A variable F-factor to explain changes in base cation concentrations as a function of strong acid deposition

1990 ◽  
Vol 24 (1) ◽  
pp. 146-149 ◽  
Author(s):  
D. F. Brakke ◽  
A. Henriksen ◽  
S. A. Norton
2013 ◽  
Vol 116 (1-3) ◽  
pp. 119-130 ◽  
Author(s):  
Andrew L. Robison ◽  
Todd M. Scanlon ◽  
Bernard J. Cosby ◽  
James R. Webb ◽  
James N. Galloway

1993 ◽  
Vol 50 (2) ◽  
pp. 258-268 ◽  
Author(s):  
Richard F. Wright ◽  
Erik Lotse ◽  
Arne Semb

At Risdalsheia (southern Norway), an ongoing catchment-scale acid-exclusion experiment has been conducted since 1984 as part of the RAIN project (Reversing Acidification In Norway). Acid precipitation is collected on a 1200-m2 transparent roof, treated by ion exchange, sea salts readded, and reapplied as clean rain beneath the roof Up to 1990 annual surveys of soil chemistry have revealed no significant trends. The chemical composition of runoff has changed: sulfate decreased from about 111 μeq/L in 1984 to 38 μeq/L in 1992 and nitrate from about 33 to 5 μeq/L. Base cations decreased and alkalinity increased over the 8-yr period from −88 to −29 μeq/L to compensate for this change in strong acid anions. Much of the alkalinity change is due to the increased role of organic anions. The results fit an empirical nomograph relating alkalinity, base cations, and strong acid anions and a new empirical nomograph relating alkalinity, H+, and total organic carbon. The acid-exclusion experiment provides the first catchment-scale evidence for the reversibility of nitrogen saturation; RAIN results corroborate field observations of changes in surface water chemistry in response to reduced acid deposition as well as process-oriented, conceptual acidification models.


Chemosphere ◽  
2019 ◽  
Vol 226 ◽  
pp. 149-158
Author(s):  
Dai Dan ◽  
Yu Tao ◽  
Deng Yixiang ◽  
Sun Fuhong ◽  
Zhao Jian ◽  
...  

1984 ◽  
Vol 41 (11) ◽  
pp. 1664-1677 ◽  
Author(s):  
Bruce D. LaZerte ◽  
Peter J. Dillon

Anthropogenic acid deposition has been implicated in the acidification of surface waters of central Ontario and elsewhere. However, alternative sources of acidity have been proposed, including (i) the release of protons and their accompanying acid anions by soils (e.g. organic acids) and (ii) the exchange of internally generated protons for the cations of atmospherically deposited neutral salts (e.g. sea salts). We show that for a typical acidified catchment in central Ontario the first hypothesis is not important during periods of high discharge or on an annual basis. As most of the neutral salts deposited on inland areas are sulphate and nitrate of anthropogenic origin, any acidity generated via the second mechanism can be reduced by reducing the emission of the salts. A third and alternative hypothesis is that deposition of strong acid alters only the balance between humic anions and sulphate in runoff waters, but not pH; we have shown this to be incorrect using catchments from the Sudbury region of Ontario where rates of acid deposition have recently declined. We conclude that in central Ontario, acidic deposition derived from anthropogenic SO2 sources is the primary causal factor in recent lake acidification, and that a reduction in the anthropogenic emissions affecting this area will result in a decrease in lake acidity.


2002 ◽  
Vol 6 (5) ◽  
pp. 833-848 ◽  
Author(s):  
S. A. Watmough ◽  
P. J. Dillon

Abstract. The impact of acid deposition and tree harvesting on three lakes and their representative sub-catchments in the Muskoka-Haliburton region of south-central Ontario was assessed using a critical loads approach. As nitrogen dynamics in forest soils are complex and poorly understood, for simplicity and to allow comparison among lakes and their catchments, CLs (A) for both lakes and forest soils were calculated assuming that nitrate leaching from catchments will not change over time (i.e. a best case scenario). In addition, because soils in the region are shallow, base cation weathering rates for the representative sub-catchments were calculated for the entire soil profile and these estimates were also used to calculate critical loads for the lakes. These results were compared with critical loads obtained by the Steady State Water Chemistry (SSWC) model. Using the SSWC model, critical loads for lakes were between 7 and 19 meq m-2yr-1 higher than those obtained from soil measurements. Lakes and forests are much more sensitive to acid deposition if forests are harvested, but two acid-sensitive lakes had much lower critical loads than their respective forested sub-catchments implying that acceptable acid deposition levels should be dictated by the most acid-sensitive lakes in the region. Under conditions that assume harvesting, the CL (A) is exceeded at two of the three lakes and five of the six sub-catchments assessed in this study. However, sulphate export from catchments greatly exceeds input in bulk deposition and, to prevent lakes from falling below the critical chemical limit, sulphate inputs to lakes must be reduced by between 37% and 92% if forests are harvested. Similarly, sulphate leaching from forested catchments that are harvested must be reduced by between 16 and 79% to prevent the ANC of water draining the rooting zone from falling below 0 μeq l-1. These calculations assume that extremely low calcium leaching losses (9–27 μeq l-1) from forest soils can be maintained without any decrease in forest productivity. Calcium concentrations in the three lakes have decreased by between ∼10 and 25% over the past 20 years and calculations assume that calcium concentrations in lakes can fall to around 30% of their current values without any harmful effects on biota. Both these assumptions require urgent investigation. Keywords: acid deposition, calcium, critical loads, forests, harvesting, lakes


Soil Systems ◽  
2021 ◽  
Vol 5 (1) ◽  
pp. 16
Author(s):  
Scott W. Bailey ◽  
Robert P. Long ◽  
Stephen B. Horsley

Reductions in exchangeable calcium and magnesium and increase in exchangeable aluminum concentrations have been shown in soils impacted by acid deposition, including at four sites on the Allegheny Plateau, PA, USA, sampled in 1967 and 1997 during a period of peak deposition. We repeated sampling at these sites in 2017 to evaluate changes in soils during the more recent period when there has been a strong decline in acid deposition. The uppermost horizons, including the Oa and A horizons where humified organic matter transitions to mineral soil, were thicker, had higher concentrations of organic carbon and exchangeable calcium and magnesium, and lower concentrations of exchangeable aluminum in 2017 compared to 1997, approximating values measured in 1967. Below the Oa/A horizons, 2017 soil chemistry was more similar to the 1997 results, with some reduction of Ca in the recent measurements. These results suggest recovery of base cation–aluminum balance in surface horizons and may indicate a reduction of aluminum mobilization and increased efficiency of vegetation recycling of nutrients with decreased acid anion concentrations. These changes are consistent with a partial recovery from acid deposition. However, the increase in humified soil organic matter may also be affected by coincident increases in temperature and soil moisture.


2009 ◽  
Vol 6 (3) ◽  
pp. 3917-3945
Author(s):  
L. Rapp ◽  
K. Bishop

Abstract. As acid deposition decreases, uncertainties in methods for calculating critical loads become more important when judgements have to be made about whether or not further emission reductions are needed. An important aspect of one type of model that has been used to calculate surface water critical loads is the empirical F-factor which estimates the degree to which acid deposition is neutralised before it reaches a lake at any particular point in time relative to the pre-industrial, steady-state water chemistry conditions. In this paper we will examine how well the empirical F-functions are able to estimate pre-industrial lake chemistry as lake chemistry changes during different phases of acidification and recovery. To accomplish this, we use the dynamic, process-oriented biogeochemical model SAFE to generate a plausible time series of annual runoff chemistry for ca 140 Swedish catchments between 1800 and 2100. These annual hydrochemistry data are then used to generate empirical F-factors that are compared to the "actual" F-factor seen in the SAFE data for each lake and year in the time series. The dynamics of the F-factor as catchments acidify, and then recover are not widely recognised. Our results suggest that the F-factor approach worked best during the acidification phase when soil processes buffer incoming acidity. However, the empirical functions for estimating F from contemporary lake chemistry are not well suited to the recovery phase when the F-factor turns negative due to recovery processes in the soil. Therefore, the empirical estimates of the F-factor are a significant source of uncertainty in the estimate of surface water critical loads and related calculations for quantifying lake acidification status, especially now that acid deposition has declined across large areas of Europe and North America.


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