Introductory remarks
The substratum of the Earth, as Arthur Holmes originally described it, now generally known as the mantle , is the envelope, mainly of magnesium silicates, surrounding the fluid metallic core. It is separated from the continental and oceanic crusts which overlie it by the Mohorovicic seismic discontinuity, where there is a sharp change from earthquake wave velocities less than 7.2 km s -1 above to 7.8-8.1 km s -1 below. The thickness of the envelope is of the order of 2900 km, compared with about 4 km for ocean crust and 30 km for unthickened continental crust. Much attention has been devoted by geophysicists to the properties of the mantle, particularly in the course of the Geodynamics Project of I.U.G.G./I.U.G.S., during which important conclusions regarding sea floor spreading, plate tectonics and mantle convection have been reached. The fact that the overwhelming bulk of the mantle is not, and never will be, accessible for direct collection has perhaps resulted in less interest so far from the geochemical side. Accepting, however, that a partly indirect approach is inevitable, the time is now ripe for a thorough examination of the contribution that geochemical techniques can make.