Silane coupling agent with amine group grafted nano/micro-glass fiber as novel toughener for epoxy resin: fabrication and mechanical properties

2020 ◽  
Vol 27 (12) ◽  
pp. 1085-1100 ◽  
Author(s):  
Cuong Manh Vu ◽  
Quang-Vu Bach ◽  
Le Xuan Duong ◽  
Nguyen Viet Thai ◽  
Vu Dinh Thao ◽  
...  
2017 ◽  
Vol 25 (1) ◽  
pp. 23-28 ◽  
Author(s):  
Jiuqiang Song ◽  
Yan Qin ◽  
Jia Chen ◽  
Siwen Qin

In this paper, a continuous glass fiber-reinforced polypropylene prepreg was prepared by fiber treatment with a silane coupling agent and MAH-g-PP resin. Continuous glass fiber-reinforced polypropylene sheets were made from prepreg and PP mats by hot-pressing; they displayed exceptional performance. This paper studies the effects of maleic anhydride grafting on the polypropylene crystallinity and MAH-g-PP content in the prepreg, and the mechanical properties of the composites. The results showed that modifying PP with maleic anhydride decreased the tacticity of the polypropylene molecular chain, which reduced the crystallinity and melting point. An excellent interface formed between the polypropylene and fiber after the glass fiber was treated with a silane coupling agent and MAH-g-PP resin. The mechanical properties of the polymer materials displayed more favorable properties as MAH-g-PP content increased; the ideal MAH-g-PP content was 50%.


2018 ◽  
Vol 2 (1) ◽  
pp. 29-35
Author(s):  
Widya Puspita Sari ◽  
Siti Sunarintyas ◽  
Nuryono Nuryono

E-glass fiber merupakan fiber reinforcement yang sering digunakan di kedokteran gigi karena berikatan baik dengan polimer melalui silane coupling agent, meningkatkan kekuatan mekanis dan tidak sensitif terhadap kelembaban. Ketersediaan E-glass fiber dental di Indonesia terbatas dengan harga relatif mahal. Glass fiber non dental banyak tersedia di Indonesia dengan harga terjangkau, yang biasa digunakan pada pembuatan panel gypsum dan komponen otomotif. Tujuan penelitian ini adalah mengetahui pengaruh komposisi glass fiber non dental terhadap kekuatan fleksural fiber reinforced composites. Bahan yang digunakan dalam penelitian ini adalah E-glass fiber dental (Fiber-splint, Polydentia SA, Switzerland), glass fiber non dental A (LT, China), B (CMAX, China) dan C (HJ, China), flowable composite (CharmFil Flow, Denkist, Korea) dan silane coupling agent (Monobond S, Ivoclar Vivadent, Liechtenstein). Subjek dibagi dalam 5 kelompok: tanpa fiber, E-glass fiber dental, glass fiber non dental A, B dan C . Uji kekuatan fleksural berdasarkan ISO 10477. Hasil yang diperoleh dianalisis menggunakan ANAVA satu jalur. Hasil penelitian menunjukkan rerata kekuatan fleksural (MPa) terendah pada kelompok tanpa fiber (126,18±5,21) dan tertinggi pada kelompok glass fiber non dental A (208,03±8,32). Hasil ANAVA satu jalur menunjukkan pengaruh bermakna dari komposisi fiber terhadap kekuatan fleksural (α < 0,05). Kesimpulan penelitian: Kandungan SiO2, Al2O3 dan alkali tanah oksida (MgO dan CaO) yang tinggi pada glass fiber meningkatkan kekuatan fleksural dari fiber reinforced composites.


MICC 90 ◽  
1991 ◽  
pp. 356-360
Author(s):  
G. O. Eremenko ◽  
M. N. Larichev ◽  
I. O. Leypunsky ◽  
A. S. Orlichenko ◽  
V. G. Krasovsky ◽  
...  

2012 ◽  
Vol 268-270 ◽  
pp. 127-133
Author(s):  
Chen Zheng ◽  
Yan Yan Xu ◽  
Takahiko Kawai ◽  
Shin-ichi Kuroda

In order to improve the properties and the processability of kenaf fiber (KF) / polystyrene (PS) composites, the newly synthesized polymeric silane coupling agent (CA) was utilized and evaluated. KFs were reacted with CA in the melt system and in the solvent system. The composites reinforced by the modified KF showed enhanced mechanical properties compared with those reinforced by the unmodified KF. The effect was especially remarkable when the KF was modified with CA in the solvent system. As the CA content increases, the surface of KF recovered from the composites showed the higher Si / C ratio indicating the good reaction between KF and CA. The modified composites also showed a remarkable reduction in water uptake rate.


2011 ◽  
Vol 675-677 ◽  
pp. 361-364 ◽  
Author(s):  
Yang Zhao ◽  
Jian Hui Qiu ◽  
Hui Xia Feng ◽  
Guo Hong Zhang ◽  
Liang Shao

Rice straw/Poly(butylene succinate)(PBS) composites were prepared by injection molding machine. The influence of content and particle size of rice straw on the mechanical properties of composites indicated that with the increase of rice straw content the tensile strength and fracture strain of the composites was decreased. With the same content of rice straw, the smaller particle size, the more obvious decreased. The influence of dosage of silane coupling agent(SCA) on the composites was studied, the result indicated that with the increase of SCA content, the interface of composite materials significantly improved, the Young’s modulus increased 362% after rice straw was treated by SCA. Thermal analysis showed that the adding of coupling agent didn’t undermine the thermodynamic stability of the composites.


2012 ◽  
Vol 200 ◽  
pp. 321-324 ◽  
Author(s):  
Zhao Xia Wang ◽  
De Gao ◽  
Wen Cai Xu

Mechanical properties of the calcium-plastic composite have a great influence on the containers. The main factors affecting the mechanical properties are the process and material formulations. This paper mainly describes its impact of the addition of coupling agent. Under the usage of analysis of variance on single factor experiment, the mechanical properties of the calcium carbonate-plastic composite with three different coupling agents (silane, titanate and aluminate) were studied in the same test conditions. The results show that: The type and quantity of the coupling agent effect a lot on the mechanical properties of the composite. The silane coupling agent is the most suitable for calcium carbonate-plastic composite packaging materials, and the compatibility of calcium carbonate and polyethylene can be improved. When the silane coupling agent was at a 2.25 wt. % concentration, the tensile and flexural strength were improved obviously, especially the tensile strength increased by 23.24%, but the impact strength improved slightly.


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