Boosted dielectric performance of organic‐inorganic nanocomposites based on BaTiO3 via 2D TiO2 templates

Author(s):  
Se Yeon Park ◽  
Moonjeong Jang ◽  
Wooseok Song ◽  
Sun Sook Lee ◽  
Dae Ho Yoon ◽  
...  

Abstract Organic-inorganic hybrid dielectrics composed of nanoscale ceramic fillers in polymer matrices have attracted considerable attention because they can overcome the inherent limitations such as the low dielectric constant, high dielectric loss, and low film density associated with mechanically flexible pristine polymer materials. Barium titanate (BaTiO3), a representative perovskite-based material with a high permittivity, is suitable for applications as nanofillers in nanocomposite dielectrics. X-ray diffraction combined with Raman analysis suggest that a two-step hydrothermal synthesis, which uses synthesized TiO2 nanosheets as a template, is an effective method for the synthesis of pure BaTiO3 nanoparticles compared with other methods. Ultrasonic treatment is employed to disperse BaTiO3 nanoparticles with different concentrations in polyvinyl alcohol (PVA) polymer, and the dielectric performance of the nanocomposite films has been examined. In this study, 20 wt% BaTiO3-PVA nanocomposite dielectric showed superior capacitance and dielectric constant performance, i.e., five times higher than that of the pristine PVA.

2018 ◽  
Vol 2018 ◽  
pp. 1-15 ◽  
Author(s):  
Yong You ◽  
Chenhao Zhan ◽  
Ling Tu ◽  
Yajie Wang ◽  
Weibin Hu ◽  
...  

Flexible polymer-based composites exhibiting high dielectric constant as well as low dielectric loss have been intensively investigated for their potential utilization in electronics and electricity industry and energy storage. Resulting from the polar -CN on the side chain, polyarylene ether nitrile (PEN) shows relatively high dielectric constant which has been extensively investigated as one of the hot spots as dielectric materials. However, the dielectric constant of PEN is still much lower than the ceramic dielectrics such as BaTiO3, TiO2, and Al2O3. In this review, recent and in-progress advancements in the designing and preparing strategies to obtain high-k PEN-based nanocomposites are summarized. According to the types of the added fillers, the effects of organic fillers, dielectric ceramic fillers, and conductive fillers on electric properties of PEN-based composites are investigated. In addition, other factors including the structures and sizes of the additive, the compatibility between the additive agent and the PEN, and the interface which affects the dielectric properties of the obtained composite materials are investigated. Finally, challenges facing in the design of more effective strategies for the high-k PEN-based dielectric materials are discussed.


2018 ◽  
Vol 6 (2) ◽  
pp. 271-279 ◽  
Author(s):  
Jianwen Chen ◽  
Xiucai Wang ◽  
Xinmei Yu ◽  
Lingmin Yao ◽  
Zhikui Duan ◽  
...  

Nanocomposite films with a small loading of two-dimensional Bi2Te3@Al2O3 hexagonal nanoplates exhibit a high dielectric constant of 140 and relatively low dielectric loss of 0.05 at 1 kHz.


2003 ◽  
Vol 17 (18n20) ◽  
pp. 3738-3744 ◽  
Author(s):  
C. Zhang ◽  
J. T. Wang ◽  
M. Q. Qian ◽  
T. P. Chen ◽  
I. Akujobi ◽  
...  

Lead magnesium niobate-lead titanate (PMN-PT) is an intriguing candidate for applications in many electronic devices such as multi-layer capacitors, electro-mechanical transducers etc. because of its high dielectric constant, low dielectric loss and high strain near the Curie temperature. As an extension of our previous work on Ta-doped PMNT-PT aimed at optimizing the performance and reducing the cost, this paper focuses on the effect of Pb volatilization on the dielectric properties of 0.77 Pb ( Mg 1/3( Nb 0.9 Ta 0.1)2/3) O 3-0.23 PbTiO 3. The dielectric constant and loss of the samples are measured at different frequencies and different temperatures. The phase purity of this compound is determined by X-ray diffraction pattern. It is found that the volatilization during sintering does influence the phase formation and dielectric properties. The best condition is sintering with 0.5 g extra PbO around a 4 g PMNT-PT sample.


2019 ◽  
Vol 13 (4) ◽  
pp. 323-332 ◽  
Author(s):  
Zeynep Özdemir ◽  
Mehmet Kılıç ◽  
Yaşar Karabul ◽  
Seda Erdönmez ◽  
Orhan İçelli

In this work, EuxBi1-xSr2CaCu2O6.5 (where x = 0, 0.3, 0.5) samples were prepared by solid-state reaction method and sintered at 950?C for 24 h. The structural characterizations were done by X-ray diffraction, X-ray fluorescence, scanning electron microscope and Fourier transformed infrared spectroscopy. The thermal stability of the samples was also analysed by thermogravimetric TG and DTA measurements. It was shown that Eu0.5Bi0.5Sr2CaCu2O6.5 sample exhibited high dielectric constant and low dielectric loss relative to BiSr2CaCu2O6.5 material. Thus, the dielectric loss was lowered by heavy rare earth metal substitution on Bi-Sr-Ca-Cu-O ceramics while the dielectric constant still remained high. Temperature-dependent complex electrical modulus spectra obtained between 296 and 433K also revealed the temperature-activated relaxation process in the materials which can be attributed to the Maxwell-Wagner type polarization effect. Ultimately, it was suggested that the Eu0.5Bi0.5Sr2CaCu2O6.5 ceramics may have a promising potential for applications which require high dielectric constant with a low dielectric loss.


2018 ◽  
Vol 6 (40) ◽  
pp. 10829-10837 ◽  
Author(s):  
Guifang Liu ◽  
Yi Chen ◽  
Minjie Gong ◽  
Xiaoyun Liu ◽  
Zhong-Kai Cui ◽  
...  

Enhanced dielectric constant of PDMS incorporating chain-ball structured CCTO@MWCNT nanoparticles.


2018 ◽  
Vol 6 (9) ◽  
pp. 2370-2378 ◽  
Author(s):  
Yang Liu ◽  
Cheng Zhang ◽  
Benyuan Huang ◽  
Xu Wang ◽  
Yulong Li ◽  
...  

A novel skin–core structured fluorinated MWCNT nanofiller was prepared to fabricate epoxy composite with broadband high dielectric constant and low dielectric loss.


RSC Advances ◽  
2017 ◽  
Vol 7 (38) ◽  
pp. 23309-23312 ◽  
Author(s):  
Ting Yang ◽  
Wenhui Xu ◽  
Xinwen Peng ◽  
Haoqing Hou

Crown ether-containing polyimides possess high dielectric constant and low dielectric loss, without sacrificing other properties.


2021 ◽  
Author(s):  
Shashwat Shukla ◽  
Gerald Wesley Patterson

<p>One of the unique candidates to explore the evolution of physical surface processes on the Moon is Tycho, a dark haloed impact crater representing well-preserved bright ray pattern and intact crater morphology. Sampling of the central peak in such complex crater formation proves significant in terms of unraveling intriguing science of the lunar interior. With the current state-of-the-art radar technology, it is possible to evaluate the response of the geologic features constrained in the near surface and subsurface regolith environments. This can be achieved by modelling the dielectric constant of media, which is a physical parameter crucial for furthering our knowledge about the distribution of materials within different stratigraphic layers at multiple depths. Here, we used the applicability of Mini-RF S-band data augmented with a deep learning based inversion model to retrieve the dielectric variations over the central peak of the Tycho crater. A striking observation is made in certain regions of the central peak, wherein we observe anomalously high dielectric constant, not at all differentiated in the hyperspectral image and first Stokes parameter image, which usually is a representation of retrieved backscatter of the target. The results are also supported by comparing the variations in the scattering mechanisms. We found those particular regions to be associated with high degree of depolarization, thereby attributing to the presence of cm- to m- scale scatterers buried within a low dielectric layer that are not big enough to produce even-bounce geometry for the radar wave. Moreover, we also observe high rock concentration in the central peak slopes from DIVINER data and NAC images, indicating the exposure of clasts ranging in size from 10 meter to 100s of meter. Furthermore, from surface temperature data, these distinctive outcrops sense warmer temperature at night than the surrounding, which suggests the existence of thermal skin depth in such vicinities. Interestingly, we are able to quantify the pessimistic dielectric constant limit of the large boulder in the middle of the central peak, observable at the Mini-RF radar wavelength, as 4.54 + j0.077. Compared to the expected dielectric constant of rocks, this value is lowered significantly. One probable reason could be the emergence of small radar shadows due to the rugged surface of the boulder on the radar illuminated portion. From our analysis, we showcase the anomalous dielectric variability of Tycho central peak, thereby providing new insights into the evolution of the impact cratering process that could be important for both science and necessary for framing human or robotic exploration strategies.  </p>


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