scholarly journals XX. Experiments on contact electricity between non-conductors

1877 ◽  
Vol 25 (171-178) ◽  
pp. 169-171 ◽  

It was observed that when a plate of copper was lifted from a plate of glass the copper was electrified, and also that when a plate of glass was lifted from a plate of wax the glass was electrified, care being taken to have as little friction as possible; it was afterwards found that the former experiment had already been made by Fechner (see Wiedemann’s ‘Gal-vanismus, page 21), who also tried lifting copper from sulphur and got the same effect; although the plates were lifted as carefully as possible, yet- it was not certain that friction had been entirely got rid of, so the following experiments were made to show that there is an electrical displacement when two non-conductors or a conductor and a non-conductor are put in contact without friction. The arrangement used was as follows:— Glass rods, AB, CD, EF, GH, were fixed in a wooden frame ACGE; round these rods silk threads, BF, DH, were wound; an aluminium needle carrying a mirror, M, was hung by a silk thread from a brass rod, T, fastened in the wooden frame; a wire from the needle dipped into a glass vessel, N, containing sulphuric acid; a small magnet was fastened to the back of the mirror, and a glass case wTas placed over the whole; outside the glass case were magnets, by means of which the position of the needle was regulated; a wire also from the outside dipped into the vessel N, and was used to charge the needle with electricity; positive electricity was got from an ordinary electrophorus, negative from an electrophorus in which the resin was replaced by a plate of glass which was excited by silk. If wax and glass were the substances experimented on; a cake, OQRP, was made, one half of which, OSQ, was glass, the other half, RPS, being wax; the junction of the wax and glass was parallel to OQ, the wax sticking fast to the glass: this cake was then placed on the silk threads under the needle, and it was found possible to bring the needle into such a position that when it was charged with positive electricity it was deflected from the glass part of the cake, when charged with negative it was attracted towards it. In order to get rid of any electricity which might have got on the cake in the making, the cake was made the day before it was placed on the threads, and the experiment was made at least a day, sometimes a week, after putting the cake on the threads; pieces of glass and sulphur which had been treated in as nearly as possible the same way as those of which the cakes were made were taken and placed separately on the threads, but no electricity could be detected on them.

1913 ◽  
Vol 32 ◽  
pp. 12-16
Author(s):  
Alexander Charles Cumming ◽  
E. W. Hamilton Smith

So many papers have appeared on this subject that some apology seems desirable before making an additional contribution. The amount of published work on reduction with sulphurous acid is in itself an indication that many workers have found difficulties. It has been shown that the reduction does not take place in presence of large excess of hydrochloric or sulphuric acid, but the reduction will still occur while the reaction of the solution is strongly acid. On the other hand, Hillebrand (“Analysis of Silicate and Carbonate Rocks,” U.S. Bulletin, 442, p. 113) states if the solution after addition of sulphite is red in colour, it is too alkaline and acid must be added.


1838 ◽  
Vol 128 ◽  
pp. 79-81 ◽  

1307. I Have recently put into an experimental form that general statement of the question of specific inductive capacity which is given at No. 1252 of Series XI., and the result is such as to lead me to hope the Council will authorise its addition to the paper in the form of a supplementary note. Three circular brass plates, about five inches in diameter, were mounted side by side upon insulating pillars; the middle one, A, was a fixture, but the outer plates B and C were moveable on slides, so that all three could be brought with their sides almost into contact, or separated to any required distance. Two gold leaves were suspended in a glass jar from insulated wires; one of the outer plates B was connected with one of the gold leaves, and the other outer plate with the other leaf. The outer plates B and C were adjusted at the distance of an inch and a quarter from the middle plate A, and the gold leaves were fixed at two inches apart; A was then slightly charged with electricity, and the plates B and C, with their gold leaves, thrown out of insulation at the same time , and then left insulated. In this state of things A was charged positive inductrically, and B with C negative inducteously; the same dielectric, air, being in the two intervals, and the gold leaves hanging, of course, parallel to each other in a relatively unelectrified state. 1308. A plate of shell-lac three quarters of an inch in thickness, and four inches square, suspended by clean white silk thread, was very carefully deprived of all charge (1203.), so that it produced no effect on the gold leaves if A were uncharged, and then introduced between plates A and B; the electric relation of the three plates was immediately altered, and the gold leaves attracted each other. On removing the shell-lac this attraction ceased; on introducing it between A and C it was renewed; on removing it the attraction again ceased; and the shell-lac when examined by a delicate Coulomb electrometer was still without charge.


1890 ◽  
Vol 46 (280-285) ◽  
pp. 372-376 ◽  

About fourteen months ago we had the honour of communicating to the Society (‘Roy. Soc. Proc.,’ vol. 44, p. 182) the results of a large number of experiments made with electromotor cells, of which a special feature was that one of the plates of the combination consisted of an “aeration plate,” or layer of conducting material exposed to the atmosphere, and consequently superficially charged with a film of condensed air, which served as a means of indirectly effecting the oxidation of the other plate (when made of oxidisable metal), or of the fluid surrounding it (when the plate is of non-oxidisable material immersed in an oxidisable fluid). We showed that the E. M. F. of a given combination varies very considerably with the nature of the material of which the aeration plate is made, surfaces of platinum sponge, and especially platinum black, yielding the highest results when the electrolyte is dilute sulphuric acid; a convenient way of constructing the plates being to apply the spongy metal to the surface of unglazed earthenware, or other similar porous non-conducting material, so as to form a conducting film, the electrolytic fluid being absorbed in the porous material and so making contact.


1815 ◽  
Vol 105 ◽  
pp. 203-213 ◽  

In the two papers containing researches on iodine which the Royal Society has done me the honour of publishing in the Transactions, I have described a class of bodies consisting of iodine, oxygene, and different bases analogous to the hyper-oxymuriates. In the last of these papers, I mentioned, that I had not been able to procure any binary combination of iodine and oxygene from these compounds, neither by the method proposed by M. Gay Lussac, namely, the action of sulphuric acid on the oxyiode of barium, nor by other methods of my own institution; and that in experiments on the effects of the acids on the oxyiodes, new combinations only were formed. I have lately resumed this enquiry, and by pursuing a new and entirely different plan of operation, I have at last succeeded in combining oxygene and iodine. In the following pages I shall describe the circumstances which led me to ascertain the existence of this compound, and I shall detail some experiments on its analysis and its chemical agencies. In the course of my researches, I observed, that when a solution of the compound of iodine and chlorine was poured into alkaline solutions, or even into certain muriatic solutions, the precipitate was an oxyiode; and this fact seemed to indicate, that iodine had a stronger attraction for oxygene than chlorine; iodine, likewise, has an attraction for chlorine; it appeared, therefore, extremely probable, that euchlorine, or the gaseous combination of oxygene and chlorine, would be decomposed by heat, and two compounds formed, one of oxygene and iodine, and the other of iodine and chlorine, or that a triple compound would be produced from which chlorine could be easily separated, and on submitting the idea to the test of experiment, I found that I had not been deceived.


2006 ◽  
Vol 20 (25n27) ◽  
pp. 3611-3616 ◽  
Author(s):  
B. WITHY ◽  
M. HYLAND ◽  
B. JAMES

Chemical pretreatments are often used to improve the adhesion of coatings to aluminium. XPS and AFM were used to study the effect of these pretreatments on the surface chemistry and morphology of Al 5005. Four pretreatments were investigated, an acetone degrease, boiling water immersion, and two sulphuric acid etches, FPL and P2. Degreasing had no affect on surface morphology and simply added to the adventitious carbon on the surface. Boiling water immersion produced a chemically stable pseudo-boehmitic surface that was quite porous. The acid etches produced porous pitted surfaces similar to each other but significantly different to the other surfaces. The surface chemistry of the acid etched surfaces was variable and dependant on atmospheric conditions on removal from etch due to the very active surface that the etch produced.


Author(s):  
Gilbert C. Bourne

Mr. Wilfrid Grenfell, the Superintendent of the Mission to Deep Sea Fishermen, has most kindly arranged to carry on a series of observations on the pelagic fauna and the fishes of the seas traversed by the Mission boats in the course of their work. The following report gives an account of the pelagic fauna collected in the North Sea during the early spring, and in the west of Scotland and Kinsale Harbour during the summer. The collections were preserved in picro-sulphuric acid and spirit, and were forwarded to Plymouth for examination. Owing to pressure of work, and to my leaving Plymouth somewhat unexpectedly, I have not been able to make a thorough investigation of all the collections, but have worked out the Copepoda with care, and have confined myself to short notes on the other species.


1977 ◽  
Vol 32 (4) ◽  
pp. 430-433 ◽  
Author(s):  
Mohamed Hilmy Elnagdi ◽  
Ezzat Mohamed Zayed ◽  
Ezzat Mohamed Kandeel ◽  
Sherif Mahmoud Fahmy

3-Amino-4-phenylhydrazono-2-pyrazolin-5-one (1) reacts with isothiocyanate to yield the corresponding pyrazolylthiourea derivatives (2 a-c). Whereas 2 a reacted with hydrazines to yield the pyrazolylamino-1,2,4-triazoles (3 a, b), it cyclised into the pyrazolo-[3,4-e]-as-triazine derivative (4) upon treatment with concentrated sulphuric acid. On the other hand, the pyrazolo[1,5-c]-S-triazine derivative (5) was formed from reaction of 2a with ethanolic sodium ethoxide.3-Amino-2-pyrazolin-5-one (8) reacted with ethyl acrylate to yield a mixture of the 4-dialkylated derivative (9) and the pyrazolo[3,4-b]pyrone (11). Compound 11 could be converted into the corresponding pyrazolo[3,4-b]pyrones (12) and (13) by the action of acetic acid hydrochloric acid mixture and of concentrated sulphuric acid, respectively.


Keyword(s):  

Part I. On the variations of the Acidity of the Urine in Health . The modeof examination adopted bythe authorwas the following: Two test solutions were made; the one with carbonate of soda; the other with dilute sulphuric acid, of such strength that each measure of a graduated tube, when filled with either solution, was equivalent to one-twelfth of a grain of dry and pure carbonate of soda. A weighed quantity of urine was neutralized by one or other of the test solutions, and thus the degree of acidity or alkalescence was determined.


1969 ◽  
Vol 17 (5) ◽  
pp. 755 ◽  
Author(s):  
TE Thompson

Acid secretion is recorded for 22 species of Pacific Ocean gastropods. Pleurobranchus peroni, Cypraea clandestina, C. spadicea, and Lamellaria sp. were investigated in detail. It was established that the "empty" epidermal cells of P. peroni elaborate and secrete the acid and it is suggested that cells of similar appearance in the other species have the same function. The acid is discharged, following abrupt disturbance, by rupture of the epidermal acid cells in most species, but through permanent pores in Lamellaria sp. Tests suggest that the secretion is predominantly sulphuric acid. The structure of the epidermal acid cells was investigated with the electron microscope and the formation and coalescence of acid vacuoles are described. A second type of epidermal cell, found in P. peroni and C. spadicea, contains longitudinally striated material and is believed to play a mechanically supporting role. Mucous goblet cells and sparse epidermal cilia were also identified in various species.


The existence of a relation between the depression of the freezing point, produced by dissolving an acid or a salt in water, and the electrolytic conductivity of the solution thus obtained was pointed out by Arrhenius in 1887, and has been the subject of much experiment and discussion since that date. As is well known, the facts of electrolysis indicate that an electric current, when passing through a solution, is associated with a passage in opposite directions of the constituents of the salt. Faraday called these mobile parts ions. The number of the ions depends on the chemical nature of the salt, and is usually indicated by its formula. Thus for one molecule of potassium chloride we have two ions, the potassium travelling in one direction and the chlorine in the other. For barium chloride or sulphuric acid we have three ions, and, since the electric charge of an ion is proportional to its valency, the electrically equivalent weights of these substances are represented by ½BaCl 2 and ½H 2 So 4 , respectively.


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