Effects of Coupling Agents on the Mechanical Properties of the Calcium Carbonate-Plastic Composite Packaging Materials

2012 ◽  
Vol 200 ◽  
pp. 321-324 ◽  
Author(s):  
Zhao Xia Wang ◽  
De Gao ◽  
Wen Cai Xu

Mechanical properties of the calcium-plastic composite have a great influence on the containers. The main factors affecting the mechanical properties are the process and material formulations. This paper mainly describes its impact of the addition of coupling agent. Under the usage of analysis of variance on single factor experiment, the mechanical properties of the calcium carbonate-plastic composite with three different coupling agents (silane, titanate and aluminate) were studied in the same test conditions. The results show that: The type and quantity of the coupling agent effect a lot on the mechanical properties of the composite. The silane coupling agent is the most suitable for calcium carbonate-plastic composite packaging materials, and the compatibility of calcium carbonate and polyethylene can be improved. When the silane coupling agent was at a 2.25 wt. % concentration, the tensile and flexural strength were improved obviously, especially the tensile strength increased by 23.24%, but the impact strength improved slightly.

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4896
Author(s):  
Yiren Pan ◽  
Meng Zhang ◽  
Jian Zhang ◽  
Xiaoyao Zhu ◽  
Huiguang Bian ◽  
...  

In this paper, the areca fiber was extracted by physical and chemical treatment, and then the areca fiber/natural latex composite was prepared by natural latex impregnation technology. In order to combine areca fiber and natural rubber latex better, three silane coupling agents with different action mechanism were selected: Si−69, KH550, and KH570 which were used to treat the areca fiber/natural latex compound. The results show that the silane coupling agent can change the surface of the fiber from hydrophilic surface to organophilic surface, making the bonding of areca fiber to natural latex more closely. At the same time, the mechanical properties, physical and mechanical properties, swelling properties, and dynamic viscoelastic properties of the tightly bonded areca fiber/nature latex composites were improved. After observing the micro-structure through a scanning electron microscope, it was found that the three silane coupling agents could effectively bind areca fiber and natural latex to enhance the performance of the composite material, of which Si−69 performed best, and the tensile strength and tear strength of the composite increased by 21.19% and 12.90% respectively.


2010 ◽  
Vol 105-106 ◽  
pp. 104-107 ◽  
Author(s):  
Zhi Qi Zhuo ◽  
Li Min Dong ◽  
Cheng Wang ◽  
Qing Feng Zan ◽  
Jie Mo Tian

This paper focuses on the influence on the mechanical properties of hydroxyapatite / poly-hydroxybutyrate (HA / PHB) composites by different HA contents, and the effect of Silane coupling agent on improving the interface of HA/PHB composite materials. The HA/PHB composites were prepared by ball milling, hot-pressing, the HA content were 0, 5, 10, 15, 20 and 30wt%, respectively. Silane coupling agent was used for HA surface treatment in HA/PHB composites to compare with not having HA surface treatment in HA/PHB composite materials. The impact strength and flexural strength of HA / PHB composites were tested, and the microstructure of the fracture surface was observed by SEM. The results showed that HA could enhance the bending strength of HA/PHB composites. With HA content increased, the bending strength increased first and then decreased, when the HA content was 10wt%, the maximum bending strength reached 32.74MPa, increased about 41% comparing with pure PHB. Silane coupling agent can improve the interface of HA / PHB, then enhance the mechanical strength. When the HA content was 15wt%, the maximum bending strength reached 46.6MPa, Increased about 56% comparing with the same proportion of untreated HA/PHB composite material, and about double comparing with pure PHB.


Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 3058
Author(s):  
Sang Yoon Lee ◽  
Jung Soo Kim ◽  
Seung Ho Lim ◽  
Seong Hyun Jang ◽  
Dong Hyun Kim ◽  
...  

The methoxy-type silane coupling agents were synthesized via the modification of the hydrolyzable group and characterized to investigate the change in properties of silica/rubber composites based on the different silane coupling agent structures and the masterbatch fabrication methods. The prepared methoxy-type silane coupling agents exhibited higher reactivity towards hydrolysis compared to the conventional ethoxy-type one which led to the superior silanization to the silica filler surface modified for the reinforcement of styrene-butadiene rubber. The silica/rubber composites based on these methoxy-type silane coupling agents had the characteristics of more developed vulcanization and mechanical properties when fabricated as masterbatch products for tread materials of automobile tire surfaces. In particular, the dimethoxy-type silane coupling agent showed more enhanced rubber composite properties than the trimethoxy-type one, and the environmentally friendly wet masterbatch fabrication process was successfully optimized. The reactivity of the synthesized silane coupling agents toward hydrolysis was investigated by FITR spectroscopic analysis, and the mechanical properties of the prepared silica-reinforced rubber polymers were characterized using a moving die rheometer and a universal testing machine.


2012 ◽  
Vol 268-270 ◽  
pp. 127-133
Author(s):  
Chen Zheng ◽  
Yan Yan Xu ◽  
Takahiko Kawai ◽  
Shin-ichi Kuroda

In order to improve the properties and the processability of kenaf fiber (KF) / polystyrene (PS) composites, the newly synthesized polymeric silane coupling agent (CA) was utilized and evaluated. KFs were reacted with CA in the melt system and in the solvent system. The composites reinforced by the modified KF showed enhanced mechanical properties compared with those reinforced by the unmodified KF. The effect was especially remarkable when the KF was modified with CA in the solvent system. As the CA content increases, the surface of KF recovered from the composites showed the higher Si / C ratio indicating the good reaction between KF and CA. The modified composites also showed a remarkable reduction in water uptake rate.


2011 ◽  
Vol 675-677 ◽  
pp. 361-364 ◽  
Author(s):  
Yang Zhao ◽  
Jian Hui Qiu ◽  
Hui Xia Feng ◽  
Guo Hong Zhang ◽  
Liang Shao

Rice straw/Poly(butylene succinate)(PBS) composites were prepared by injection molding machine. The influence of content and particle size of rice straw on the mechanical properties of composites indicated that with the increase of rice straw content the tensile strength and fracture strain of the composites was decreased. With the same content of rice straw, the smaller particle size, the more obvious decreased. The influence of dosage of silane coupling agent(SCA) on the composites was studied, the result indicated that with the increase of SCA content, the interface of composite materials significantly improved, the Young’s modulus increased 362% after rice straw was treated by SCA. Thermal analysis showed that the adding of coupling agent didn’t undermine the thermodynamic stability of the composites.


2017 ◽  
Vol 25 (1) ◽  
pp. 23-28 ◽  
Author(s):  
Jiuqiang Song ◽  
Yan Qin ◽  
Jia Chen ◽  
Siwen Qin

In this paper, a continuous glass fiber-reinforced polypropylene prepreg was prepared by fiber treatment with a silane coupling agent and MAH-g-PP resin. Continuous glass fiber-reinforced polypropylene sheets were made from prepreg and PP mats by hot-pressing; they displayed exceptional performance. This paper studies the effects of maleic anhydride grafting on the polypropylene crystallinity and MAH-g-PP content in the prepreg, and the mechanical properties of the composites. The results showed that modifying PP with maleic anhydride decreased the tacticity of the polypropylene molecular chain, which reduced the crystallinity and melting point. An excellent interface formed between the polypropylene and fiber after the glass fiber was treated with a silane coupling agent and MAH-g-PP resin. The mechanical properties of the polymer materials displayed more favorable properties as MAH-g-PP content increased; the ideal MAH-g-PP content was 50%.


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