Physicochemical Properties and Method for Determination of Potassium Guaiacolsulfonate

1987 ◽  
Vol 70 (4) ◽  
pp. 673-678
Author(s):  
Kunio Kawamura ◽  
Hideo Nakamachi ◽  
Hiroaki Araki ◽  
Kiyokazu Sonoda
Keyword(s):  
Liquid Chromatography ◽  
Physicochemical Properties ◽  
Infrared Spectra ◽  
Uv Spectra ◽  
Differential Scanning Calorimetric ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ph Values ◽  
Diffraction Patterns

Abstract The physicochemical properties of potassium guaiacol-4-sulfonate (I) and -S-suIfonate (II) have been investigated. Analyses of the X-ray diffraction patterns, infrared spectra, and thermogravimetric and differential scanning calorimetric curves showed that I occurs as crystals that are anhydrous or hydrated up to ⅔ mole (4.8%) and that II occurs as crystals that are anhydrous or dihydrated (13.5%). Solutions of I and II at various pH values showed almost the same UV spectra at <pH 6.0 but very different UV spectra >pH 7.0. Most commercially available potassium guaiacolsulfonate consists predominantly of potassium guaiacol-4-sulfonate (as determined by UVabsorption measurements and liquid chromatography).

Infrared spectroscopic study of the YPO4-YCrO4 system

1985 ◽  
Vol 50 (10) ◽  
pp. 2139-2145
Author(s):  
Alexander Muck ◽  
Eva Šantavá ◽  
Bohumil Hájek
Keyword(s):  
Spectroscopic Study ◽  
Infrared Spectra ◽  
Point Of View ◽  
Mixed Crystals ◽  
Crystal Symmetry ◽  
Infrared Spectroscopic Study ◽  
X Ray Diffraction ◽  
X Ray ◽  
Infrared Spectroscopic ◽  
Diffraction Patterns

The infrared spectra and powder X-ray diffraction patterns of polycrystalline YPO4-YCrO4 samples are studied from the point of view of their crystal symmetry. Mixed crystals of the D4h19 symmetry are formed over the region of 0-30 mol.% YPO4 in YCrO4. The Td → D2d → D2 or C2v(GS eff) correlation is appropriate for both PO43- and CrO43- anions.

scholarly journals Born out of Fire and Ice: Polymorph Studies of the Antiviral Famciclovir

Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 129
Author(s):  
Liana Vella-Zarb ◽  
Ulrich Baisch
Keyword(s):  
Variable Temperature ◽  
Chemical Properties ◽  
Crystal Form ◽  
X Ray Diffraction ◽  
Crystal Forms ◽  
X Ray ◽  
Physical Chemical ◽  
Diffraction Patterns ◽  
Crystalline Forms

There is much interest and focus on solid forms of famciclovir. However, in spite of the abundance of reported differences in oral bioavailability, compressibility, and other physical–chemical properties of the various crystal forms of this drug, very little precise structural analysis is available in the literature to date. The form used in the commercial formulation is the anhydrous form I. Patents and patent applications report three different anhydrous crystalline forms on the basis of unindexed powder diffraction patterns. Single-crystal and variable-temperature X-ray diffraction experiments using the commercially available anhydrous form of famciclovir were carried out and led not only to the crystal structure determination of the anhydrous form I, but also to discovery of a new crystal form of anhydrous famciclovir from powder data.

scholarly journals Synthesis of the Modifications of Ca2SiO4 and the Determination of their Powder X-ray Diffraction Patterns

1963 ◽  
Vol 71 (806) ◽  
pp. 63-68 ◽  
Author(s):  
Goro YAMAGUCHI ◽  
Yoshio ONO ◽  
Shigeo KAWAMURA ◽  
Yoshiaki SODA
Keyword(s):  
X Ray Diffraction ◽  
X Ray ◽  
Diffraction Patterns

Effect of Germination on Physicochemical Properties of Tartary Buckwheat Starch

2013 ◽  
Vol 634-638 ◽  
pp. 1454-1459
Author(s):  
Yi Ming Zhou ◽  
Xiao Li Zhou ◽  
Ying Xiao ◽  
Ning Liu ◽  
Yue Chen
Keyword(s):  
Physicochemical Properties ◽  
Tartary Buckwheat ◽  
Moderate Increase ◽  
X Ray Diffraction ◽  
Raw Starch ◽  
X Ray ◽  
Germination Process ◽  
Swelling Capacity ◽  
Diffraction Patterns ◽  
Percent Crystallinity

The changes in physicochemical properties of tartary buckwheat starch during germination process were studied in the present study. After germination, there was a moderate increase in loss of starch (4.4~5.9%). The outcomes from scanning electron microscope indicated that the process of germination moderately increased the multi-pore around the granules of starch. The X-ray diffraction pattern of raw starch showed an A-pattern. Germination process did not distinctly affect X-ray diffraction patterns, but percent crystallinity of starch were increased with the increase of germination. Germination process raised the solubility of buckwheat starch but did not distinctly affect swelling capacity. The paste clarity and freeze–thaw stability of starch were improved after 24-h germination, but the germinated starch for 36 h exhibited no improvements in these properties compared with the raw starch. Therefore, moderate germination improved some physicochemical properties of tartary buckwheat starch.

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