Abstract. We simulated instrumental line shape (ILS) degradations with respect to
typical types of misalignment, and compared their influence on each NDACC
(Network for Detection of Atmospheric Composition Change) gas. The
sensitivities of the total column, the root mean square (rms) of the fitting residual,
the total random uncertainty, the total systematic uncertainty, the total uncertainty,
degrees of freedom for signal (DOFs), and the profile with respect to different
levels of ILS degradation for all current standard NDACC gases, i.e. O3, HNO3, HCl, HF, ClONO2, CH4, CO, N2O,
C2H6, and HCN, were investigated. The influence of an imperfect ILS
on NDACC gases' retrieval was assessed, and the consistency under different
meteorological conditions and solar zenith angles (SZAs) were examined. The
study concluded that the influence of ILS degradation can be approximated by
the linear sum of individual modulation efficiency (ME) amplitude influence
and phase error (PE) influence. The PE influence is of secondary importance
compared with the ME amplitude. Generally, the stratospheric gases are more
sensitive to ILS degradation than the tropospheric gases, and the positive ME
influence is larger than the negative ME. For a typical ILS degradation
(10 %), the total columns of stratospheric gases O3, HNO3, HCl,
HF, and ClONO2 changed by 1.9, 0.7, 4, 3, and 23 %,
respectively, while the columns of tropospheric gases CH4, CO, N2O,
C2H6, and HCN changed by 0.04, 2.1, 0.2, 1.1, and
0.75 %, respectively. In order to suppress the fractional difference in the total column for ClONO2 and other NDACC gases within 10 and 1 %,
respectively, the maximum positive ME degradations for O3, HNO3,
HCl, HF, ClONO2, CO, C2H6, and HCN should be less than 6,
15, 5, 5, 5, 5, 9, and 13 %, respectively; the
maximum negative ME degradations for O3, HCl, and HF should be less than
6, 12, and 12 %, respectively; the influence of ILS degradation on
CH4 and N2O can be regarded as being negligible.