Application of Square Wave Voltammetry for Electrochemical Detection in Gradient Elution HPLC

1993 ◽  
Vol 16 (18) ◽  
pp. 3887-3901 ◽  
Author(s):  
John A. Roush ◽  
Mark R. Anderson
Keyword(s):  
Electrochemical Detection ◽  
Square Wave Voltammetry ◽  
Gradient Elution ◽  
Square Wave ◽  
Wave Voltammetry

scholarly journals Electrochemical detection of exogenously administered melatonin in the brain

The Analyst ◽  
2020 ◽  
Vol 145 (7) ◽  
pp. 2612-2620 ◽  
Author(s):  
Elisa Castagnola ◽  
Kevin Woeppel ◽  
Asiyeh Golabchi ◽  
Moriah McGuier ◽  
Neharika Chodapaneedi ◽  
...  
Keyword(s):  
Electrochemical Detection ◽  
Square Wave Voltammetry ◽  
Electrochemical Measurement ◽  
Square Wave ◽  
Wave Voltammetry ◽  
The Brain

Optimized square wave voltammetry for electrochemical measurement of exogenously administered MT in vivo.

Electrochemical detection of sulphide in water/seawater using nanostructured carbon–epoxy composite electrodes

2014 ◽  
Vol 6 (13) ◽  
pp. 4775-4782 ◽  
Author(s):  
M. Ardelean ◽  
F. Manea ◽  
N. Vaszilcsin ◽  
R. Pode
Keyword(s):  
Electrochemical Detection ◽  
Square Wave Voltammetry ◽  
Epoxy Composite ◽  
Composite Electrodes ◽  
Nanostructured Carbon ◽  
Square Wave ◽  
Wave Voltammetry

Detection results obtained for sulphide detection in real water using a CNF electrode by square-wave voltammetry.

An electrochemical detection of cadmium (II) and lead (II) ions using a polymer-modified electrode with a Schiff base by square wave voltammetry

2021 ◽  
Author(s):  
Mohammed Qasim Mohammed ◽  
Hani Khalil Ismail ◽  
Hasan Fisal Alesary ◽  
Stephen Barton
Keyword(s):  
Schiff Base ◽  
Modified Electrode ◽  
Electrochemical Detection ◽  
Square Wave Voltammetry ◽  
Electrochemical Behaviour ◽  
Modified Electrodes ◽  
Polymer Coatings ◽  
Square Wave ◽  
Enhanced Sensitivity ◽  
Wave Voltammetry

Abstract The work herein concentrates on the electrochemical detection of heavy metal ions, specifically cadmium and lead ions. The introduction and modification of functional groups such as Schiff bases had led to an enhanced sensitivity of the electrode to analytes. In this study, a platinum electrode has for the first time been modified with poly(3,4- ethylenedioxythiophene) (PEDOT/Schiff base) in CH2Cl2 containing Bu4NPF6 for use to detection cadmium (II) and lead (II) ions. The structure and morphology of the polymer coatings were characterised by Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM), respectively. The electrochemical synthesis and redox state response in monomer-free synthesised films have been studied by cyclic voltammetry. Moreover, the effect of scan rate on the electrochemical behaviour of the modified electrodes was also studied. The voltammetric findings have been used to calculate the surface coverage required for the polymer films and the stability of polymer electrodes in the monomer-free solutions. Square wave voltammetry (SWV) was applied for the determination of cadmium (II) and lead (II) ion concentrations and to assess the effects of pH on aqueous samples. The limits of detection for the modified electrode for cadmium (II) and lead (II) were found to be 0.95 μg L-1 and 1.84 μg L-1, respectively. These findings revealed that modified films can be considered good candidates for application in electrochemical detection devices

A competitive electrochemical aptamer-based method for aflatoxin B1 detection with signal-off response

2020 ◽  
Vol 12 (5) ◽  
pp. 646-650 ◽  
Author(s):  
Chao Wang ◽  
Yapiao Li ◽  
Qiang Zhao
Keyword(s):  
Methylene Blue ◽  
Electrochemical Detection ◽  
Aflatoxin B1 ◽  
Gold Electrode ◽  
Square Wave Voltammetry ◽  
Complementary Dna ◽  
Square Wave ◽  
Wave Voltammetry

Electrochemical detection of AFB1 with square wave voltammetry by using a complementary DNA modified gold electrode and a methylene blue labeled aptamer.

Facile and Fast Detection of Genistein in Derris scandens by Square Wave Voltammetry using a Cobalt(II) Phthalocyanine-Modified Screen-Printed Electrochemical Sensor

2020 ◽  
Vol 16 (3) ◽  
pp. 341-348
Author(s):  
Surinya Traipop ◽  
Suchada Chuanuwatanakul ◽  
Orawon Chailapakul ◽  
Eakkasit Punrat
Keyword(s):  
Electrochemical Sensor ◽  
Square Wave Voltammetry ◽  
Silver Chloride ◽  
Reference Electrode ◽  
High Sensitivity ◽  
Plastic Substrate ◽  
Fast Analysis ◽  
Square Wave ◽  
Wave Voltammetry ◽  
Screen Printed

Background: Recently, Derris scandens, a Thai herbal medicine with anti-inflammatory activity, is widely used as beverage and supplementary food. When the traditional medicine is a choice for health therapy, the simple and reliable equipment is required to control the suitable consuming amount of the active component. Objective: To develop the electrochemical sensor for genistein determination in Derris scandens with high sensitivity and rapid operation. Methods: An in-house screen-printed electrochemical sensor consisting of a three-electrode system was developed for genistein determination. A silver/silver chloride (Ag/AgCl) reference electrode, a carbon counter electrode and a carbon working electrode were prepared on a 0.3-mm-thick plastic substrate by the screen-printing technique using conductive ink. The dimensions of each sensor were 2.5×1.0 cm. Only 50 µL of sample solution was required on this device for the determination of genistein concentration by rapid response square wave voltammetry. Results: The oxidation peak of genistein appeared with good response in acidic media at a peak potential of 0.6 V. Moreover, the signal was enhanced by modifying the conductive carbon ink with cobalt( II) phthalocyanine. Under the optimized conditions, the linear range was found to be 2.5-150 µM and the detection limit was 1.5 µM. Moreover, the small volume extraction was successfully developed without any further pre-concentration. This proposed method was applied to determine genistein in Derris scandens with satisfying results. Conclusion: The proposed method is promising as an alternative method for genistein determination with facile and fast analysis.

Isopotential points in square-wave voltammetry of reversible electrode reactions

2009 ◽  
Vol 74 (10) ◽  
pp. 1489-1501 ◽  
Author(s):  
Marina Zelić ◽  
Milivoj Lovrić
Keyword(s):  
Square Wave Voltammetry ◽  
Electrode Reaction ◽  
Time Model ◽  
Model Calculations ◽  
Square Wave ◽  
Electrode Reactions ◽  
Wave Voltammetry ◽  
Electron Transfer Processes ◽  
Diagnostic Criterion ◽  
First Time

Isopotential points in square-wave voltammetry are described for the first time. Model calculations and real measurements (performed with UO22+ and Eu3+ in perchlorate and bromide solutions, respectively) indicate that such an intersection could be observed when backward components of the net response, resulting from an increase in frequency or reactant concentration, are presented together. The electrode reaction should be fully reversible because quasireversible or slower electron transfer processes give the isopoints only at increasing reactant concentrations but not at increasing square-wave frequencies. The effect could be used as an additional diagnostic criterion for recognition of reversible electrode reactions where products remain dissolved in the electrolyte solution.

scholarly journals Simultaneous Hydrolysis and Detection of Organophosphate by Benzimidazole Containing Ligand-Based Zinc(II) Complexes

Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 714
Author(s):  
Gaber A. M. Mersal ◽  
Hamdy S. El-Sheshtawy ◽  
Mohammed A. Amin ◽  
Nasser Y. Mostafa ◽  
Amine Mezni ◽  
...  
Keyword(s):  
Square Wave Voltammetry ◽  
Limit Of Detection ◽  
Organophosphorus Compounds ◽  
Organophosphorus Pesticides ◽  
Carbon Paste ◽  
Square Wave ◽  
Wave Voltammetry ◽  
Carbon Past Electrode ◽  
Hydrolysis Of ◽  
Biomimetic Sensor

The agricultural use of organophosphorus pesticides is a widespread practice with significant advantages in crop health and product yield. An undesirable consequence is the contamination of soil and groundwater by these neurotoxins resulting from over application and run-off. Here, we design and synthesize the mononuclear zinc(II) complexes, namely, [Zn(AMB)2Cl](ClO4) 1 and [Zn(AMB)2(OH)](ClO4) 2 (AMB = 2-aminomethylbenzimidazole), as artificial catalysts inspired by phosphotriesterase (PTE) for the hydrolysis of organophosphorus compounds (OPs) and simultaneously detect the organophosphate pesticides such as fenitrothion and parathion. Spectral and DFT (B3LYP/Lanl2DZ) calculations revealed that complexes 1 and 2 have a square-pyramidal environment around zinc(II) centers with coordination chromophores of ZnN4Cl and ZnN4O, respectively. Both 1 and 2 were used as a modifier in the construction of a biomimetic sensor for the determination of toxic OPs, fenitrothion and parathion, in phosphate buffer by square wave voltammetry. The hydrolysis of OPs using 1 or 2 generates p-nitrophenol, which is subsequently oxidized at the surface of the modified carbon past electrode. The catalytic activity of 2 was higher than 1, which is attributed to the higher electronegativity of the former. The oxidation peak potentials of p-nitrophenol were obtained at +0.97 V (vs. Ag/AgCl) using cyclic voltammetry (CV) and +0.88 V (vs. Ag/AgCl) using square wave voltammetry. Several parameters were investigated to evaluate the performance of the biomimetic sensor obtained after the incorporation of zinc(II) complex 1 and 2 on a carbon paste electrode (CPE). The calibration curve showed a linear response ranging between 1.0 μM (0.29 ppm) and 5.5 μM (1.6 ppm) for fenitrothion and 1.0 μM (0.28 ppm) and 0.1 μM (0.028 ppm) for parathion with a limit of detection (LOD) of 0.08 μM (0.022 ppm) and 0.51 μM (0.149 ppm) for fenitrothion and parathion, respectively. The obtained results clearly demonstrated that the CPE modified by 1 and 2 has a remarkable electrocatalytic activity towards the hydrolysis of OPs under optimal conditions.

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