Effect of fiber surface modifications on the properties of snake grass fiber reinforced polypropylene bio-composites

Author(s):  
Haydar U. Zaman ◽  
Ruhul A. Khan
2021 ◽  
pp. 096739112110230
Author(s):  
Adane Dagnaw Gudayu ◽  
Leif Steuernagel ◽  
Dieter Meiners ◽  
Rotich Gideon

Dynamic mechanical analysis (DMA) is an essential procedure for characterizing the performance of composites and effectively simulate with the real-world applications. This research work aims to characterize the dynamic mechanical (DM) properties of sisal fiber reinforced polyethylene terephthalate (PET) composites as a factor of fiber content and fiber surface modification. The effect of elevated processing temperature (>260°C) on the thermal degradation of sisal fibers is also analyzed. To study the effect of sisal fiber loading, PET composite specimens; one with 25% by weight fraction of raw sisal fiber (w/w), abbreviated as 25% RSC and the other with 40% by weight fraction (w/w) of raw sisal fiber, hereafter abbreviated as 40% RSC, were prepared by injection molding. Similarly, to analyze the impact of fiber surface modifications, PET composite samples containing 40% by weight fraction (w/w) of alkali-treated sisal, hereafter abbreviated as (40% Al-SC), and 40% by weight fraction (w/w) of a combined alkali/acetylation-treated sisal, hereafter abbreviated as (40% Al-ASC), were prepared. It was found that the fiber volume fraction and fiber surface modifications affected the DM properties of the produced composites. The improved storage module and glass transition temperature (Tg) with minimized damping has been demonstrated by increasing fiber content. With the same 40% fiber content, the composites produced from modified fibers enhanced the storage modulus and Tg values. However, with increasing temperature, the storage modulus decreased, the loss modulus increased, and the damping factor increased with composites containing higher fiber content and surface modified fibers. This indicates the low thermal stability of the sisal fiber and the interface damage at elevated temperatures.


2014 ◽  
Vol 906 ◽  
pp. 167-177 ◽  
Author(s):  
Hou Lei Gan ◽  
Lei Tian ◽  
Chang Hai Yi

Abstract: The Interface of sisal fiber which was treated by using alkali, potassium permanganate, atmospheric plasma and silane reinforced polypropylene composites were investigated by single fiber pull-out testes and surface morphology were studied. The results indicated that the morphological changes observed on the sisal fiber surface were obviously evident. Untreated, permanganate and plasma treated sisal fiber reinforced PP show a stable debonding process. Silane treated sisal fiber reinforced PP show an unstable debonding process. Single fiber pull-out tests indicated that the IFSS value was in the order of FIB < FIBKMnO4 < FIBP < FIBKH-550 < FIBKH-570. As can be seen from surface morphology of pull-out fiber, a little of PP resin was adhered to the pull-out FIB, FIBKMnO4, FIBP of sisal fiber. In contrast, PP resin at the surface of pull-out fiber was flaked off and sisal fibril was drawn out from sisal fiber were observed from pull-out fibers of FIBKH-550 and FIBKH-570.


Polymers ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1486 ◽  
Author(s):  
Wojciech Ignaczak ◽  
Anne Ladegaard Skov ◽  
Miroslawa El Fray

The aim of this work was to study the interfacial behavior of basalt-fiber-reinforced thermoplastic blends of polypropylene and poly(butylene terephthalate) (PP/PBT). We examined the effect of two compatibilizers and two basalt fiber (BF) sizings: commercial (REF) and experimental (EXP). Differential scanning calorimetry was used to assess the influence of BFs on the phase structure of obtained composites. Furthermore, dielectric relaxation spectroscopy was used for the first time to non-destructively study the interfacial adhesion within an entire volume of BF-reinforced composites by assessing the α relaxation, DC conductivity, and Maxwell–Wagner–Sillars (MWS) polarization. The fiber–matrix adhesion was further investigated using the Havriliak–Negami model. Using complex plane analysis, the dielectric strength, which is inversely related to the adhesion, was calculated. The composites reinforced with EXP fibers showed significantly lower values of dielectric strength compared to the REF fibers, indicating better adhesion between the reinforcement and blend matrix. Static bending tests also confirmed improved fiber adhesion with EXP fibers, while also suggesting a synergistic effect between compatibilizer and sizing in enhancing interfacial properties. Thus, we conclude that substantially improved adhesion of PP/PBT BF-reinforced composites is the result of mutual interactions of functional groups of blend matrix, mostly from blend compatibilizer, and fiber surface due to sizing.


2017 ◽  
Vol 51 (28) ◽  
pp. 3909-3922 ◽  
Author(s):  
Priyadarshi Tapas Ranjan Swain ◽  
Sandhyarani Biswas

The present paper discovers the effect of ceramic filler inclusion on physico-mechanical and water absorption behaviour of untreated and chemically treated (alkali and benzoyl chloride treated) bi-directional jute natural-fiber-reinforced epoxy composites. In practice, the major drawbacks of using natural fibers are their high degree of moisture absorption and poor dimensional stability. Currently, chemical treatments are able to induce fiber modifications that increase their resistance when utilized in composite products. Jute fibers were subjected to various chemical modifications to improve the interfacial bonding with the matrix. In this study, an analysis has been carried out to make pre-treated jute fiber (10, 20, 30 and 40 wt.%) and different filler content (5 and 10 wt.%) with epoxy-based composites. A comparative study of all the untreated jute/aluminium oxide based hybrid composites with chemically treated jute/aluminium oxide based hybrid composites was carried out. The investigational result reveals that chemically treated composites considerably improved the mechanical properties of the composite. The maximum water absorption resistance and strength properties were found with benzoyl chloride-treated fiber-reinforced composite. Lastly, the surface morphology of fractured surfaces after tensile and flexural testing is studied using scanning electron microscope.


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