THE TECHNOLOGY OF TITANIUM ALUMINIDES FOR AEROSPACE APPLICATIONS

1992 ◽  
Vol 7 (4) ◽  
pp. 527-559 ◽  
Author(s):  
J.C. Beddoes ◽  
W. Wallace ◽  
M.C. de Malherbe
2020 ◽  
Vol 321 ◽  
pp. 08002
Author(s):  
Matthew S. Dahar ◽  
Sesh A. Tamirisakandala ◽  
John J. Lewandowski

Although the benefits of titanium aluminides for intermediate service temperature applications were well conceived and significant research and development activities were conducted in the past four decades, they remained as developmental materials due to barriers associated with melting, processing, scale-up, and cost. Demanding requirements of efficient aero-engines and extensive risk reduction demonstrations paved the path for commercial introduction of gamma titanium aluminides. The single most attractive current application is for low pressure turbine blades (LPTBs) in advanced aero-engines replacing conventionally cast nickel superalloys. This paper provides an overview of recent progress, producibility challenges, and opportunities. The successful journey of gamma (γ) TiAl LPTB development from laboratory demonstrations to production insertions in mass-produced commercial jet engines will be described. Collaboration and integrated product development were identified as the most critical needs for rapid maturation and implementation of γ-TiAl into aerospace applications. An integrated computational materials engineering modeling framework and toolsets developed under a collaborative US Air Force Metals Affordability Initiative project between industry, government, and academia will be illustrated. Model-based optimization of material and processing for achieving desired performance goals will be highlighted.


2021 ◽  
Vol 139 ◽  
pp. 107270
Author(s):  
Alexander Donchev ◽  
Lukas Mengis ◽  
Alain Couret ◽  
Svea Mayer ◽  
Helmut Clemens ◽  
...  

Author(s):  
Daniel S. Schwartz ◽  
S. M. L. Sastry

The high strength-to-weight ratios and high elevated-temperature strength of dispersion strengthened titanium and titanium aluminides make them attractive materials for aerospace applications. A fine dispersion of hard particles is introduced into these alloys to increase their strength through an Orowan hardening mechanism. In addition to strengthening the material, dispersoids with whisker morphologies can produce toughening. Titanium alloys containing boride dispersions are currently being investigated at McDonnell Douglas Research Laboratories, and the microstructure of the dispersoids will be reported in this paper. Fine boride dispersions were produced in alloys with the compositions Ti-6B, Ti-25A1-4B and Ti-48A1-5B (at.%) using rapid solidification processing. The alloys were then annealed at ∼800°C/1 h, TEM specimens produced by electropolishing, and the structure of the borides examined in detail with a JEOL 2000FX TEM.


Author(s):  
R. E. Herfert ◽  
N. T. McDevitt

Durability of adhesive bonded joints in moisture and salt spray environments is essential to USAF aircraft. Structural bonding technology for aerospace applications has depended for many years on the preparation of aluminum surfaces by a sulfuric acid/sodium dichromate (FPL etch) treatment. Recently, specific thin film anodizing techniques, phosphoric acid, and chromic acid anodizing have been developed which not only provide good initial bond strengths but vastly improved environmental durability. These thin anodic films are in contrast to the commonly used thick anodic films such as the sulfuric acid or "hard" sulfuric acid anodic films which are highly corrosion resistant in themselves, but which do not provide good initial bond strengths, particularly in low temperature peel.The objective of this study was to determine the characteristics of anodic films on aluminum alloys that make them corrosion resistant. The chemical composition, physical morphology and structure, and mechanical properties of the thin oxide films were to be defined and correlated with the environmental stability of these surfaces in humidity and salt spray. It is anticipated that anodic film characteristics and corrosion resistance will vary with the anodizing processing conditions.


Author(s):  
Gerald B. Feldewerth

In recent years an increasing emphasis has been placed on the study of high temperature intermetallic compounds for possible aerospace applications. One group of interest is the B2 aiuminides. This group of intermetaliics has a very high melting temperature, good high temperature, and excellent specific strength. These qualities make it a candidate for applications such as turbine engines. The B2 aiuminides exist over a wide range of compositions and also have a large solubility for third element substitutional additions, which may allow alloying additions to overcome their major drawback, their brittle nature.One B2 aluminide currently being studied is cobalt aluminide. Optical microscopy of CoAl alloys produced at the University of Missouri-Rolla showed a dramatic decrease in the grain size which affects the yield strength and flow stress of long range ordered alloys, and a change in the grain shape with the addition of 0.5 % boron.


Author(s):  
Warren J. Moberly ◽  
Daniel B. Miracle ◽  
S. Krishnamurthy

Titanium-aluminum alloy metal matrix composites (MMC) and Ti-Al intermetallic matrix composites (IMC), reinforced with continuous SCS6 SiC fibers are leading candidates for high temperature aerospace applications such as the National Aerospace Plane (NASP). The nature of deformation at fiber / matrix interfaces is characterized in this ongoing research. One major concern is the mismatch in coefficient of thermal expansion (CTE) between the Ti-based matrix and the SiC fiber. This can lead to thermal stresses upon cooling down from the temperature incurred during hot isostatic pressing (HIP), which are sufficient to cause yielding in the matrix, and/or lead to fatigue from the thermal cycling that will be incurred during application, A second concern is the load transfer, from fiber to matrix, that is required if/when fiber fracture occurs. In both cases the stresses in the matrix are most severe at the interlace.


Author(s):  
Pamela F. Lloyd ◽  
Scott D. Walck

Pulsed laser deposition (PLD) is a novel technique for the deposition of tribological thin films. MoS2 is the archetypical solid lubricant material for aerospace applications. It provides a low coefficient of friction from cryogenic temperatures to about 350°C and can be used in ultra high vacuum environments. The TEM is ideally suited for studying the microstructural and tribo-chemical changes that occur during wear. The normal cross sectional TEM sample preparation method does not work well because the material’s lubricity causes the sandwich to separate. Walck et al. deposited MoS2 through a mesh mask which gave suitable results for as-deposited films, but the discontinuous nature of the film is unsuitable for wear-testing. To investigate wear-tested, room temperature (RT) PLD MoS2 films, the sample preparation technique of Heuer and Howitt was adapted.Two 300 run thick films were deposited on single crystal NaCl substrates. One was wear-tested on a ball-on-disk tribometer using a 30 gm load at 150 rpm for one minute, and subsequently coated with a heavy layer of evaporated gold.


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