Melt Percolation, Melt-Rock Reaction and Oxygen Fugacity in Supra-Subduction Zone Mantle and Lower Crust from the Leka Ophiolite Complex, Norway

2021 ◽  
Author(s):  
Brian O’Driscoll ◽  
Julien Leuthold ◽  
Davide Lenaz ◽  
Henrik Skogby ◽  
James M D Day ◽  
...  
Keyword(s):  
Single Crystal ◽  
Subduction Zone ◽  
Oxygen Fugacity ◽  
Lower Crust ◽  
Oceanic Lithosphere ◽  
Ophiolite Complex ◽  
Global Comparison ◽  
Oceanic Spreading ◽  
Melt Percolation ◽  
Lower Crustal

Abstract Samples of peridotites and pyroxenites from the mantle and lower crustal sections of the Leka Ophiolite Complex (LOC; Norway) are examined to investigate the effects of melt-rock reaction and oxygen fugacity variations in the sub-arc oceanic lithosphere. The LOC is considered to represent supra-subduction zone (SSZ) oceanic lithosphere, but also preserves evidence of pre-SSZ magmatic processes. Here we combine field and microstructural observations with mineral chemical and structural analyses of different minerals from the major lithologies of the LOC. Wehrlite and websterite bodies in both the mantle and lower crust contain clinopyroxene likely formed at a pre-SSZ stage, characterised by high Al, high Cr, low Mg crystal cores. These clinopyroxenes also exhibit low Al, low Cr, high Mg outer rims and intracrystalline dissolution surfaces, indicative of reactive melt percolation during intrusion and disruption of these lithologies by later, SSZ-related, dunite-forming magmas. Chromian-spinel compositional variations correlate with lithology; dunite-chromitite Cr-spinels are characterised by relatively uniform and high TiO2 and Al2O3, indicating formation by melt-rock reaction associated with SSZ processes. Harzburgite Cr-spinel compositions are more variable but preserve a relatively high Al2O3, low TiO2 endmember that may reflect crystallisation in a pre-SSZ oceanic spreading centre setting. An important finding of this study is that the LOC potentially preserves the petrological signature of a transition between oceanic spreading centre processes and subsequent supra-subduction zone magmatism. Single crystal Cr-spinel Fe3+/ΣFe ratios calculated on the basis of stoichiometry (from electron microprobe [EPMA] and crystal structural [X-ray diffraction; XRD] measurements) correlate variably with those calculated by point-source (single crystal) Mössbauer spectroscopy. Average sample EPMA Fe3+/ΣFe ratios overestimate or underestimate the Mössbauer-derived values for harzburgites, and always overestimate the Mössbauer Fe3+/ΣFe ratios for dunites and chromitites. The highest Fe3+/ΣFe ratios, irrespective of method of measurement, are therefore generally associated with dunites and chromitites, and yield calculated log(fO2)FMQ values of up to ~+1.8. While this lends support to the formation of the dunites and chromitites during SSZ-related melt percolation in the lower part of the LOC, it also suggests that these melts were not highly oxidised, compared to typical arc basalts (fO2FMQ of >+2). This may in turn reflect the early (forearc) stage of subduction zone activity preserved by the LOC and implies that some of the arc tholeiitic and boninitic lava compositions preserved in the upper portion of the ophiolite are not genetically related to the mantle and lower crustal rocks, against which they exhibit tectonic contacts. Our new data also have implications for the use of ophiolite chromitites as recorders of mantle oxidation state through time; a global comparison suggests that the Fe3+/ΣFe signatures of ophiolite chromitites are likely to have more to do with local environmental petrogenetic conditions in sub-arc systems than large length-scale mantle chemical evolution.

Unravelling the Remagnetization of the Oman Ophiolite

2020 ◽  
Author(s):  
Louise Koornneef ◽  
Antony Morris ◽  
Michelle Harris ◽  
Christopher MacLeod
Keyword(s):  
Subduction Zone ◽  
Large Scale ◽  
Oceanic Lithosphere ◽  
Magnetic Fabric ◽  
Oman Ophiolite ◽  
Mantle Peridotites ◽  
Important Exception ◽  
Magnetic Techniques ◽  
Tectonic Rotation ◽  
Lower Crustal

<p>The Oman ophiolite is a natural laboratory for the study of processes operating above a nascent subduction zone. It formed in the Late Cretaceous by supra-subduction zone spreading and shortly afterwards was emplaced onto the Arabian continental margin. Twelve massifs in the ophiolite expose complete sections of the Neotethyan oceanic lithosphere, including upper mantle peridotites, lower crustal gabbros, and upper crustal sheeted dykes and lava flows.</p><p> </p><p>Previous palaeomagnetic studies have suggested that the southern massifs of the ophiolite were affected by a large-scale remagnetization event during emplacement, that completely replaced original remanences acquired during crustal accretion. In contrast, primary magnetizations are preserved throughout the northern massifs. This study aimed to: (i) apply palaeomagnetic, magnetic fabric and rock magnetic techniques to analyse crustal sections through the southern massifs of the Oman ophiolite to investigate further the extent and nature of this remagnetization event; and (ii) use any primary magnetizations that survived this event to document intraoceanic rotation of the ophiolite prior to emplacement.</p><p> </p><p>Our new data confirms that remagnetization appears to have been pervasive throughout the southern massifs, resulting in presence of shallowly-inclined NNW directions of magnetization at all localities. An important exception is the crustal section exposed in Wadi Abyad (Rustaq massif) where directions of magnetization change systematically through the gabbro-sheeted dyke transition. Demagnetization characteristics are shown to be consistent with acquisition of a chemical remanent overprint that decreased in intensity from the base of the ophiolite upwards. The top of the exposed Wadi Abyad section (in the sheeted dyke complex) appears to preserve original SE-directed remanences that are interpreted as primary seafloor magnetizations. Similar SE primary remanences were also isolated at a control locality in the Salahi massif, outside of the region of remagnetization. Net tectonic rotation analysis at these non-remagnetised sites shows an initial NNE-SSW strike for the supra-subduction zone ridge during spreading, comparable with recently published models for the regional evolution of the ophiolite.</p>

Structural evolution in the Moine of northwest Scotland: a Caledonian linked thrust system?

1986 ◽  
Vol 123 (1) ◽  
pp. 1-11 ◽  
Author(s):  
Robert W. H. Butler
Keyword(s):  
Cross Sections ◽  
Lower Crust ◽  
Structural Evolution ◽  
Amphibolite Facies ◽  
Metamorphic Basement ◽  
Thrust System ◽  
Lower Crustal

AbstractA model is proposed whereby the Caledonian metamorphic basement-cover complex of northwest Scotland (the Moine) is considered as a linked thrust system. This system lies between the Moine thrust at its base and the Naver–Sgurr Beag slide at its top. Ductile fold and thrust zones, which developed at mid crustal levels at metamorphic grades from greenschist to amphibolite facies, are interpreted as decoupling from a detachment presently situated at relatively shallow depths. This model is illustrated by two preliminary balanced cross-sections. These imply shortening across the northwest Scottish Caledonides in excess of 130 km and probably over 200 km. When these structures are restored onto a crustal template a considerable quantity of lower crust is found to be required at depth. The most likely location for the lower crustal wedge is beneath the Grampian Highlands.

Relative roles of source composition, fractional crystallization and crustal contamination in the petrogenesis of Andean volcanic rocks

1984 ◽  
Vol 310 (1514) ◽  
pp. 675-692 ◽  
Keyword(s):  
Subduction Zone ◽  
Continental Crust ◽  
Fractional Crystallization ◽  
Magma Mixing ◽  
Volcanic Rocks ◽  
Crustal Contamination ◽  
Oceanic Lithosphere ◽  
Alkaline Basalt ◽  
Complex Process ◽  
Heterogeneous Mantle

There are well established differences in the chemical and isotopic characteristics of the calc-alkaline basalt—andesite-dacite-rhyolite association of the northern (n.v.z.), central (c.v.z.) and southern volcanic zones (s.v.z.) of the South American Andes. Volcanic rocks of the alkaline basalt-trachyte association occur within and to the east of these active volcanic zones. The chemical and isotopic characteristics of the n.v.z. basaltic andesites and andesites and the s.v.z. basalts, basaltic andesites and andesites are consistent with derivation by fractional crystallization of basaltic parent magmas formed by partial melting of the asthenospheric mantle wedge containing components from subducted oceanic lithosphere. Conversely, the alkaline lavas are derived from basaltic parent magmas formed from mantle of ‘within-plate’ character. Recent basaltic andesites from the Cerro Galan volcanic centre to the SE of the c.v.z. are derived from mantle containing both subduction zone and within-plate components, and have experienced assimilation and fractional crystallization (a.f.c.) during uprise through the continental crust. The c.v.z. basaltic andesites are derived from mantle containing subduction-zone components, probably accompanied by a.f.c. within the continental crust. Some c.v.z. lavas and pyroclastic rocks show petrological and geochemical evidence for magma mixing. The petrogenesis of the c.v.z. lavas is therefore a complex process in which magmas derived from heterogeneous mantle experience assimilation, fractional crystallization, and magma mixing during uprise through the continental crust.

scholarly journals The Role of Lower Crustal Rheology in Lithospheric Delamination During Orogeny

2021 ◽  
Vol 9 ◽  
Author(s):  
Lin Chen
Keyword(s):  
Lower Crust ◽  
Numerical Models ◽  
The Tibetan Plateau ◽  
Mantle Lithosphere ◽  
Laboratory Studies ◽  
Surface Uplift ◽  
Continental Lower Crust ◽  
Lower Crustal ◽  
Flow Laws

The continental lower crust is an important composition- and strength-jump layer in the lithosphere. Laboratory studies show its strength varies greatly due to a wide variety of composition. How the lower crust rheology influences the collisional orogeny remains poorly understood. Here I investigate the role of the lower crust rheology in the evolution of an orogen subject to horizontal shortening using 2D numerical models. A range of lower crustal flow laws from laboratory studies are tested to examine their effects on the styles of the accommodation of convergence. Three distinct styles are observed: 1) downwelling and subsequent delamination of orogen lithosphere mantle as a coherent slab; 2) localized thickening of orogen lithosphere; and 3) underthrusting of peripheral strong lithospheres below the orogen. Delamination occurs only if the orogen lower crust rheology is represented by the weak end-member of flow laws. The delamination is followed by partial melting of the lower crust and punctuated surface uplift confined to the orogen central region. For a moderately or extremely strong orogen lower crust, topography highs only develop on both sides of the orogen. In the Tibetan plateau, the crust has been doubly thickened but the underlying mantle lithosphere is highly heterogeneous. I suggest that the subvertical high-velocity mantle structures, as observed in southern and western Tibet, may exemplify localized delamination of the mantle lithosphere due to rheological weakening of the Tibetan lower crust.

Thermodynamic constraints on assimilation of silicic crust by primitive magmas

2021 ◽  
Author(s):  
Jussi S Heinonen ◽  
Frank J Spera ◽  
Wendy A Bohrson
Keyword(s):  
Phase Equilibria ◽  
Lower Crust ◽  
Primitive Mantle ◽  
Upper Crust ◽  
Basaltic Composition ◽  
Primitive Magma ◽  
Partial Melts ◽  
Thermodynamic Limits ◽  
Melt Composition ◽  
Lower Crustal

<p>Some studies on basaltic and more primitive rocks suggest that their parental magmas have assimilated more than 50 wt.% (relative to the initial uncontaminated magma) of crustal silicate wallrock. But what are the thermodynamic limits for assimilation by primitive magmas? This question has been considered for over a century, first by N.L. Bowen and many others since then. Here we pursue this question quantitatively using a freely available thermodynamic tool for phase equilibria modeling of open magmatic systems — the Magma Chamber Simulator (MCS; https://mcs.geol.ucsb.edu).</p><p>In the models, komatiitic, picritic, and basaltic magmas of various ages and from different tectonic settings assimilate progressive partial melts of average lower, middle, and upper crust. In order to pursue the maximum limits of assimilation constrained by phase equilibria and energetics, the mass of wallrock in the simulations was set at twice that of the initially pristine primitive magmas. In addition, the initial temperature of wallrock was set close to its solidus at a given pressure. Such conditions would approximate a rift setting with tabular chambers and high magma input causing concomitant crustal heating and steep geotherms.</p><p>Our results indicate that it is difficult for any primitive magma to assimilate more than 20−30 wt.% of upper crust before evolving to intermediate/felsic compositions. However, if assimilant is lower crust, typical komatiitic magmas can assimilate more than their own weight (range of 59−102 wt.%) and retain a basaltic composition. Even picritic magmas, more relevant to modern intraplate settings, have a thermodynamic potential to assimilate 28−49 wt.% of lower crust before evolving into intermediate/felsic compositions.</p><p>These findings have important implications for petrogenesis of magmas. The parental melt composition and the assimilant heavily influence both how much assimilation is energetically possible in primitive magmas and the final magma composition. The fact that primitive mantle melts have potential to partially melt and assimilate significant fractions of (lower) crust may have fundamental importance for how trans-Moho magmatic systems evolve and how crustal growth is accomplished. Examples include generation of siliceous high-magnesium basalts in the Precambrian and anorogenic anorthosite-mangerite-charnockite-granite complexes with geochemical evidence of considerable geochemical overprint from (lower) crustal sources.</p>

Subduction initiation-induced rapid emplacement of garnet-bearing peridotites at a nascent forearc: Petrological and Os-Li isotopic evidence from the Purang ophiolite, Tibet

2021 ◽  
Author(s):  
Xiao-Han Gong ◽  
Ji-Feng Xu ◽  
Ren-Deng Shi ◽  
Ben-Xun Su ◽  
Qi-Shuai Huang ◽  
...  
Keyword(s):  
Oceanic Lithosphere ◽  
Garnet Peridotite ◽  
Chemical Compositions ◽  
Close Link ◽  
Geological Evidence ◽  
Subduction Initiation ◽  
Mid Ocean Ridge ◽  
Rapid Ascent ◽  
Melt Percolation ◽  
Ocean Ridge

Garnet-bearing peridotites commonly occur in the deeper parts of mature or thickened oceanic lithosphere, and are rarely exhumed and emplaced onto the seafloor. The Purang ophiolitic peridotites in south Tibet contain rare symplectite pseudomorphs after garnet, offering a unique window into the still poorly understood evolution of the deep oceanic lithosphere. Here, integrated petrologic and Os-Li isotopic data are used to constrain the evolution and dynamics of emplacement for these garnet peridotite protoliths. The Purang peridotites show wide variations of chemical compositions (spinel Cr#: 0.2−0.8) and Os model ages (up to 2.0 Ga), thus representing a piece of heterogeneous oceanic mantle lithosphere. Dunite channels show two distinctive groups of Cr# of spinels and Os-isotope compositions, with the low- to medium-Cr# (0.2−0.6) and high-Cr# (0.7−0.8) dunites reflecting the reaction of host lherzolites/harzburgites with percolating mid-ocean ridge basalt−like and boninitic melts, respectively. This confirms recent subduction initiation-related melt percolation in the Purang peridotites. Coexisting olivines and pyroxenes in the peridotites show systematic Li elemental and isotopic disequilibrium, suggesting fast cooling of the peridotites to Li closure temperature shortly after the melt percolations, likely during exhumation of the peridotites onto the seafloor. This supports a close link between subduction initiation and tectonic emplacement of the Purang peridotites. Combined with other geological evidence, we suggest the Purang peridotites may originate from the deep part of old, thick oceanic lithosphere of the Neo-Tethys. This thick oceanic lithosphere was progressively weakened and thinned likely during widespread plume-lithosphere interaction, triggering the transformation of garnet peridotite protoliths to spinel peridotites. Subsequently, initiation of a new subduction zone along the lithospheric weakness caused rapid ascent and emplacement of the Purang peridotites at a nascent forearc.

scholarly journals Ophiolitic Pyroxenites Record Boninite Percolation in Subduction Zone Mantle

Minerals ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 565 ◽  
Author(s):  
Véronique Le Roux ◽  
Yan Liang
Keyword(s):  
Subduction Zone ◽  
Subduction Zones ◽  
Mantle Wedge ◽  
Major Element ◽  
Early Stage ◽  
Diffusion Modeling ◽  
Melt Infiltration ◽  
Melt Percolation ◽  
Back Arc ◽  
Parental Melts

The peridotite section of supra-subduction zone ophiolites is often crosscut by pyroxenite veins, reflecting the variety of melts that percolate through the mantle wedge, react, and eventually crystallize in the shallow lithospheric mantle. Understanding the nature of parental melts and the timing of formation of these pyroxenites provides unique constraints on melt infiltration processes that may occur in active subduction zones. This study deciphers the processes of orthopyroxenite and clinopyroxenite formation in the Josephine ophiolite (USA), using new trace and major element analyses of pyroxenite minerals, closure temperatures, elemental profiles, diffusion modeling, and equilibrium melt calculations. We show that multiple melt percolation events are required to explain the variable chemistry of peridotite-hosted pyroxenite veins, consistent with previous observations in the xenolith record. We argue that the Josephine ophiolite evolved in conditions intermediate between back-arc and sub-arc. Clinopyroxenites formed at an early stage of ophiolite formation from percolation of high-Ca boninites. Several million years later, and shortly before exhumation, orthopyroxenites formed through remelting of the Josephine harzburgites through percolation of ultra-depleted low-Ca boninites. Thus, we support the hypothesis that multiple types of boninites can be created at different stages of arc formation and that ophiolitic pyroxenites uniquely record the timing of boninite percolation in subduction zone mantle.

scholarly journals Geology, Geochronology and Geochemistry of Weilasituo Sn-Polymetallic Deposit in Inner Mongolia, China

Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 104 ◽  
Author(s):  
Fan Yang ◽  
Jinggui Sun ◽  
Yan Wang ◽  
Junyu Fu ◽  
Fuchao Na ◽  
...  
Keyword(s):  
Pacific Ocean ◽  
Lower Crust ◽  
Structural Evolution ◽  
Magma Source ◽  
Crustal Material ◽  
Quartz Porphyry ◽  
Polymetallic Deposit ◽  
High Concentrations ◽  
Great Xing’An Range ◽  
Lower Crustal

The recently discovered Weilasituo Sn-polymetallic deposit in the Great Xing’an Range is an ultralarge porphyry-type deposit. The mineralization is closely associated with an Early Cretaceous quartz porphyry. Analysis of quartz porphyry samples, including zircon U-Pb dating and Hf isotopies, geochemical and molybdenite Re-Os isotopic testing, reveals a zircon U-Pb age of 138.6 ± 1.1 Ma and a molybdenite Re-Os isotopic age of 135 ± 7 Ma, suggesting the concurrence of the petrogenetic and metallogenic processes. The quartz porphyry has high concentrations of SiO2 (71.57 wt %–78.60 wt %), Al2O3 (12.69 wt %–16.32 wt %), and K2O + Na2O (8.85 wt %–10.44 wt %) and A/CNK ratios from 0.94–1.21, is mainly peraluminous, high-K calc-alkaline I-type granite and is relatively rich in LILEs (large ion lithophile elements, e.g., Th, Rb, U and K) and HFSEs (high field strength elements, e.g., Hf and Zr) and relatively poor in Sr, Ba, P, Ti and Nb. The zircon εHf(t) values range from 1.90 to 6.90, indicating that the magma source materials were mainly derived from the juvenile lower crust and experienced mixing with mantle materials. Given the regional structural evolution history, we conclude that the ore-forming magma originated from lower crust that had thickened and delaminated is the result of the subduction of the Paleo–Pacific Ocean. Following delamination, the lower crustal material entered the underlying mantle, where it was partially melted and reacted with mantle during ascent. The deposit formed at a time of transition from post-orogenic compression to extension following the subduction of the Paleo–Pacific Ocean.

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