Methyl methacrylate as a healing agent for self-healing cementitious materials

2011 ◽  
Vol 20 (12) ◽  
pp. 125016 ◽  
Author(s):  
K Van Tittelboom ◽  
K Adesanya ◽  
P Dubruel ◽  
P Van Puyvelde ◽  
N De Belie
2011 ◽  
Vol 374-377 ◽  
pp. 1899-1903
Author(s):  
Xiong Zhou Yuan ◽  
Wei Sun ◽  
Xiao Bao Zuo

Based on detailed consideration of the autonomic healing concept of microencapsulated healing agent, micro- bacteria induced calcite and shape memory alloys, our research team proposed a new self-healing technique coupled with of SMA and heat-melt adhesive. In this article, chemical stability and bonding strength with cementitious materials of PA heat-melt adhesive were tested. Experimental results show that PA heat-melt adhesive may contain the ability being used in self-healing techniques coupled with SMA.


2020 ◽  
Vol 62 (1) ◽  
pp. 63-85
Author(s):  
Rahul Roy ◽  
Emanuele Rossi ◽  
Johan Silfwerbrand ◽  
Henk Jonkers

AbstractCrack formation in concrete structures due to various load and non-load factors leading to degradation of service life is very common. Repair and maintenance operations are, therefore, necessary to prevent cracks propagating and reducing the service life of the structures. Accessibility to affected areas can, however, be difficult as the reconstruction and maintenance of concrete buildings are expensive in labour and capital. Autonomous healing by encapsulated bacteria-based self-healing agents is a possible solution. During this process, the bacteria are released from a broken capsule or triggered by water and oxygen access. However, its performance and reliability depend on continuous water supply, protection against the harsh environment, and densification of the cementitious matrix for the bacteria to act. There are vast methods of encapsulating bacteria and the most common carriers used are: encapsulation in polymeric materials, lightweight aggregates, cementitious materials, special minerals, nanomaterials, and waste-derived biomass. Self-healing efficiency of these encapsulated technologies can be assessed through many experimental methodologies according to the literature. These experimental evaluations are performed in terms of quantification of crackhealing, recovery of durability and mechanical properties (macro-level test) and characterization of precipitated crystals by healing agent (micro-level test). Until now, quantification of crack-healing by light microscopy revealed maximum crack width of 1.80mm healed. All research methods available for assesing self-healing efficiency of bacteria-based healing agents are worth reviewing in order to include a coherent, if not standardized framework testing system and a comparative evaluation for a novel incorporated bacteria-based healing agent.


Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3711
Author(s):  
Mohammad Fahimizadeh ◽  
Ayesha Diane Abeyratne ◽  
Lee Sui Mae ◽  
R. K. Raman Singh ◽  
Pooria Pasbakhsh

Crack formation in concrete is one of the main reasons for concrete degradation. Calcium alginate capsules containing biological self-healing agents for cementitious materials were studied for the self-healing of cement paste and mortars through in vitro characterizations such as healing agent survivability and retention, material stability, and biomineralization, followed by in situ self-healing observation in pre-cracked cement paste and mortar specimens. Our results showed that bacterial spores fully survived the encapsulation process and would not leach out during cement mixing. Encapsulated bacteria precipitated CaCO3 when exposed to water, oxygen, and calcium under alkaline conditions by releasing CO32− ions into the cement environment. Capsule rupture is not required for the initiation of the healing process, but exposure to the right conditions are. After 56 days of wet–dry cycles, the capsules resulted in flexural strength regain as high as 39.6% for the cement mortar and 32.5% for the cement paste specimens. Full crack closure was observed at 28 days for cement mortars with the healing agents. The self-healing system acted as a biological CO32− pump that can keep the bio-agents retained, protected, and active for up to 56 days of wet-dry incubation. This promising self-healing strategy requires further research and optimization.


2011 ◽  
Vol 33 (4) ◽  
pp. 497-505 ◽  
Author(s):  
Kim Van Tittelboom ◽  
Nele De Belie ◽  
Denis Van Loo ◽  
Patric Jacobs

2011 ◽  
Vol 99-100 ◽  
pp. 1087-1091 ◽  
Author(s):  
Xiong Zhou Yuan ◽  
Wei Sun ◽  
Xiao Bao Zuo

Based on detailed consideration of the autonomic healing concept of microencapsulated healing agent, micro- bacteria induced calcite and shape memory alloys, our research team proposed a new self-healing technique coupled with of SMA and heat-melt adhesive. In this article, chemical stability and bonding strength with cementitious materials of EVA heat-melt adhesive were tested. Experimental results show that EVA heat-melt adhesive may contain the ability being used in self-healing techniques coupled with SMA.


Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1725
Author(s):  
Wei Du ◽  
Quantao Liu ◽  
Runsheng Lin ◽  
Xin Su

Self-healing of cracks in cementitious materials using healing agents encapsulated in microcapsules is an intelligent and effective method. In this study, microcapsules were prepared by the melt–dispersion–condensation method using microcrystalline wax as the shell and E-51 epoxy resin as the healing agent. The effects of preparation process parameters and microcrystalline wax/E-51 epoxy resin weight ratio on the core content, particle size distribution, thermal properties, morphology, and chemical composition of microcapsules were investigated. The results indicated that the optimal parameters of the microcapsule were microcrystalline wax/E-51 epoxy resin weight ratio of 1:1.2, stirring speed of 900 rpm, and preparation temperature of 105 °C. The effects of microcapsules on pore size distribution, pore structure, mechanical properties, permeability, and ultrasonic amplitude of mortar were determined, and the self-healing ability of mortar with different contents of microcapsules was evaluated. The optimal content of microcapsules in mortars was 4% of the cement weight, and the surface cracks of mortar containing microcapsules with an initial width of 0.28 mm were self-healed within three days, indicating that microcapsules have excellent self-healing ability for cementitious materials.


2020 ◽  
Vol 996 ◽  
pp. 104-109 ◽  
Author(s):  
Zhen Hong Yang ◽  
Xian Feng Wang ◽  
Ning Xu Han ◽  
Feng Xing

In this study, Na2CO3 solution as a self-healing agent was impregnated in LWA for autonomic self-healing on cracked cementitious material. The results showed that under the joint action of expansive agent, crystalline additive, phosphate and carbonate, the crack area showed a high self-healing efficiency (close to 70%) after curing in the still water 28d. SEM-EDS test results showed that in addition to ettringite and C-S-H/C-A-S-H, there was also a large amount of CaCO3 crystal in the depths of the crack.


2017 ◽  
Vol 26 (2) ◽  
pp. 340-357 ◽  
Author(s):  
Shuai Zhou ◽  
Hehua Zhu ◽  
J Woody Ju ◽  
Zhiguo Yan ◽  
Qing Chen

Concrete with a micro-encapsulated healing agent is appealing due to its self-healing capacity. The discrete element method (DEM) is emerging as an increasingly used approach for investigating the damage phenomenon of materials at the microscale. It provides a promising way to study the microcapsule-enabled self-healing concrete. Based on the experimental observation and DEM, a three-dimensional damage-healing numerical model of microcapsule-enabled self-healing cementitious materials under compressive loading is proposed. The local healing effect can be simulated in our model, as well as the stress concentration effect and the partial healing effect. The healing variable of the DEM model is developed to describe the healing process. We examine the dependence of the mechanical properties of the microcapsule-enabled self-healing material on (a) the stiffness of the solidified healing agent, (b) the strength of the solidified healing agent, (c) the initial damage of specimens, and (d) the partial healing effect. In particular, the proposed numerical damage-healing model demonstrates the potential capability to explain and simulate the physical behavior of microcapsule-enabled self-healing materials on the microscale.


2019 ◽  
Vol 289 ◽  
pp. 01004 ◽  
Author(s):  
Anthony Jefferson ◽  
Tharmesh Selvarajoo ◽  
Brubeck Freeman ◽  
Robert Davies

This paper gives an overview of a combined experimental-numerical study on vascular self-healing (SH) systems for cementitious composite materials. The work aimed to bridge the gap between numerical and experimental investigations for this type of SH system and to provide a set of data for developing, calibrating and validating a finite element model for these materials. The study investigated both healing-agent transport and mechanical damage-healing processes, including healing-agent curing. The experimental programme included mechanical tests on notched concrete beams and compact direct-tension specimens with inbuilt vascular healing systems, as well as tests to measure the transport properties of healing-agent within discrete concrete cracks and through the concrete matrix. The new coupled model employs elements with embedded strong discontinuities to simulate cracks and mechanical healing behaviour. A damage-healing constitutive model is described that simulates multiple damage-healing ‘events’. This mechanical model is coupled to discrete and continuum flow models that simulate healing-agent transport. The transport model accounts for pressurised and capillary flow, as well as curing-dependent flow properties. The main focus of this contribution is to show how these parallel programmes of work were combined so that the experimental observations guided the numerical developments and modelling questions were answered using experimental findings.


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