Solvothermal Preparation, Crystal Structure, and Photoluminescence of a Cadmium Compound With a Two-Dimensional Supramolecular Layer

Author(s):  
Han-Mao Kuang ◽  
Wen-Tong Chen ◽  
Qiu-Yan Luo ◽  
Ya-Ping Xu ◽  
Xian Zhang ◽  
...  
2021 ◽  
Author(s):  
Tao Li ◽  
Xuefeng Chang ◽  
Lifang Mei ◽  
Xiayun Shu ◽  
Jidong Ma ◽  
...  

Ti3C2Tx is a promising new two-dimensional layered material for supercapacitors with good electrical conductivity and chemical stability. However, Ti3C2Tx has problems such as collapse of the layered structure and low...


Energies ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2460
Author(s):  
Jian Zou ◽  
Mengnan Liu ◽  
Shuyu Tan ◽  
Zhijie Bi ◽  
Yong Wan ◽  
...  

A two-dimensional perovskite photonic crystal structure of Methylamine lead iodide (CH3NH3PbI3, MAPbI3) is rationally designed as the absorption layer for solar cells. The photonic crystal (PC) structure possesses the distinct “slow light” and band gap effect, leading to the increased absorption efficiency of the absorption layer, and thus the increased photoelectric conversion efficiency of the battery. Simulation results indicate that the best absorption efficiency can be achieved when the scattering element of indium arsenide (InAs) cylinder is arranged in the absorption layer in the form of tetragonal lattice with the height of 0.6 μm, the diameter of 0.24 μm, and the lattice constant of 0.4 μm. In the wide wavelength range of 400–1200 nm, the absorption efficiency can be reached up to 82.5%, which is 70.1% higher than that of the absorption layer without the photonic crystal structure. In addition, the absorption layer with photonic crystal structure has good adaptability to the incident light angle, presenting the stable absorption efficiency of 80% in the wide incident range of 0–80°. The results demonstrate that the absorption layer with photonic crystal structure can realize the wide spectrum, wide angle, and high absorption of incident light, resulting in the increased utilization efficiency of solar energy.


2016 ◽  
Vol 231 (4) ◽  
pp. 1163-1164
Author(s):  
Yu Youzhu ◽  
Guo Yuhua ◽  
Yang Liguo ◽  
Niu Yongsheng

AbstractC5H5N5O3Ni, monoclinic, C2/c (no. 15), a = 8.5804(17) Å, b = 13.790(3) Å, c = 13.969(3) Å, β = 104.37(3)°, V =1601.2(6)Å3, Z = 8, Rgt(F) = 0.0203, wRref(F2) = 0.0550, T = 293 K.


2014 ◽  
Vol 70 (12) ◽  
pp. o1252-o1252 ◽  
Author(s):  
Rodolfo Moreno-Fuquen ◽  
Diego F. Sánchez ◽  
Javier Ellena

In the title compound, C10H6N4O5S, the mean plane of the non-H atoms of the central amide fragment C—N—C(=O)—C [r.m.s. deviation = 0.0294 Å] forms dihedral angles of 12.48 (7) and 46.66 (9)° with the planes of the thiazole and benzene rings, respectively. In the crystal, molecules are linked by N—H...O hydrogen bonds, forming chains along [001]. In addition, weak C—H...O hydrogen bonds link these chains, forming a two-dimensional network, containingR44(28) ring motifs parallel to (100).


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Runmei Ding ◽  
Zixin He ◽  
Meilin Wang ◽  
Danian Tian ◽  
Peipei Cen

AbstractBased on 2-(4-pyridyl)-terephthalate (H2pta) and oxalate ligands, two new lanthanide-containing coordination polymers (CPs), [Tb(pta)(C2O4)0.5(H2O)2)]·2H2O (1) and [Sm(pta)(C2O4)0.5(H2O)2)]·2H2O (2), have been synthesized under solvothermal conditions. The structures of both 1 and 2 have been determined by single-crystal X-ray diffraction. Infrared, elemental analysis, powder X-ray diffraction and thermogravimetric analysis data are also presented. The crystals of 1 and 2 exhibit isostructural layer-like networks, crystallizing in the triclinic space group P$‾{1}$. The layers are further stabilized and associated into 3D architectures through hydrogen bonding. Remarkably, the CPs 1 and 2 exhibit excellent water stability and remarkable thermostability with thermal decomposition temperatures of more than 420 °C.


2014 ◽  
Vol 136 (14) ◽  
pp. 5245-5248 ◽  
Author(s):  
Shigeyuki Ishida ◽  
Yousuke Yanagi ◽  
Kunihiko Oka ◽  
Kunimitsu Kataoka ◽  
Hiroshi Fujihisa ◽  
...  

2015 ◽  
Vol 71 (11) ◽  
pp. 1384-1387
Author(s):  
Marwen Chouri ◽  
Habib Boughzala

The title compound bis(1,4-diazoniabicyclo[2.2.2]octane) di-μ-chlorido-bis[tetrachloridobismuthate(III)] dihydrate, (C6H14N2)2[Bi2Cl10]·2H2O, was obtained by slow evaporation at room temperature of a hydrochloric aqueous solution (pH = 1) containing bismuth(III) nitrate and 1,4-diazabicyclo[2.2.2]octane (DABCO) in a 1:2 molar ratio. The structure displays a two-dimensional arrangement parallel to (100) of isolated [Bi2Cl10]4−bioctahedra (site symmetry -1) separated by layers of organic 1,4-diazoniabicyclo[2.2.2]octane dications [(DABCOH2)2+] and water molecules. O—H...Cl, N—H...O and N—H...Cl hydrogen bonds lead to additional cohesion of the structure.


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