic wave-transmission measurements on an ice-brine coexisting system were conducted to examine the influence of unfrozen brine in the pore microstructure on ultrasonic waves. We observed the variations of a 150–1000 kHz wave transmitted through a liquid system to a solid-liquid coexistence system, changing its temperature from [Formula: see text] to –[Formula: see text]. We quantitatively estimated attenuation in a frequency range of [Formula: see text] by considering different distances between the source and receiver transducers. We also estimated the total amount of frozen brine at each temperature by using the pulsed nuclear magnetic resonance (NMR) technique and related those results to attenuation results. The waveform analyses indicate that ultrasonic attenuation in an ice-brine coexisting system reaches its peak at [Formula: see text], at which the ratio of the liquid phase to the total volume in an ice-brine coexisting system is maximal. Finally, we obtained a highly positive correlation between the attenuation of ultrasonic waves and the total amount of unfrozen brine. Thus, laboratory experiments demonstrate that ultrasonic waves within this frequency range are affected significantly by the existence of unfrozen brine in the pore microstructure.


1983 ◽  
Vol 44 (C9) ◽  
pp. C9-337-C9-340 ◽  
Author(s):  
R. L. Smith ◽  
W. N. Reynolds ◽  
S. Perring

2021 ◽  
Vol 11 (12) ◽  
pp. 5720
Author(s):  
Saeid Taghizadeh ◽  
Robert Sean Dwyer-Joyce

When two rough surfaces are loaded together contact occurs at asperity peaks. An interface of solid contact regions and air gaps is formed that is less stiff than the bulk material. The stiffness of a structure thus depends on the interface conditions; this is particularly critical when high stiffness is required, for example in precision systems such as machine tool spindles. The rough surface interface can be modelled as a distributed spring. For small deformation, the spring can be assumed to be linear; whilst for large deformations the spring gets stiffer as the amount of solid contact increases. One method to measure the spring stiffness, both the linear and nonlinear aspect, is by the reflection of ultrasound. An ultrasonic wave causes a perturbation of the contact and the reflection depends on the stiffness of the interface. In most conventional applications, the ultrasonic wave is low power, deformation is small and entirely elastic, and the linear stiffness is measured. However, if a high-powered ultrasonic wave is used, this changes the geometry of the contact and induces nonlinear response. In previous studies through transmission methods were used to measure the nonlinear interfacial stiffness. This approach is inconvenient for the study of machine elements where only one side of the interface is accessible. In this study a reflection method is undertaken, and the results are compared to existing experimental work with through transmission. The variation of both linear and nonlinear interfacial stiffnesses was measured as the nominal contact pressure was increased. In both cases interfacial stiffness was expressed as nonlinear differential equations and solved to deduce the contact pressure-relative surface approach relationships. The relationships derived from linear and nonlinear measurements were similar, indicating the validity of the presented methods.


2014 ◽  
Vol 894 ◽  
pp. 45-49 ◽  
Author(s):  
Luisa Pani ◽  
Lorena Francesconi

In this paper an experimental program has been carried out in order to compare compressive strength fcand elastic static modulus Ecof recycled concrete with ultrasonic waves velocity Vp, to establish the possibility of employing nondestructive ultrasonic tests to qualify recycled concrete. 9 mix of concrete with different substitution percentage of recycled aggregates instead of natural ones and 27 cylindrical samples have been made. At first ultrasonic tests have been carried out on cylindrical samples, later elastic static modulus Ecand compressive strength fchave been experimentally evaluated. The dynamic elastic modulus Edhas been determined in function of ultrasonic wave velocity Vp; furthermore the correlations among Ed, Ec, fce Vphave been determined. It has been demonstrated that ultrasonic tests are suitable for evaluating different deformative and resisting concrete performances even when variations are small.


2022 ◽  
Vol 64 (2) ◽  
pp. 223
Author(s):  
Ф.С. Хоробрых ◽  
В.Д. Чуркин ◽  
М.Ю. Попов

We study the effect of high hydrostatic pressure on 3D polymerized fullerite C60. We do not observe further structural changes until 150 GPa after a formation of 3D C60 under hydrostatic pressure 28 GPa. It is experimentally shown that the obtained samples consist of different clusters formed by sp3 bonds with a different set of force constants, the values of which vary within 20% and exceed the diamond force constants by the factor of 1.3–1.5. The influence of the exposure of laser radiation on the process of 3D polymerization of C60 under pressure was found. Increasing of the exposure by the factor of 15 leads to a decrease in the bulk modulus of 3D C60 from 610 GPa to 504 GPa.


Sign in / Sign up

Export Citation Format

Share Document