Dramatic Drop in Cell Resistance through Induced Dipoles and Bipolar Electrochemistry

The use of slurries of conducting particles has been considered a way to extend the electrode area in some energy storage electrochemical cells. When suspensions of conducting particles are used in electrolytes a decreased impedance is observed, even for concentrations much lower than the theoretical percolation limits. Indeed, it is known that polarization occurs when a conducting material is immersed in an electrolyte in presence of electric fields, and bipolar electrochemistry processes may occur. This work demonstrates the dramatic drop in resistance for electrochemical cells with just a few macroscopic conducting pieces immersed in the electrolyte, in the absence of any electrical contact, through bipolar induction. Furthermore, mediation of soluble redox species between adjacent induced poles of opposite charge results in an additional mechanism for charge transfer, contributing further to the decrease in impedance. Relevant parameters like size, geometry, and spatial occupation of inducible pieces within the electric field, are relevant. Remarkably, the effects observed can explain some empirical observations previously reported for carbon suspensions and slurries. Thus, no electronic percolation requiring particle contact, nor ordering, are needed to explain the good performance associated to lowered impedance These results suggest new engineering designs for electrochemical cells with enhanced currents

High-Performance Protonic Ceramic Fuel Cell Cathode using Protophilic Mixed Ion and Electron Conducting Material

Protonic ceramic fuel cells (PCFCs) are attractive energy conversion devices for intermediate-temperature operation (400-600 °C), however widespread application of PCFCs relies on the development of new high-performance electrode materials. Here...

Poly(aspartic acid) Biohydrogel as the Base of a New Hybrid Conducting Material

In the present study, a composite made of conducting polymer, poly(3,4-ethylenedioxythiophene) (PEDOT), and a biodegradable hydrogel of poly(aspartic acid) (PASP) were electrochemically interpenetrated with poly(hydroxymethyl-3,4-ethylenedioxythiophene) (PHMeDOT) to prepare a new interpenetrated polymer network (IPN). Different cross-linker and PEDOT MPs contents, as well as different electropolymerization times, were studied to optimize the structural and electrochemical properties. The properties of the new material, being electrically conductive, biocompatible, bioactive, and biodegradable, make it suitable for possible uses in biomedical applications.

Neutrosophic statistical analysis of resistance depending on the temperature variance of conducting material

In this work, we have proposed a neutrosophic statistical approach for the analysis of resistance of conducting material depending on the temperature variance. We have developed a neutrosophic formula and applied it to the resistance data. We also use the classical statistical approach for making a comparison between both approaches. As a result, it is observed that the neutrosophic statistical approach is more flexible and informative. Also, this work suggests that the neutrosophic statistical approach analyzes the resistance of conducting material for big data.

Wear resistance discrete management of formative tool

The article is devoted to the organization of management of the application of wear-resistant materials on the formative tool at set intervals by the method of electro-acoustic spraying. A complex highly concentrated effect of the ultrasonic method in a permanent process, based on the pulse energy, which leads to an increase in the plasticity of the material and is not associated with its heating. The law of electro-plastic deformation for a conducting material, taking into account the high density of the acting amperage in the process of active deformation at a constant rate, considered in this article, establishes a clear dependence of the strengthening of the substrate material. The process of concentration of electromagnetic and thermal fields in a conductive material with defects such as a crack makes it possible to use this technology to slow down the propagation of cracks while reducing the concentration of mechanical stresses.

Thermal atomic layer deposition of In2O3 thin films using a homoleptic indium triazenide precursor and water

Indium oxide (In2O3) is an important transparent conducting material widely used in optoelectronic applications. Herein, we study the deposition of In2O3 by thermal atomic layer deposition (ALD) using our recently reported indium(III) triazenide precursor and H2O. A temperature interval with self-limiting growth was found between ~270–385°C with a growth per cycle of ~1.0 Å. The deposited films were polycrystalline cubic In2O3 with In/O ratios of ~1.20, and low levels of C and no detectable N impurities. The transmittance of the films was found to be >70% in visible light and the resistivity was found to be 0.2 mΩcm. The high growth rates, low impurities, high optical transmittance, and low resistivity of these films give promise to this process being used for ALD of In2O3 films that are good candidates for potential display and touch-screen applications.

The Principal's Role as Manager and Teacher Pedagogic Competence in Online Learning

The Covid-19 pandemic requires people to learn online, one of which is at the elementary school level. Principals must be able to play a role as managers in managing learning during the Covid-19 Pandemic. This study aims to analyze the role of the principal as a manager and the pedagogical competence of teachers in online learning during the Covid-19 period. This type of research is descriptive quantitative research, namely by interpreting the data obtained from the field. Data collection was carried out on 4 principals and 49 teachers using a questionnaire distributed via google forms. Data analysis used descriptive quantitative with percentages. The results showed that the principal's role as a manager in online learning was not optimal in the indicators of the school determining the curriculum used in online learning (44%) and the principal facilitating support for online learning (50%). At the same time, the pedagogic competence also showed less than optimal in Playing their competencies is shown by the 5 lowest percentage indicators, including understanding the cognitive development of students (59%), designing learning methods (52%), designing learning models (56%), carrying out assessments of learning outcomes (54.5%), and conducting material assessments. (56%). With a strong commitment from teachers and principals, various efforts and programs carried out during online learning will optimally achieve learning objectives.