scholarly journals Excited States of 8Be From the 7Li(d,n)8Be Reaction

1958 ◽  
Vol 11 (4) ◽  
pp. 502 ◽  
Author(s):  
RH Spear
Keyword(s):  
Excited State ◽  
Energy Spectrum ◽  
Excited States ◽  
Nuclear Emulsion ◽  
Nuclear Emulsions ◽  
Bombarding Energy ◽  
Broad Level

The energy spectrum of neutrons from the reaction 7Li(d,n)8 Be at 700 keV bombarding energy has been studied with nuclear emulsions at 0, 75, and 135�. Both resolution and statistics compare favourably with those of previous nuclear emulsion measurements of this spectrum. The results do not confirm the suggestions made by earlier workers that levels at 2�2, 4�1, 5�3, and 7�5 MeV in 8Be participate in the reaction, and support the view that the only excited state below 9 MeV in 8Be is the well-known broad level at 2�9 MeV.

scholarly journals The scattering of α -particles in helium

1939 ◽  
Vol 172 (951) ◽  
pp. 559-567 ◽  
Keyword(s):  
Excited State ◽  
Excited States ◽  
Ground State ◽  
Potential Barrier Height ◽  
Light Nuclei ◽  
Coulomb Scattering ◽  
Particle Scattering ◽  
Broad Level ◽  
Resonances In Scattering ◽  
Α Particles

In a previous paper (Devons 1939) the author has discussed the possibility of observing resonance phenomena in the scattering of α -particles by light nuclei, and the experimental results given there show that in general resonances in scattering are observable for light nuclei of atomic number less than about 12 and for α -particle energies about equal to or greater than the potential barrier height. In the case of the scattering by helium nuclei the classical coulomb scattering is very small, and therefore anomalies in the scattering due to excited states of Be 8 , the compound nucleus formed by He 4 and an α -particle, should be comparatively easy to detect. In addition no disintegration is possible with α -particles of the energies used (less than 8.5 MeV), so that if the nucleus Be 8 is formed in an excited state it can only dissociate into two α -particles, and hence the width of any level of Be 8 excited by α -particle scattering in helium will be due practically entirely to elastic scattering. The investigation of the excited states of Be 8 by means of the scattering of α -particles by helium nuclei has a particular interest since the existence of a broad level of Be 8 with an excitation energy of about 3 MeV above the ground state, which is capable of splitting up into two α -particles, is postulated to account for the results of several disintegration experiments.

Excited-State Dynamics in the RNA Nucleotide Uridine 5’-Monophosphate Investigated by Femtosecond Broadband Transient Absorption Spectroscopy

2019 ◽  
Author(s):  
Matthew M. Brister ◽  
Carlos Crespo-Hernández
Keyword(s):  
Excited State ◽  
Excited States ◽  
Ground State ◽  
Transient Absorption ◽  
Electronic Energy ◽  
Transient Absorption Spectroscopy ◽  
Electronic Relaxation ◽  
Vibrationally Excited ◽  
Excited State Dynamics ◽  
Π State

<p></p><p> Damage to RNA from ultraviolet radiation induce chemical modifications to the nucleobases. Unraveling the excited states involved in these reactions is essential, but investigations aimed at understanding the electronic-energy relaxation pathways of the RNA nucleotide uridine 5’-monophosphate (UMP) have not received enough attention. In this Letter, the excited-state dynamics of UMP is investigated in aqueous solution. Excitation at 267 nm results in a trifurcation event that leads to the simultaneous population of the vibrationally-excited ground state, a longlived <sup>1</sup>n<sub>O</sub>π* state, and a receiver triplet state within 200 fs. The receiver state internally convert to the long-lived <sup>3</sup>ππ* state in an ultrafast time scale. The results elucidate the electronic relaxation pathways and clarify earlier transient absorption experiments performed for uracil derivatives in solution. This mechanistic information is important because long-lived nπ* and ππ* excited states of both singlet and triplet multiplicities are thought to lead to the formation of harmful photoproducts.</p><p></p>

The Malleable Excited States of Benzothiadiazole Dyes and Investigation of their Potential for Photochemical Control

2019 ◽  
Author(s):  
Caroline C. Warner ◽  
andrea thooft ◽  
Bryan J. Lampkin ◽  
selin demirci ◽  
Brett VanVeller
Keyword(s):  
Excited State ◽  
Excited States ◽  
Polar Solvent ◽  
Nonpolar Solvent ◽  
Photochemical Degradation ◽  
Solvent Lead ◽  
Environmentally Sensitive

<p>A strategy to control the efficiency of a photocleavage reaction based on changing the nature of the excited state is presented. A novel class of photoactive compounds has been synthesized by combining the classical o-nitrobenzyl scaffold with an environmentally sensitive dye, 4-amino-nitrobenzothiazole. Irradiation in a polar solvent lead to an excited state that is inoperative for photochemistry whereas excitation in a nonpolar solvent lead to an excited state that is photochemically active. A photochemical degradation appears to be the preferred process in contrast to the intended photocleavage process.</p>

Excited State Tracking During the Relaxation of Coordination Compounds

2018 ◽  
Author(s):  
Juan Sanz García ◽  
Martial Boggio-Pasqua ◽  
Ilaria Ciofini ◽  
Marco Campetella
Keyword(s):  
Excited State ◽  
Excited States ◽  
Potential Energy Surfaces ◽  
Photochemical Reactions ◽  
Complex Nature ◽  
Electronic Excited States ◽  
Ruthenium Nitrosyl ◽  
State Tracking ◽  
Energy Surfaces ◽  
Electronic Wavefunction

<div>The ability to locate minima on electronic excited states (ESs) potential energy surfaces (PESs) both in the case of bright and dark states is crucial for a full understanding of photochemical reactions. This task has become a standard practice for small- to medium-sized organic chromophores thanks to the constant developments in the field of computational photochemistry. However, this remains a very challenging effort when it comes to the optimization of ESs of transition metal complexes (TMCs), not only due to the presence of several electronic excited states close in energy, but also due to the complex nature of the excited states involved. In this article, we present a simple yet powerful method to follow an excited state of interest during a structural optimization in the case of TMC, based on the use of a compact hole-particle representation of the electronic transition, namely the natural transition orbitals (NTOs). State tracking using NTOs is unambiguously accomplished by computing the mono-electronic wavefunction overlap between consecutive steps of the optimization. Here, we demonstrate that this simple but robust procedure works not only in the case of the cytosine but also in the case of the ES optimization of a ruthenium-nitrosyl complex which is very problematic with standard approaches.</div>

scholarly journals Heisenberg spin chain as a worldsheet coordinate for lightcone quantized string

2021 ◽  
Vol 2021 (2) ◽  
Author(s):  
Charles B. Thorn
Keyword(s):  
Energy Spectrum ◽  
Excited States ◽  
Spin Chain ◽  
Discrete Dynamical System ◽  
Heisenberg Spin ◽  
Free Fermions ◽  
Heisenberg Spin Chain ◽  
Delta Sigma ◽  
Special Cases ◽  
Quantized String

Abstract Although the energy spectrum of the Heisenberg spin chain on a circle defined by$$ H=\frac{1}{4}\sum \limits_{k=1}^M\left({\sigma}_k^x{\sigma}_{k+1}^x+{\sigma}_k^y{\sigma}_{k+1}^y+\Delta {\sigma}_k^z{\sigma}_{k+1}^z\right) $$ H = 1 4 ∑ k = 1 M σ k x σ k + 1 x + σ k y σ k + 1 y + Δ σ k z σ k + 1 z is well known for any fixed M, the boundary conditions vary according to whether M ∈ 4ℕ + r, where r = −1, 0, 1, 2, and also according to the parity of the number of overturned spins in the state, In string theory all these cases must be allowed because interactions involve a string with M spins breaking into strings with M1< M and M − M1 spins (or vice versa). We organize the energy spectrum and degeneracies of H in the case ∆ = 0 where the system is equivalent to a system of free fermions. In spite of the multiplicity of special cases, in the limit M → ∞ the spectrum is that of a free compactified worldsheet field. Such a field can be interpreted as a compact transverse string coordinate x(σ) ≡ x(σ) + R0. We construct the bosonization formulas explicitly in all separate cases, and for each sector give the Virasoro conformal generators in both fermionic and bosonic formulations. Furthermore from calculations in the literature for selected classes of excited states, there is strong evidence that the only change for ∆ ≠ 0 is a change in the compactification radius R0→ R∆. As ∆ → −1 this radius goes to infinity, giving a concrete example of noncompact space emerging from a discrete dynamical system. Finally we apply our work to construct the three string vertex implied by a string whose bosonic coordinates emerge from this mechanism.

scholarly journals Ground- and excited-state characteristics in photovoltaic polymer N2200

RSC Advances ◽  
2021 ◽  
Author(s):  
Guanzhao Wen ◽  
Xianshao Zou ◽  
Rong Hu ◽  
Jun Peng ◽  
Zhifeng Chen ◽  
...  
Keyword(s):  
Density Functional Theory ◽  
Excited State ◽  
Steady State ◽  
Excited States ◽  
Density Functional ◽  
Density Functional Theory Calculations ◽  
Time Dependent ◽  
Functional Theory ◽  
Time Resolved ◽  
Dependent Density

Ground- and excited-states properties of N2200 have been studied by steady-state and time-resolved spectroscopies as well as time-dependent density functional theory calculations.

scholarly journals Theoretical Electronic and Rovibrational Studies for Anions of Interest to the DIBs

2013 ◽  
Vol 9 (S297) ◽  
pp. 344-348 ◽  
Author(s):  
R. C. Fortenberry
Keyword(s):  
Excited State ◽  
Excited States ◽  
State Of The Art ◽  
Spectroscopic Constants ◽  
Coupled Cluster ◽  
Electronic Excitations ◽  
Electronically Excited States ◽  
Coupled Cluster Theory ◽  
Electronically Excited ◽  
Enolate Anion

AbstractThe dipole-bound excited state of the methylene nitrile anion (CH2CN−) has been suggested as a candidate carrier for a diffuse interstellar band (DIB) at 803.8 nm. Its corresponding radical has been detected in the interstellar medium (ISM), making the existence for the anion possible. This work applies state-of-the-art ab initio methods such as coupled cluster theory to reproduce accurately the electronic excitations for CH2CN− and the similar methylene enolate anion, CH2CHO−. This same approach has been employed to indicate that 19 other anions may possess electronically excited states, five of which are valence in nature. Concurrently, in order to assist in the detection of these anions in the ISM, work has also been directed towards predicting vibrational frequencies and spectroscopic constants for these anions through the use of quartic force fields (QFFs). Theoretical rovibrational work on anions has thus far included studies of CH2CN−, C3H−, and is currently ongoing for similar systems.

An acidity scale, [H+]hv, for proton quenching of excited states

1989 ◽  
Vol 67 (2) ◽  
pp. 227-238 ◽  
Author(s):  
J. A. Pincock ◽  
P. R. Redden
Keyword(s):  
Excited State ◽  
Fluorescence Quenching ◽  
Excited States ◽  
Benzyl Alcohols ◽  
Fluorescent Indicator ◽  
Quenching Of Fluorescence ◽  
Acidity Scale

An acidity scale for excited state protonation kinetics in 20% ethanol:80% aqueous sulfuric has been developed using 1-cyano-naphthalene as a fluorescent indicator. The utility of this new scale is demonstrated using the proton quenching of fluorescence of a variety of chromophores. These include 1- and 2-cyanonaphthalenes, 1- and 2-methoxynaphthalenes, benzyl alcohols, toluenes, and 2-vinylnaphthalene. Keywords: acidity scale, fluorescence quenching, excited state basicity.

Effects of extending the π-conjugation of the acetylide ligand on the photophysics and reverse saturable absorption of Pt(ii) bipyridine bisacetylide complexes

2016 ◽  
Vol 18 (41) ◽  
pp. 28674-28687 ◽  
Author(s):  
Taotao Lu ◽  
Chengzhe Wang ◽  
Levi Lystrom ◽  
Chengkui Pei ◽  
Svetlana Kilina ◽  
...  
Keyword(s):  
Excited State ◽  
Excited States ◽  
Substituent Effect ◽  
Excited State Absorption ◽  
Saturable Absorption ◽  
Reverse Saturable Absorption ◽  
Triplet Excited State ◽  
Near Ir ◽  
Terminal Substituent ◽  
Acetylide Ligand

Extending the acetylide ligand π-conjugation diminishes the terminal substituent effect on the lowest excited states, but expands the triplet excited-state absorption to the near-IR region.

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