scholarly journals An empirical infrared transit spectrum of Earth: opacity windows and biosignatures

2019 ◽  
Vol 489 (1) ◽  
pp. 196-204 ◽  
Author(s):  
Evelyn J R Macdonald ◽  
Nicolas B Cowan

Abstract The Atmospheric Chemistry Experiment Fourier Transform Spectrometer on the SCISAT satellite has been measuring infrared (IR) transmission spectra of Earth during Solar occultations since 2004. We use these data to build an IR transit spectrum of Earth. Regions of low atmospheric opacity, known as windows, are of particular interest, as they permit observations of the planet’s lower atmosphere. Even in the absence of clouds or refraction, imperfect transmittance leads to a minimum effective thickness of hmin ≈ 4 km in the 10–12 $\mu \mathrm{m}$ opacity window at a spectral resolution of R = 103. None the less, at R = 105, the maximum transmittance at the surface is around ${70}{{{\ \rm per\ cent}}}$. In principle, one can probe the troposphere of an Earth-like planet via high-dispersion transit spectroscopy in the mid-IR; in practice aerosols and/or refraction likely make this impossible. We simulate the transit spectrum of an Earth-like planet in the TRAPPIST-1 system. We find that a long-term near-IR (NIR) campaign with the James Webb Space Telescope(JWST) could readily detect CO2, establishing the presence of an atmosphere. A mid-IR campaign or longer NIR campaign would be more challenging, but in principle could detect H2O and the biosignatures O3 and CH4.

2014 ◽  
Vol 32 (6) ◽  
pp. 589-608 ◽  
Author(s):  
M. G. Shepherd ◽  
S. R. Beagley ◽  
V. I. Fomichev

Abstract. The response of the upper mesosphere/lower thermosphere region to major sudden stratospheric warming (SSW) is examined employing temperature, winds, NOX and CO constituents from the extended Canadian Middle Atmosphere Model (CMAM) with continuous incremental nudging below 10 hPa (~ 30 km). The model results considered cover high latitudes (60–85° N) from 10 to 150 km height for the December–March period of 2003/2004, 2005/2006 and 2008/2009, when some of the strongest SSWs in recent years were observed. NOX and CO are used as proxies for examining transport. Comparisons with ACE-FTS (Atmospheric Chemistry Experiment–Fourier Transform Spectrometer) satellite observations show that the model represents well the dynamics of the upper mesosphere/lower thermosphere region, the coupling of the stratosphere–mesosphere, and the NOX and CO transport. New information is obtained on the upper mesosphere/lower thermosphere up to 150 km showing that the NOX volume mixing ratio in the 2003/2004 winter was very perturbed indicating transport from the lower atmosphere and intense mixing with large NOX influx from the thermosphere compared to 2006 and 2009. These results, together with those from other models and observations, clearly show the impact of stratospheric warmings on the thermosphere.


2013 ◽  
Vol 13 (2) ◽  
pp. 4221-4287 ◽  
Author(s):  
A. T. Brown ◽  
C. M. Volk ◽  
M. R. Schoeberl ◽  
C. D. Boone ◽  
P. F. Bernath

Abstract. Long lived halogen-containing compounds are important atmospheric constituents since they can act both as a source of chlorine radicals, which go on to catalyse ozone loss, and as powerful greenhouse gases. The long term impact of these species on the ozone layer is dependent on their stratospheric lifetimes. Using observations from the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) we present calculations of the stratospheric lifetimes of CFC-12, CCl4, CH4, CH3Cl and N2O. The lifetimes were calculated using the slope of the tracer-tracer correlation of these species with CFC-11 at the tropopause. The correlation slopes were corrected for the changing atmospheric concentrations of each species based on age of air and CFC-11 measurements from samples taken aboard the Geophysica aircraft – along with the effective linear trend of the VMR from tropical ground-based AGAGE sites. Stratospheric lifetimes were calculated using a CFC-11 lifetime of 45 yr. These calculations produced values of 113 + (−) 26 (18) yr (CFC-12), 35 + (−) 11 (7) yr (CCl4), 195 + (−) 75 (42) yr (CH4), 69 + (−) 65 (23) yr (CH3Cl) and 123 + (−) 53 (28) yr (N2O). The errors on these values are the weighted 1-σ non-systematic errors. The stratospheric lifetime of CH3Cl represents the first calculations of the stratospheric lifetime of CH3Cl using data from a space based instrument.


2015 ◽  
Vol 8 (10) ◽  
pp. 11171-11207
Author(s):  
E. M. Buzan ◽  
C. A. Beale ◽  
C. D. Boone ◽  
P. F. Bernath

Abstract. This paper presents an analysis of observations of methane and its two major isotopologues, CH3D and 13CH4 from the Atmospheric Chemistry Experiment (ACE) satellite between 2004 and 2013. Additionally, atmospheric methane chemistry is modeled using the Whole Atmospheric Community Climate Model (WACCM). ACE retrievals of methane extend from 6 km for all isotopologues to 75 km for 12CH4, 35 km for CH3D, and 50 km for 13CH4. While total methane concentrations retrieved from ACE agree well with the model, values of δD–CH4 and δ13C–CH4 show a bias toward higher δ compared to the model and balloon-based measurements. Calibrating δD and δ13C from ACE using WACCM in the troposphere gives improved agreement in δD in the stratosphere with the balloon measurements, but values of δ13C still disagree. A model analysis of methane's atmospheric sinks is also performed.


2015 ◽  
Vol 15 (8) ◽  
pp. 4215-4224 ◽  
Author(s):  
G. E. Nedoluha ◽  
D. E. Siskind ◽  
A. Lambert ◽  
C. Boone

Abstract. While global stratospheric O3 has begun to recover, there are localized regions where O3 has decreased since 1991. Specifically, we use measurements from the Halogen Occultation Experiment (HALOE) for the period 1991–2005 and the NASA Aura Microwave Limb Sounder (MLS) for the period 2004–2013 to demonstrate a significant decrease in O3 near ~ 10 hPa in the tropics. O3 in this region is very sensitive to variations in NOy, and the observed decrease can be understood as a spatially localized, yet long-term increase in NOy. In turn, using data from MLS and from the Atmospheric Chemistry Experiment (ACE), we show that the NOy variations are caused by decreases in N2O which are likely linked to long-term variations in dynamics. To illustrate how variations in dynamics can affect N2O and O3, we show that by decreasing the upwelling in the tropics, more of the N2O can photodissociate with a concomitant increase in NOy production (via N2O + O(1D) → 2NO) at 10 hPa. Ultimately, this can cause an O3 decrease of the observed magnitude.


2013 ◽  
Vol 13 (14) ◽  
pp. 6921-6950 ◽  
Author(s):  
A. T. Brown ◽  
C. M. Volk ◽  
M. R. Schoeberl ◽  
C. D. Boone ◽  
P. F. Bernath

Abstract. Long lived halogen-containing compounds are important atmospheric constituents since they can act both as a source of chlorine radicals, which go on to catalyse ozone loss, and as powerful greenhouse gases. The long-term impact of these species on the ozone layer is dependent on their stratospheric lifetimes. Using observations from the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) we present calculations of the stratospheric lifetimes of CFC-12, CCl4, CH4, CH3Cl and N2O. The lifetimes were calculated using the slope of the tracer–tracer correlation of these species with CFC-11 at the tropopause. The correlation slopes were corrected for the changing atmospheric concentrations of each species based on age of air and CFC-11 measurements from samples taken aboard the Geophysica aircraft – along with the effective linear trend of the volume mixing ratio (VMR) from tropical ground based AGAGE (Advanced Global Atmospheric Gases Experiment) sites. Stratospheric lifetimes were calculated using a CFC-11 lifetime of 45 yr. These calculations produced values of 113 + (−) 26 (18) yr (CFC-12), 35 + (−) 11 (7) yr (CCl4), 69 + (−) 65 (23) yr (CH3Cl), 123 + (−) 53 (28) yr (N2O) and 195 + (−) 75 (42) yr (CH4). The errors on these values are the weighted 1σ non-systematic errors. Systematic errors were estimated by recalculating lifetimes using VMRs which had been modified to reflect differences between ACE-FTS retrieved VMRs and those from other instruments. The results of these calculations, including systematic errors, were as follows: 113 + (−) 32 (20) for CFC-12, 123 + (−) 83 (35) for N2O, 195 + (−) 139 (57) for CH4, 35 + (−) 14 (8) for CCl4 and 69 + (−) 2119 (34) yr for CH3Cl. For CH3Cl & CH4 this represents the first calculation of the stratospheric lifetime using data from a space based instrument.


2020 ◽  
Author(s):  
Patrick Sheese ◽  
Kaley Walker ◽  
Chris Boone ◽  
Laura Saunders ◽  
Sandip Dhomse ◽  
...  

<p>Since 2004, the Atmospheric Chemistry Experiment – Fourier Transform Spectrometer (ACE-FTS) instrument has been measuring concentrations of chlorofluorocarbons (CFCs) in the stratosphere and upper troposphere and is currently the only satellite instrument that measures vertically resolved profiles of CFC‑11. Since CFCs are major ozone depleting substances, monitoring their atmospheric abundances is critical for understanding ozone layer recovery. Recent studies based solely on surface-level measurements have shown strong evidence for new CFC‑11 production, leading to an increase in CFC‑11 emissions over the past decade. In this study, the TOMCAT/SLIMCAT 3-D chemical transport model is used in order to bridge the altitude/geolocation gap between ACE-FTS measurements in the UTLS and surface level measurements. Trends in two different time periods over the ACE-FTS mission, 2004-2012 and 2013-2018, are examined to determine if the recent change in surface level CFC-11 trends is influencing UTLS concentrations. The ACE-FTS measurements show that, below ~10 km, the rate of decrease of global CFC-11 concentrations was slower during 2013-2018 (-1.2 pptv/year) than during 2004-2012 (‑2.0 pptv/year). Similar trends are observed in the model data for the same spatial/temporal regions.</p>


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