Investigating the surface wettability and surface free energy of sodium silicate-impregnated poplar wood

2021 ◽  
pp. 1-10
Author(s):  
Xinde Bao ◽  
Mengying Zhang ◽  
Ping Li ◽  
Jianxiong Lu ◽  
Guangming Yuan ◽  
...  
Keyword(s):  
Free Energy ◽  
Surface Free Energy ◽  
Sodium Silicate ◽  
Surface Wettability ◽  
Poplar Wood

scholarly journals Influence of Multiple Factors on the Wettability and Surface Free Energy of Leaf Surface

2019 ◽  
Vol 9 (3) ◽  
pp. 593 ◽  
Author(s):  
Yong He ◽  
Shupei Xiao ◽  
Jianjian Wu ◽  
Hui Fang
Keyword(s):  
Contact Angle ◽  
Free Energy ◽  
Surface Free Energy ◽  
Solid Surface ◽  
Leaf Surface ◽  
Plant Protection ◽  
Plant Protection Products ◽  
Surface Wettability ◽  
Multiple Factors ◽  
Key Factor

The wettability of plant leaves directly reflects leaf hydrophilicity, which is the key factor that influences the adhesion of liquid pesticide as well as affects plant protection products (PPP) efficacy. Generally, the wettability of leaf surface is quantified by the contact angle and surface free energy (SFE), which are mainly dependent on leaf surface properties, liquid properties and other spraying parameters. Therefore, the aim of this paper was to investigate the SFE of rice and rape leaves with the variation of leaf status, leaf surface, and probe liquid as well as the influence of droplet falling height, solid surface, and PPP concentration on the wettability. The results showed that: (1) the dispersive components of SFE of rice and rape account for a large proportion which are closely related to their hydrophobicity—the abaxial of rape new leaf and the adaxial of rape old leaf are easier to wet comparing with rice and rape leaves in other statuses; (2) the increase of droplet falling height had a significant effect on improving the wettability between wax surface and adjuvant solution, while it had little improving effect on the wettability between wax surface and water; (3) the wettability of different solid surface varied greatly, and the order of wettability from good to bad is water-sensitive paper (WSP), wax, rape leaf, and rice leaf; (4) the effect of PPP concentration on the leaf surface wettability is significant, the contact angle decreased with the increase of PPP concentration, and the wettability of microemulsion is better than that of suspending agent and wettable powder. In conclusion, the SFE and wettability of crop leaf surface determine the suitable type of PPP, studying the influence of multiple factors on leaf surface wettability can provide a reliable reference for providing scientific guidance as well as improving the effective utilization of PPP.

scholarly journals Benefits of Residual Aluminum Oxide for Sand Blasting Titanium Dental Implants: Osseointegration and Bactericidal Effects

Materials ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 178
Author(s):  
Javier Gil ◽  
Román Pérez ◽  
Mariano Herrero-Climent ◽  
Maria Rizo-Gorrita ◽  
Daniel Torres-Lagares ◽  
...  
Keyword(s):  
Free Energy ◽  
Dental Implants ◽  
Surface Free Energy ◽  
Tissue Growth ◽  
Surface Wettability ◽  
Sand Blasting ◽  
Chemical Surface ◽  
Physico Chemical ◽  
Titanium Dental Implants

Objectives. The purpose of this work was to determine the influence of residual alumina after sand blasting treatment in titanium dental implants. This paper studied the effect of alumina on physico-chemical surface properties, such as: surface wettability, surface energy. Osseointegration and bacteria adhesion were determined in order to determine the effect of the abrasive particles. Materials and Methods. Three surfaces were studied: (1) as-received, (2) rough surface with residual alumina from sand blasting on the surface and (3) with the same roughness but without residual alumina. Roughness was determined by white light interferometer microscopy. Surface wettability was evaluated with a contact angle video-based system and the surface free energy by means of Owens and Wendt equation. Scanning electron microscopy equipped with microanalysis was used to study the morphology and determine the chemical composition of the surfaces. Bacteria (Lactobacillus salivarius and Streptococcus sanguinis) were cultured in each surface. In total, 110 dental implants were placed into the bone of eight minipigs in order to compare the osseointegration. The percentage of bone-to-implant contact was determined after 4 and 6 weeks of implantation with histometric analysis. Results. The surfaces with residual alumina presented a lower surface free energy than clean surfaces. The in vivo studies demonstrated that the residual alumina accelerated bone tissue growth at different implantation times, in relation to clean dental implants. In addition, residual alumina showed a bactericidal effect by decreasing the quantity of bacteria adhering to the titanium. Conclusions. It is possible to verify the benefits that the alumina (percentages around 8% in weight) produces on the surface of titanium dental implants. Clinical relevance. Clinicians should be aware of the benefits of sand-blasted alumina due to the physico-chemical surface changes demonstrated in in vivo tests.

scholarly journals Wettability of Sanded and Aged Fast-growing Poplar Wood Surfaces: I. Surface Free Energy

BioResources ◽  
2014 ◽  
Vol 10 (1) ◽  
Author(s):  
Qin Zhiyong ◽  
Hui Chen ◽  
Qiang Gao ◽  
Shifeng Zhang ◽  
Jianzhang Li
Keyword(s):  
Free Energy ◽  
Surface Free Energy ◽  
Poplar Wood ◽  
Fast Growing ◽  
Wood Surfaces

Smectic A-Smectic B interface : faceting and surface free energy measurement

1989 ◽  
Vol 50 (24) ◽  
pp. 3527-3534 ◽  
Author(s):  
P. Oswald ◽  
F. Melo ◽  
C. Germain
Keyword(s):  
Free Energy ◽  
Surface Free Energy ◽  
Energy Measurement ◽  
Smectic A

Examination of the lubricant storing and releasing ability of thermally sprayed surfaces

2011 ◽  
Vol 2 (2) ◽  
pp. 101-105
Author(s):  
L. Fazekas ◽  
Z. S. Tiba ◽  
G. Kalácska
Keyword(s):  
Free Energy ◽  
Surface Energy ◽  
Surface Free Energy ◽  
Essential Role ◽  
Index Number ◽  
Adhesion Ability ◽  
Thermally Sprayed ◽  
Proper Operation

Abstract The lubricant storing and releasing ability of the thermally sprayed surfaces plays an essential role in the proper operation of the components. In the case of porous sprayed surfaces the lubricant storing and releasing ability depends mainly on porosity and the surface energy (adhesion susceptibility). The adhesion ability can also be expressed indirectly with an index number that is by determining the surface free energy.

Molecular orientation of liquid aliphatic hydrocarbons on the surface and at the interface with water

1989 ◽  
Vol 54 (12) ◽  
pp. 3171-3186 ◽  
Author(s):  
Jan Kloubek
Keyword(s):  
Free Energy ◽  
Surface Free Energy ◽  
Molecular Orientation ◽  
Phase Changes ◽  
Aliphatic Hydrocarbons ◽  
Water Molecules ◽  
Free Energies ◽  
Dispersion Component ◽  
System Water ◽  
Orientation Of Molecules

The validity of the Fowkes theory for the interaction of dispersion forces at interfaces was inspected for the system water-aliphatic hydrocarbons with 5 to 16 C atoms. The obtained results lead to the conclusion that the hydrocarbon molecules cannot lie in a parallel position or be randomly arranged on the surface but that orientation of molecules increases there the ration of CH3 to CH2 groups with respect to that in the bulk. This ratio is changed at the interface with water so that the surface free energy of the hydrocarbon, γH, rises to a higher value, γ’H, which is effective in the interaction with water molecules. Not only the orientation of molecules depends on the adjoining phase and on the temperature but also the density of hydrocarbons on the surface of the liquid phase changes. It is lower than in the bulk and at the interface with water. Moreover, the volume occupied by the CH3 group increases on the surface more than that of the CH2 group. The dispersion component of the surface free energy of water, γdW = 19.09 mJ/m2, the non-dispersion component, γnW = 53.66 mJ/m2, and the surface free energies of the CH2 and CH3 groups, γ(CH2) = 32.94 mJ/m2 and γ(CH3) = 15.87 mJ/m2, were determined at 20 °C. The dependence of these values on the temperature in the range 15-40 °C was also evaluated.

scholarly journals Effect of calcination temperature on neptunium dioxide microstructure and dissolution

2020 ◽  
Vol 7 (12) ◽  
pp. 3869-3876
Author(s):  
Kathryn M. Peruski ◽  
Brian A. Powell
Keyword(s):  
Grain Size ◽  
Free Energy ◽  
Surface Area ◽  
Calcination Temperature ◽  
Surface Free Energy ◽  
Neptunium Dioxide

Solubility of neptunium dioxide decreases as microstructure grain size increases, likely due to decreasing surface free energy and surface area.

Bifunctional Composites for Biofilms Modulation on Cervical Restorations

2021 ◽  
pp. 002203452110181
Author(s):  
A.A. Balhaddad ◽  
I.M. Garcia ◽  
L. Mokeem ◽  
M.S. Ibrahim ◽  
F.M. Collares ◽  
...  
Keyword(s):  
Free Energy ◽  
Surface Free Energy ◽  
Contact Angles ◽  
Bacterial Biofilm ◽  
Dental Composite ◽  
Log P ◽  
Rrna Gene ◽  
Cervical Lesions ◽  
Biofilm Growth ◽  
Biofilm Development

Cervical composites treating root carious and noncarious cervical lesions usually extend subgingivally. The subgingival margins of composites present poor plaque control, enhanced biofilm accumulation, and cause gingival irritation. A potential material to restore such lesions should combine agents that interfere with bacterial biofilm development and respond to acidic conditions. Here, we explore the use of new bioresponsive bifunctional dental composites against mature microcosm biofilms derived from subgingival plaque samples. The designed formulations contain 2 bioactive agents: dimethylaminohexadecyl methacrylate (DMAHDM) at 3 to 5 wt.% and 20 wt.% nanosized amorphous calcium phosphate (NACP) in a base resin. Composites with no DMAHDM and NACP were used as controls. The newly formulated 5% DMAHDM–20% NACP composite was analyzed by micro-Raman spectroscopy and transmission electron microscopy. The wettability and surface-free energy were also assessed. The inhibitory effect on the in vitro biofilm growth and the 16S rRNA gene sequencing of survival bacterial colonies derived from the composites were analyzed. Whole-biofilm metabolic activity, polysaccharide production, and live/dead images of the biofilm grown over the composites complement the microbiological assays. Overall, the designed formulations had higher contact angles with water and lower surface-free energy compared to the commercial control. The DMAHDM-NACP composites significantly inhibited the growth of total microorganisms, Porphyromonas gingivalis, Prevotella intermedia/nigrescens, Aggregatibacter actinomycetemcomitans, and Fusobacterium nucleatum by 3 to 5-log ( P < 0.001). For the colony isolates from control composites, the composition was typically dominated by the genera Veillonella, Fusobacterium, Streptococcus, Eikenella, and Leptotrichia, while Fusobacterium and Veillonella dominated the 5% DMAHDM–20% NACP composites. The DMAHDM-NACP composites contributed to over 80% of reduction in metabolic and polysaccharide activity. The suppression effect on plaque biofilms suggested that DMAHDM-NACP composites might be used as a bioactive material for cervical restorations. These results may propose an exciting path to prevent biofilm growth and improve dental composite restorations’ life span.

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