RAIN Project: Results after 8 Years of Experimentally Reduced Acid Deposition to a Whole Catchment

1993 ◽  
Vol 50 (2) ◽  
pp. 258-268 ◽  
Author(s):  
Richard F. Wright ◽  
Erik Lotse ◽  
Arne Semb

At Risdalsheia (southern Norway), an ongoing catchment-scale acid-exclusion experiment has been conducted since 1984 as part of the RAIN project (Reversing Acidification In Norway). Acid precipitation is collected on a 1200-m2 transparent roof, treated by ion exchange, sea salts readded, and reapplied as clean rain beneath the roof Up to 1990 annual surveys of soil chemistry have revealed no significant trends. The chemical composition of runoff has changed: sulfate decreased from about 111 μeq/L in 1984 to 38 μeq/L in 1992 and nitrate from about 33 to 5 μeq/L. Base cations decreased and alkalinity increased over the 8-yr period from −88 to −29 μeq/L to compensate for this change in strong acid anions. Much of the alkalinity change is due to the increased role of organic anions. The results fit an empirical nomograph relating alkalinity, base cations, and strong acid anions and a new empirical nomograph relating alkalinity, H+, and total organic carbon. The acid-exclusion experiment provides the first catchment-scale evidence for the reversibility of nitrogen saturation; RAIN results corroborate field observations of changes in surface water chemistry in response to reduced acid deposition as well as process-oriented, conceptual acidification models.

Author(s):  
Richard F. Wright ◽  
Michael Hauhs

SynopsisAs empirical relationships between acidic deposition and its effects on soils and surface waters have become increasingly understood, the focus of attention has shifted to the reversal of acidification in response to decreased amounts of acidic deposition.Recent decreases in acidic deposition, in both North America and parts of Europe, have initiated the reversal of acidification and the recovery of impacted ecosystems. Reversal has also been investigated in large-scale experiments with whole ecosystems. Predictive models can account for much of this empirical and experimental data, at least at the catchment scale, over periods of years.Discrepancies between observed and predicted effects are attributable in part to the increasingly important role of nitrogen in soil and water acidification. ‘Nitrogen saturation’ threatens to offset the incipient recovery following decreases in SO2 emissions. Future climate change might further exacerbate the problem by increasing the rate of mineralisation of soil organic matter and releasing stored nitrogen.


2012 ◽  
Vol 163 (9) ◽  
pp. 374-382 ◽  
Author(s):  
Sabine Braun ◽  
Walter Flückiger

Soil acidification in permanent observation plots Soil acidification is followed in Swiss forest observation plots differing in soil chemistry. Soil solution samples from suction cups show clearly increasing soil acidification between 1998 and 2011, although the rate has declined in many cases during the last five years. The most rapid decline is currently observed in plots with medium to high base saturation. Nitrogen addition experiments and time series after thinning out forests confirm the important role of nitrogen input and nitrate leaching for the acidification process. It is suggested that the slowdown of acidification since 2003 has several reasons: reaching of the aluminium buffer range in the very acidic plots, decreased nitrate leaching in a series of dry years, reduction of acid deposition.


1998 ◽  
Vol 2 (4) ◽  
pp. 385-397 ◽  
Author(s):  
R. F. Wright ◽  
B. A. Emmett ◽  
A. Jenkins

Abstract. Nitrogen processes are now included in a new version of MAGIC (version 7), a process-oriented catchment-scale model for simulating runoff chemistry. Net retention of nitrogen (N) is assumed to be controlled by plant uptake and the carbon/nitrogen (C/N) ratio of soil organic matter, the latter as evidenced by empirical data from forest stands in Europe. The ability of this version of MAGIC 7 to simulate and predict inorganic N concentrations in runoff is evaluated by means of data from whole-ecosystem manipulation experiments at Aber, Wales, UK, (nitrogen addition as part of the NITREX project) and Risdalsheia, Norway (exclusion of acid deposition as part of the RAIN project and climate change as part of the CLIMEX project). MAGIC 7 simulated the changes in N leaching satisfactorily as well as changes in base cations and acid neutralising capacity observed at these two sites. MAGIC 7 offers a potential tool for regional assessments and scenario studies of the combined effects of acid deposition, land-use and climate change.


Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 4083
Author(s):  
Heming Jiang ◽  
Tian-Yu Sun

A computational study on the origin of the activating effect for Pd-catalyzed directed C–H activation by the concerted metalation-deprotonation (CMD) mechanism is conducted. DFT calculations indicate that strong acids can make Pd catalysts coordinate with directing groups (DGs) of the substrates more strongly and lower the C–H activation energy barrier. For the CMD mechanism, the electrophilicity of the Pd center and the basicity of the corresponding acid ligand for deprotonating the C–H bond are vital to the overall C–H activation energy barrier. Furthermore, this rule might disclose the role of some additives for C–H activation.


2021 ◽  
Author(s):  
◽  
Tapuwa Marapara

<p>During the last two decades there has been increasing interest in the role of forests and wetlands as flood mitigating tools due to growing concerns regarding the sustainability of many traditional engineering flood defences such as dykes, sea walls and dams. In forests, the role is facilitated by the interaction between trees, soil and water. Specifically trees reduce surface runoff and prevent flooding through increased evapotranspiration and canopy interception and enhance physical and hydraulic properties of soil that are critical for the absorption and retention of flood waters by the soil. It is increasingly realised that the answer to flood mitigation is not a blanket recommendation to “plant trees”. This is because the role of trees varies spatially and temporally as a function of climate, topography, rainfall properties, soil type and condition, catchment scale and geology, among others. For example, where trees are present in wetlands, particularly forested wetlands, the mechanisms by which trees interact with soil and water are similar to that in forests but because of a high water table, the impact of trees may be reduced. Therefore, the mere presence of forests and forested wetlands will not necessarily deliver flood risk management.  The purpose of this study was to explore the effectiveness of trees as flood mitigating tools under various bio-geo climatic factors in forests and forested wetland environments. Three forms of investigation were followed to fulfil this purpose.  A detailed literature review was carried out to assess the role of trees and forests as flood mitigation tools under changing climate, topography, species type, rainfall properties, soil type and condition, catchment scale and geology. A field experiment was carried out to collect data and analyse the effect of trees on soil physical and hydraulic properties that include bulk density, saturated hydraulic conductivity, soil organic carbon, soil moisture content, matric potential and soil moisture retention in a previously forested wetland undergoing restoration in New Zealand. A spatially explicit decision support tool, the Land Use Capability Indicator (LUCI) was then used to determine appropriate areas where intervention can be targeted to optimise the role of trees as flood mitigating tools in previously forested wetlands undergoing restoration.  The detailed review identified a major data gap in the role of trees under hydric conditions (high water table), along with uncertainties on their effectiveness in large catchments (>˜40 km²) and in extreme rainfall events. The field experiment provided the first set of soil hydrology data from an ephemeral wetland in New Zealand showing the benefits of newly established trees in improving hydraulic conductivity of soils. The soil hydrology data is a useful baseline for continuous monitoring of the forested wetlands undergoing restoration. The use of the Land Use Capability Indicator was its first application for the optimisation of flood mitigation in a forested wetland. Its suggested target areas are not necessarily conducive for survival of some tree species, although if suitable species are established, flood risk mitigation could be maximised. Further research on what native species are best for what conditions and in what combinations is recommended, to increase survival in the proposed target areas.</p>


2021 ◽  
Author(s):  
Jeffrey Munroe

&lt;p&gt;The concept of &amp;#8220;Vineyard Geological Identity&amp;#8221; (VGI) was introduced (Ferretti, 2019: &lt;em&gt;Catena&lt;/em&gt;) in recognition of the role of geologic setting in contributing to fertility, hydrology, and other important aspects of vineyard soils.&amp;#160; This study applied the VGI concept to two vineyards in the Champlain Valley of Vermont, USA where a burgeoning wine-making industry has been catalyzed by the development of French-American hybrid grape variety capable of surviving cold winters and bringing fruit to ripeness in relatively cool summers.&amp;#160; The vineyards studied here, &amp;#8220;LP&amp;#8221; and &amp;#8220;SV&amp;#8221;, both produce the hybrid grape known as &amp;#8220;Marquette&amp;#8221;, are at a similar elevation (~100 m), have a similar macroclimate (MAT ~7 &amp;#176;C, MAP ~ 850 mm, ~1400 GDD), and were inundated by proglacial Lake Vermont during deglaciation (~15,000 years ago).&amp;#160; Notable differences between the sites are the lithology of the underlying bedrock (Ordovician carbonate at LP, and Cambrian quartzite at SV), and the fact that the SV site was located at the edge of a marine embayment at the Pleistocene/Holocene transition after Lake Vermont drained.&amp;#160; The hypothesis tested was the prediction that despite their broadly similar physical settings and geologic histories, the VGI of the two vineyards would vary as a result of differences in their underlying bedrock and the soil parent materials at these settings.&amp;#160; Samples were collected at depths of 25, 50, 75, and 100 cm from 10 locations within the Marquette block at in each vineyard.&amp;#160; All samples were evaluated for grain size distribution (with the hydrometer method and a laser scattering analyzer), thermogravimetric analysis (from 25 to 1000 &amp;#176;C), pH, nutrient status, base saturation, and cation exchange capacity.&amp;#160; The deepest samples were also analyzed for mineralogy (with XRD) and major element chemistry (with XRF).&amp;#160; Results confirm the tested hypothesis.&amp;#160; Most base cations are significantly more abundant in the samples from the LP site (reflecting the underlying carbonate bedrock), and the LP site is significantly finer grained (reflecting its former deepwater location in Lake Vermont).&amp;#160; Conversely, at the SV vineyard Na is significantly more abundant and samples are significantly coarser, consistent with the former location of this site in the nearshore zone of a marine embayment.&amp;#160; In future work these results could be used as a physical foundation for evaluating the possible role of terroir in controlling aspects of the flavors expressed in Marquette wines from these two vineyards.&lt;/p&gt;


Water ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 1071 ◽  
Author(s):  
Remi Valois ◽  
Nicole Schaffer ◽  
Ronny Figueroa ◽  
Antonio Maldonado ◽  
Eduardo Yáñez ◽  
...  

High-altitude peatlands in the Andes, i.e., bofedales, play an essential role in alpine ecosystems, regulating the local water balance and supporting biodiversity. This is particularly true in semiarid Chile, where bofedales develop near the altitudinal and hydrological limits of plant life. The subterranean geometry and stratigraphy of one peatland was characterized in north-central Chile using Electrical Resistivity Tomography (ERT), Ground Penetrating Radar (GPR) and core extraction. Two sounding locations, two transversal and one longitudinal profile allowed a 3D interpretation of the bofedal’s internal structure. A conceptual model of the current bofedal system is proposed. Geophysical results combined with porosity measurements were used to estimate the bofedal water storage capacity. Using hydrological data at the watershed scale, implications regarding the hydrological role of bofedales in the semiarid Andes were then briefly assessed. At the catchment scale, bofedal water storage capacity, evapotranspiration losses and annual streamflow are on the same order of magnitude. High-altitude peatlands are therefore storing a significant amount of water and their impact on basin hydrology should be investigated further.


1998 ◽  
Vol 2 (4) ◽  
pp. 555-562 ◽  
Author(s):  
B. L. Skjelkvåle ◽  
R. F. Wright ◽  
A. Henriksen

Abstract. Surveys of 485 lakes in Norway conducted in 1986 and again in 1995 reveal widespread chemical recovery from acidification. Sulphate concentrations in lakes have decreased by 40% in acidified areas in southern Norway. This decrease has been compensated about 25% by decreases in concentrations of base cations and of 75% by increased Acid Neutralising Capacity (ANC). The increased ANC in turn reflects lower concentrations of acidic cations Aluminum (ALn+) and Hydrogen (H+). A sub-set of 78 of the 485 lakes sampled yearly between 1986 and 1997 shows that, at first most of the decrease in non-marine sulphate (SO4*) was compensated by a decrease in base cations, such that ANC remained unchanged. Then as SO4* continued to decrease, the concentrations of non- marine calcium and magnesium ((Ca+Mg)*) levelled out. Consequently, ANC increased, and H+ and Aln+ started to decrease. In eastern Norway, this shift occurred in 1989–90, and came slightly later in southern and western Norway. Similar shifts in trends in about 1991–92 can also be seen in the non-acidified areas in central and northern Norway. This shift in trends is not as pronounced in western Norway, perhaps because of the confounding influence of sea-salt episodes on water chemistry. This is the first documented national-scale recovery from acidification due to reduced acid deposition. Future climate warming and potentially increased N-leaching can counteract the positive trends in recovery from acidification.


Water ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 1824 ◽  
Author(s):  
Jessica Driscoll ◽  
Thomas Meixner ◽  
Noah Molotch ◽  
Ty Ferre ◽  
Mark Williams ◽  
...  

A method for quantifying the role of dynamic storage as a physical buffer between snowmelt and streamflow at the catchment scale is introduced in this paper. The method describes a quantitative relation between hydrologic events (e.g., snowmelt) and responses (e.g., streamflow) by generating event-response ellipses that can be used to (a) characterize and compare catchment-scale dynamic storage processes, and (b) assess the closure of the water balance. Event-response ellipses allow for the role of dynamic, short-term storage to be quantified and compared between seasons and between catchments. This method is presented as an idealization of the system: a time series of a snowmelt event as a portion of a sinusoidal wave function. The event function is then related to a response function, which is the original event function modified mathematically through phase and magnitude shifts to represent the streamflow response. The direct relation of these two functions creates an event-response ellipse with measurable characteristics (e.g., eccentricity, angle). The ellipse characteristics integrate the timing and magnitude difference between the hydrologic event and response to quantify physical buffering through dynamic storage. Next, method is applied to eleven snowmelt seasons in two well-instrumented headwater snowmelt-dominated catchments with known differences in storage capacities. Results show the time-period average daily values produce different event-response ellipse characteristics for the two catchments. Event-response ellipses were also generated for individual snowmelt seasons; however, these annual applications of the method show more scatter relative to the time period averaged values. The event-response ellipse method provides a method to compare and evaluate the connectivity between snowmelt and streamflow as well as assumptions of water balance.


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