The stability of gaseous lithium hydroxide at high temperatures and its relation with the hydroxyl concentration of flame gases

1953 ◽  
Vol 219 (1137) ◽  
pp. 204-215 ◽  
Keyword(s):  
Hydroxyl Radicals ◽  
Thermal Equilibrium ◽  
Alkali Metals ◽  
Lithium Hydroxide ◽  
The Other ◽  
Theoretical Treatment ◽  
Free Hydroxyl ◽  
The Stability ◽  
Comparison Of The Results ◽  
Fair Degree

The techniques developed by Sugden and collaborators have been applied to the measurement of the ionization resulting from the addition of lithium compounds to hydrogen/air flames. Comparison of the results with those for the other alkali metals shows that lithium gives many too few electrons, and it is suggested, as a result of a comparison of the hydroxides and halides, that this is due to the removal of a large proportion of the lithium as gaseous hydroxide. A quantitative test of this hypothesis shows a very marked agreement with theoretical treatment. The consistency is such that the method appears to be very suitable for the estimation of the concentration of free hydroxyl radicals in flame gases, provided that a fair degree of thermal equilibrium obtains.

Photometric investigations of alkali metals in hydrogen flame gases - II. The study of excess concentrations of hydrogen atoms in burnt gas mixtures

1956 ◽  
Vol 235 (1200) ◽  
pp. 89-106 ◽  
Keyword(s):  
Hydroxyl Radicals ◽  
Alkali Metals ◽  
Equilibrium Constants ◽  
The Other ◽  
Large Excess ◽  
Hydrogen Atoms ◽  
Free Hydrogen ◽  
Hydrogen Flame ◽  
Photometric Measurements ◽  
Oxygen Flame

Photometric measurements on alkali metals in hydrogen-oxygen flame gases, diluted with various proportions of nitrogen, are interpreted as giving a measure of the concentration of free hydrogen atoms, which persist in these gases for several milliseconds after primary combustion. These concentrations are well in excess of those expected from thermodynamic equilibrium, especially towards the lower end of the range of temperatures studied (2400 to 1600°K). Two kinds of measurement have been made. (i) Comparison of the intensities of the Na D lines and the Li resonance doublets, for equal traces of the two elements present in the gases. The amount of free lithium is modified by the balanced process, Li + H 2 O ⇌ LiOH + H, whereas corresponding reactions for sodium are negligible. Using estimated equilibrium constants for these reactions, [H] can be obtained. (ii) Measurements of the change in intensity of the Na D lines when 0∙01 to 0∙5% of chlorine or its compounds (a large excess over the sodium) are added to the flame gases. NaCl is considered to be formed by the balanced reactions Na + HCl ⇌ NaCl + H. The concentration of HCl, the most important chlorine compound in the hydrogen-rich flame gases, may be obtained from the total chlorine added. Using estimated equilibrium constants for the above reaction, [H] can again be obtained. The agreement between the [H] values obtained by these two independent methods is good. The decrease of [H] with height in the gases is consistent with ternary recombination towards full equilibrium. A general discussion of excess radical concentrations in hydrogen flame gases is given, for hydroxyl radicals and oxygen atoms as well as hydrogen atoms. The conclusions reached are supported by experimental evidence. A further discussion of the way in which the amounts of chlorine used in the experiments may affect the other radical concentrations is given.

Uniformity of Magnification from Different Electron Microscopes

1967 ◽  
Vol 25 ◽  
pp. 32-33
Author(s):  
Godfrey C. Hoskins ◽  
V. Williams ◽  
V. Allison
Keyword(s):  
Diffraction Grating ◽  
The Other ◽  
Carbon Replica ◽  
Electron Microscopes ◽  
The Stability

The method demonstrated is an adaptation of a proven procedure for accurately determining the magnification of light photomicrographs. Because of the stability of modern electrical lenses, the method is shown to be directly applicable for providing precise reproducibility of magnification in various models of electron microscopes.A readily recognizable area of a carbon replica of a crossed-line diffraction grating is used as a standard. The same area of the standard was photographed in Phillips EM 200, Hitachi HU-11B2, and RCA EMU 3F electron microscopes at taps representative of the range of magnification of each. Negatives from one microscope were selected as guides and printed at convenient magnifications; then negatives from each of the other microscopes were projected to register with these prints. By deferring measurement to the print rather than comparing negatives, correspondence of magnification of the specimen in the three microscopes could be brought to within 2%.

Thermodynamic Stability of Hexagonal and Rhombohedral Bn at Cvd Conditions from Van der Waals Corrected First Principles Calculations

2019 ◽  
Author(s):  
Henrik Pedersen ◽  
Björn Alling ◽  
Hans Högberg ◽  
Annop Ektarawong
Keyword(s):  
Thin Films ◽  
Thermodynamic Stability ◽  
First Principles ◽  
Thermal Equilibrium ◽  
Density Functional ◽  
Van Der Waals ◽  
Chemical Vapor ◽  
First Principles Calculations ◽  
Functional Theory ◽  
The Stability

Thin films of boron nitride (BN), particularly the sp<sup>2</sup>-hybridized polytypes hexagonal BN (h-BN) and rhombohedral BN (r-BN) are interesting for several electronic applications given band gaps in the UV. They are typically deposited close to thermal equilibrium by chemical vapor deposition (CVD) at temperatures and pressures in the regions 1400-1800 K and 1000-10000 Pa, respectively. In this letter, we use van der Waals corrected density functional theory and thermodynamic stability calculations to determine the stability of r-BN and compare it to that of h-BN as well as to cubic BN and wurtzitic BN. We find that r-BN is the stable sp<sup>2</sup>-hybridized phase at CVD conditions, while h-BN is metastable. Thus, our calculations suggest that thin films of h-BN must be deposited far from thermal equilibrium.

Temperature and its measurement

2017 ◽  
Author(s):  
Andrew Clarke
Keyword(s):  
Thermal Equilibrium ◽  
Isotope Fractionation ◽  
Thermodynamic Temperature ◽  
The Other ◽  
Deterministic Models ◽  
Triple Point Of Water ◽  
Temperature Scales ◽  
Classical Thermodynamics ◽  
The Relationship ◽  
Unit Of Temperature

Temperature is that property of a body which determines whether it gains or loses energy in a particular environment. In classical thermodynamics temperature is defined by the relationship between energy and entropy. Temperature can be defined only for a body that is in thermodynamic and thermal equilibrium; whilst organisms do not conform to these criteria, the errors in assuming that they do are generally small. The Celsius and Fahrenheit temperature scales are arbitrary because they require two fixed points, one to define the zero and the other to set the scale. The thermodynamic (absolute) scale of temperature has a natural zero (absolute zero) and is defined by the triple point of water. Its unit of temperature is the Kelvin. The Celsius scale is convenient for much ecological and physiological work, but where temperature is included in statistical or deterministic models, only thermodynamic temperature should be used. Past temperatures can only be reconstructed with the use of proxies, the most important of which are based on isotope fractionation.

scholarly journals Black Hole Algorithm for Sustainable Design of Counterfort Retaining Walls

2020 ◽  
Vol 12 (7) ◽  
pp. 2767 ◽  
Author(s):  
Víctor Yepes ◽  
José V. Martí ◽  
José García
Keyword(s):  
Black Hole ◽  
Sustainable Design ◽  
Retaining Walls ◽  
The Other ◽  
Trade Off ◽  
Construction Company ◽  
Geometric Variables ◽  
The Stability ◽  
The Cost ◽  
Black Hole Algorithm

The optimization of the cost and CO 2 emissions in earth-retaining walls is of relevance, since these structures are often used in civil engineering. The optimization of costs is essential for the competitiveness of the construction company, and the optimization of emissions is relevant in the environmental impact of construction. To address the optimization, black hole metaheuristics were used, along with a discretization mechanism based on min–max normalization. The stability of the algorithm was evaluated with respect to the solutions obtained; the steel and concrete values obtained in both optimizations were analyzed. Additionally, the geometric variables of the structure were compared. Finally, the results obtained were compared with another algorithm that solved the problem. The results show that there is a trade-off between the use of steel and concrete. The solutions that minimize CO 2 emissions prefer the use of concrete instead of those that optimize the cost. On the other hand, when comparing the geometric variables, it is seen that most remain similar in both optimizations except for the distance between buttresses. When comparing with another algorithm, the results show a good performance in optimization using the black hole algorithm.

The aqueous photochemistry of sodium 9,10-anthraquinone-2-sulfonate

1976 ◽  
Vol 54 (4) ◽  
pp. 512-515 ◽  
Author(s):  
James Leslie Charlton ◽  
Rhonda Gail Smerchanski ◽  
Charles Eugene Burchill
Keyword(s):  
Hydroxyl Radicals ◽  
Free Hydroxyl

The aqueous photochemistry of sodium 9,10-anthraquinone-2-sulfonate is described and a new mechanism for the photohydroxylation is proposed. The participation of kinetically free hydroxyl radicals is ruled out.

Label-free proteomic analysis revealed the mechanisms of protein oxidation induced by hydroxyl radicals in whiteleg shrimp (Litopenaeus vannamei) muscle

2021 ◽  
Author(s):  
Hui-min Lin ◽  
Xue-er Qi ◽  
Shan-shan Shui ◽  
Soottawat Benjakul ◽  
Santiago P. Aubourg ◽  
...  
Keyword(s):  
Ascorbic Acid ◽  
Hydroxyl Radicals ◽  
Litopenaeus Vannamei ◽  
Protein Oxidation ◽  
Proteomic Analysis ◽  
Muscle Proteins ◽  
Label Free ◽  
Whiteleg Shrimp ◽  
The Stability ◽  
Oxidative Effects

The oxidative effects of hydroxyl radicals derived from a FeCl3/ascorbic acid/H2O2 system on the stability of muscle proteins in peeled shrimp (Litopenaeus vannamei) were investigated.

scholarly journals A Fractional SAIDR Model in the Frame of Atangana–Baleanu Derivative

2021 ◽  
Vol 5 (2) ◽  
pp. 32
Author(s):  
Esmehan Uçar ◽  
Sümeyra Uçar ◽  
Fırat Evirgen ◽  
Necati Özdemir
Keyword(s):  
Existence And Uniqueness ◽  
Laplace Transformation ◽  
Cell Phones ◽  
Mobile Network ◽  
The Other ◽  
Banach Fixed Point Theorem ◽  
Propagation Models ◽  
Computer Worms ◽  
Computer Viruses ◽  
The Stability

It is possible to produce mobile phone worms, which are computer viruses with the ability to command the running of cell phones by taking advantage of their flaws, to be transmitted from one device to the other with increasing numbers. In our day, one of the services to gain currency for circulating these malignant worms is SMS. The distinctions of computers from mobile devices render the existing propagation models of computer worms unable to start operating instantaneously in the mobile network, and this is particularly valid for the SMS framework. The susceptible–affected–infectious–suspended–recovered model with a classical derivative (abbreviated as SAIDR) was coined by Xiao et al., (2017) in order to correctly estimate the spread of worms by means of SMS. This study is the first to implement an Atangana–Baleanu (AB) derivative in association with the fractional SAIDR model, depending upon the SAIDR model. The existence and uniqueness of the drinking model solutions together with the stability analysis are shown through the Banach fixed point theorem. The special solution of the model is investigated using the Laplace transformation and then we present a set of numeric graphics by varying the fractional-order θ with the intention of showing the effectiveness of the fractional derivative.

scholarly journals Competing Conventions with Costly Information Acquisition

Games ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 53
Author(s):  
Roberto Rozzi
Keyword(s):  
Information Acquisition ◽  
Evolutionary Model ◽  
Equilibrium Selection ◽  
The Other ◽  
Group Interactions ◽  
Social Coordination ◽  
Long Run ◽  
Stochastic Stability Analysis ◽  
The Stability ◽  
The Cost

We consider an evolutionary model of social coordination in a 2 × 2 game where two groups of players prefer to coordinate on different actions. Players can pay a cost to learn their opponent’s group: if they pay it, they can condition their actions concerning the groups. We assess the stability of outcomes in the long run using stochastic stability analysis. We find that three elements matter for the equilibrium selection: the group size, the strength of preferences, and the information’s cost. If the cost is too high, players never learn the group of their opponents in the long run. If one group is stronger in preferences for its favorite action than the other, or its size is sufficiently large compared to the other group, every player plays that group’s favorite action. If both groups are strong enough in preferences, or if none of the groups’ sizes is large enough, players play their favorite actions and miscoordinate in inter-group interactions. Lower levels of the cost favor coordination. Indeed, when the cost is low, in inside-group interactions, players always coordinate on their favorite action, while in inter-group interactions, they coordinate on the favorite action of the group that is stronger in preferences or large enough.

A Biomechanical Evaluation of Three Forms of Internal Fixation Used in Ankle Arthrodesis

1994 ◽  
Vol 15 (6) ◽  
pp. 297-300 ◽  
Author(s):  
Michael P. Dohm ◽  
James B. Benjamin ◽  
Jeffrey Harrison ◽  
John A. Szivek
Keyword(s):  
Internal Fixation ◽  
Plate Fixation ◽  
Ankle Arthrodesis ◽  
Biomechanical Study ◽  
The Other ◽  
Fixation Failure ◽  
Plate Group ◽  
Biomechanical Evaluation ◽  
The Stability ◽  
Fibular Strut

A biomechanical study was undertaken to evaluate the relative stability of three types of internal fixation used for ankle arthrodesis. Crossed screw fixation, RAF fibular strut fixation, and T-plate fixation were tested in 30 cadaver ankles using an MTS machine. T-plate fixation consistantly provided the stiffest construct when compared with the other types of fixation. Failure occurred by distraction of bony surfaces, posterior to the plane of fixation, in the crossed screw and RAF groups. In contrast, failure in the T-plate group occurred through compression of bone anterior to the midcoronal plane of the tibia. Although the stability of fixation is only one factor in determining the success or failure of ankle arthrodesis, the results of this study would support T-plate fixation over the other forms tested.

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