Remediation of Cd(II) Metal Ion from Aqueous Systems by Using Calcium Alginate Modified (CAM)Acacia salignaandDelbergia sissoPods Composite Beads

2015 ◽  
Vol 50 (3) ◽  
pp. 354-364
Author(s):  
Garima Mahajan ◽  
Dhiraj Sud
Chemistry ◽  
2021 ◽  
Vol 3 (2) ◽  
pp. 672-686
Author(s):  
Louise Gallagher ◽  
Alanna Smith ◽  
Kevin Kavanagh ◽  
Michael Devereux ◽  
John Colleran ◽  
...  

Calcium alginate (CaALG) hydrogel beads and two sets of composite beads, formed from a combination of calcium alginate/propylene glycol alginate/human serum albumin (CaALG/PGA/HSA) and from calcium alginate with the quaternary ammonium salt, (3-(trimethoxysilyl)propyl)-octadecyldimethylammonium chloride (QA), (CaALG/QA), were prepared. Bovine serum albumin (BSA) was condensed with glutaraldehyde (GLA) to form a BSA/GLA hydrogel. The corresponding Ag+-containing gels of all of the above hydrogels were also formed, and slow leaching of the biocidal transition metal ion from the gels bestowed broad spectrum antimicrobial activity. In the absence of added Ag+, CaALG/QA was the only material to deliver marginal to moderate antibacterial and antifungal effects. The Ag+ impregnated hydrogel systems have the potential to maintain the antimicrobial properties of silver, minimising the risk of toxicity, and act as reservoirs to afford ongoing sterility.


Author(s):  
Mohammed Hachemaoui ◽  
Adel Mokhtar ◽  
Soumia Abdelkrim ◽  
Rachida Ouargli-Saker ◽  
Farouk Zaoui ◽  
...  

Materials ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 395 ◽  
Author(s):  
Roberto Torres-Caban ◽  
Carmen Vega-Olivencia ◽  
Luis Alamo-Nole ◽  
Daisy Morales-Irizarry ◽  
Felix Roman-Velazquez ◽  
...  

Calcium Alginate/Spent-Coffee-Grounds composite beads (CA-SCGs beads), which were made of two different proportions of alginate and spent-coffee-grounds (3:3 and 3:10), respectively, were used to adsorb Cu2+ in aqueous solution. These beads were compared with calcium alginate beads (CA beads) and spent-coffee-grounds (SCGs) in terms of adsorption capacity and rate of adsorption. The experiments were carried out at an initial pH of 4 at 30 °C with initial concentrations of Cu2+ from 10 ppm to 100 ppm. Equilibrium data was fitted with Langmuir, Freundlich and Sips models, and a pseudo-second-order kinetic equation. The Sips model showed the best correlation with the experimental values. CA-SCGs (3:3) beads showed a faster adsorption rate versus the CA beads. Also, CA-SCGs (3:3) beads showed a larger capacity of adsorption according to the Sips model, but not in the Langmuir model. FT-IR spectra and SEM images were taken for characterization. This study has shown that the CA-SCGs (3:3) beads have a synergistic effect, combining the capacity of adsorption of CA beads with the kinetics of the SCGs. The CA-SCGs beads have proven to be an effective adsorbent of Cu2+. Therefore, they can provide a use for the SCGs; which are considered pollutants in landfills.


2017 ◽  
Vol 83 ◽  
pp. 294-305 ◽  
Author(s):  
Nassima Djebri ◽  
Nadia Boukhalfa ◽  
Mokhtar Boutahala ◽  
Didier Hauchard ◽  
Nacer-Eddine Chelali ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4728
Author(s):  
Lăcrămioara Rusu ◽  
Cristina-Gabriela Grigoraș ◽  
Andrei-Ionuț Simion ◽  
Elena Mirela Suceveanu ◽  
Daniela Șuteu ◽  
...  

Cephalexin (CPX) is recognized as a water pollutant, and it has been listed in a number of countries with a risk factor greater than one. Herein, the present work focused on the synthesis, characterization and biosorption capacity evaluation of Saccharomyces cerevisiae immobilized in calcium alginate as a biosorbent to remove CPX from aqueous solutions. Biosorbent was characterized by SEM and FTIR techniques. Batch biosorption experiments were conducted in order to evaluate the effect of the initial pH, biosorbent dose and CPX initial concentration. The removal efficiency, in considered optimal conditions (pH = 4, CPX initial concentration = 30 mg/L, biosorbent dose = 1 g/L) was 86.23%. CPX biosorption was found to follow the pseudo–second-order kinetics. The equilibrium biosorption data were a good fit for the Langmuir model with correlation coefficient of 0.9814 and maximum biosorption capacity was 94.34 mg/g. This study showed that the synthesized biosorbent by immobilization technique is a low-cost one, easy to obtain and handle, eco-friendly, with high feasibility to remove CPX antibiotic from aqueous solution. The findings of this study indicate that the biosorbents based on microorganisms immobilized on natural polymers have the potential to be applied in the treatment of wastewater.


Author(s):  
Thato Masilompane ◽  
Nhamo Chaukura ◽  
Ajay K. Mishra ◽  
Shivani B. Mishra ◽  
Bhekie B. Mamba
Keyword(s):  

2013 ◽  
Vol 2013 ◽  
pp. 1-11 ◽  
Author(s):  
S. Sugashini ◽  
K. M. Meera Sheriffa Begum

The objective of this present study is the optimization of process parameters in adsorption of Cr(VI) ions by ethylamine modified chitosan carbonized rice husk composite beads (EAM-CCRCBs) using response surface methodology (RSM) and continuous adsorption studies of Cr(VI) ions by ethylamine modified chitosan carbonized rice husk composite beads (EAM-CCRCBs). The effect of process variables such as initial metal ion concentration, adsorbent dosage and pH were optimized using RSM in order to ensure high adsorption capacity at low adsorbent dosage and high initial metal ion concentration of Cr(VI) in batch process. The optimum condition suggested by the model for the process variable such as adsorbent dosage, pH and initial metal ion concentration was 0.14 g, 300 mg/L and pH2 with maximum removal of 99.8% and adsorption capacity of 52.7 mg/g respectively. Continuous adsorption studies were conducted under optimized initial metal ion concentration and pH for the removal of Cr(VI) ions using EAM-CCRCBs. The breakthrough curve analysis was determined using the experimental data obtained from the continuous adsorption. Continuous adsorption modelling such as bed depth service model and Thomson model were established by fitting it with experimental data.


Author(s):  
Dihia Aberkane ◽  
Chafika Meziti ◽  
Soraya Ihaddaden ◽  
Abdelhamid Boukerroui ◽  
Benoît Cagnon

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