scholarly journals Evaporative fractionation of volatile stable isotopes and their bearing on the origin of the Moon

2014 ◽  
Vol 372 (2024) ◽  
pp. 20130259 ◽  
Author(s):  
James M. D. Day ◽  
Frederic Moynier
Keyword(s):  
Global Scale ◽  
Parent Body ◽  
The Moon ◽  
Magma Ocean ◽  
Volatile Elements ◽  
Giant Impact ◽  
The Earth ◽  
Present Distribution ◽  
Volatile Loss

The Moon is depleted in volatile elements relative to the Earth and Mars. Low abundances of volatile elements, fractionated stable isotope ratios of S, Cl, K and Zn, high μ ( 238 U/ 204 Pb) and long-term Rb/Sr depletion are distinguishing features of the Moon, relative to the Earth. These geochemical characteristics indicate both inheritance of volatile-depleted materials that formed the Moon and planets and subsequent evaporative loss of volatile elements that occurred during lunar formation and differentiation. Models of volatile loss through localized eruptive degassing are not consistent with the available S, Cl, Zn and K isotopes and abundance data for the Moon. The most probable cause of volatile depletion is global-scale evaporation resulting from a giant impact or a magma ocean phase where inefficient volatile loss during magmatic convection led to the present distribution of volatile elements within mantle and crustal reservoirs. Problems exist for models of planetary volatile depletion following giant impact. Most critically, in this model, the volatile loss requires preferential delivery and retention of late-accreted volatiles to the Earth compared with the Moon. Different proportions of late-accreted mass are computed to explain present-day distributions of volatile and moderately volatile elements (e.g. Pb, Zn; 5 to >10%) relative to highly siderophile elements (approx. 0.5%) for the Earth. Models of early magma ocean phases may be more effective in explaining the volatile loss. Basaltic materials (e.g. eucrites and angrites) from highly differentiated airless asteroids are volatile-depleted, like the Moon, whereas the Earth and Mars have proportionally greater volatile contents. Parent-body size and the existence of early atmospheres are therefore likely to represent fundamental controls on planetary volatile retention or loss.

Constitution of terrestrial planets

1981 ◽  
Vol 303 (1477) ◽  
pp. 287-302 ◽  
Keyword(s):  
Bulk Composition ◽  
Parent Body ◽  
The Moon ◽  
Volatile Elements ◽  
Earth’S Mantle ◽  
The Earth ◽  
History Of ◽  
Relationship Of ◽  
Reduced State

Reliable estimates of the bulk composition are so far restricted to the three planetary objects from which we have samples for laboratory investigation, i.e. the Earth, the Moon and the eucrite parent asteroid. The last, the parent body of the eucrite— diogenite family of meteorites, an object that like Earth and Moon underwent magmatic differentiations, seems to have an almost chondritic composition except for a considerable depletion of all moderately volatile (Na, K, Rb, F, etc.) and highly volatile (Cl, Br, Cd, Pb, etc.) elements. The Moon is also depleted in moderately volatile and volatile elements compared to carbonaceous chondrites of type 1 (Cl) and also compared to the Earth. Again normalized to Cl and Si the Earth’s mantle and the Moon are slightly enriched in refractory lithophile elements and in magnesium. It might be that this enrichment is fictitious and only due to the normalization to Si and that both Earth’s mantle and Moon are depleted in Si, which partly entered the Earth’s core in metallic form. The striking depletion of the Earth’s mantle for the elements V, Cr and Mn can also be explained by their partial removal into the core. The similar abundances of V, Cr and Mn in the Moon and in the Earth’s mantle indicate the strong genetic relationship of Earth and Moon. Apart from their contents of metallic iron, all siderophile elements, moderately volatile and volatile elements, Earth and Moon are chemically very similar. It might well be that, with these exceptions and that of a varying degree of oxidation, all the inner planets have a similar chemistry. The chemical composition of the Earth’s mantle, for which reliable and accurate data have recently been obtained from the study of ultramafic nodules, yields important information about the accretion history of the Earth and that of the inner planets. It seems that accretion started with highly reduced material, with all Fe as metal and even Si and Cr, V and Mn partly in reduced state, followed by the accretion of more and more oxidized matter.

A young Moon-forming giant impact at 70–110 million years accompanied by late-stage mixing, core formation and degassing of the Earth

2008 ◽  
Vol 366 (1883) ◽  
pp. 4163-4181 ◽  
Author(s):  
Alex N Halliday
Keyword(s):  
Isotopic Composition ◽  
The Moon ◽  
Lunar Crust ◽  
Core Formation ◽  
Volatile Elements ◽  
Giant Impact ◽  
Isotope Data ◽  
The Earth ◽  
Isotopic Effects ◽  
Late Veneer

New W isotope data for lunar metals demonstrate that the Moon formed late in isotopic equilibrium with the bulk silicate Earth (BSE). On this basis, lunar Sr isotope data are used to define the former composition of the Earth and hence the Rb–Sr age of the Moon, which is 4.48±0.02 Ga, or 70–110 Ma (million years) after the start of the Solar System. This age is significantly later than had been deduced from W isotopes based on model assumptions or isotopic effects now known to be cosmogenic. The Sr age is in excellent agreement with earlier estimates based on the time of lunar Pb loss and the age of the early lunar crust (4.46±0.04 Ga). Similar ages for the BSE are recorded by xenon and lead–lead, providing evidence of catastrophic terrestrial degassing, atmospheric blow-off and significant late core formation accompanying the ca 100 Ma giant impact. Agreement between the age of the Moon based on the Earth's Rb/Sr and the lead–lead age of the Moon is consistent with no major losses of moderately volatile elements from the Earth during the giant impact. The W isotopic composition of the BSE can be explained by end member models of (i) gradual accretion with a mean life of roughly 35 Ma or (ii) rapid growth with a mean life of roughly 10 Ma, followed by a significant hiatus prior to the giant impact. The former assumes that approximately 60 per cent of the incoming metal from impactors is added directly to the core during accretion. The latter includes complete mixing of all the impactor material into the BSE during accretion. The identical W isotopic composition of the Moon and the BSE limits the amount of material that can be added as a late veneer to the Earth after the giant impact to less than 0.3±0.3 per cent of ordinary chondrite or less than 0.5±0.6 per cent CI carbonaceous chondrite based on their known W isotopic compositions. Neither of these on their own is sufficient to explain the inventories of both refractory siderophiles such as platinum group elements and rhenium, and volatiles such as sulphur, carbon and water.

Early differentiation of the Earth and the Moon

2008 ◽  
Vol 366 (1883) ◽  
pp. 4105-4128 ◽  
Author(s):  
Bernard Bourdon ◽  
Mathieu Touboul ◽  
Guillaume Caro ◽  
Thorsten Kleine
Keyword(s):  
Mass Balance ◽  
Magma Mixing ◽  
The Moon ◽  
Magma Ocean ◽  
Nd Isotopes ◽  
Early Differentiation ◽  
Giant Impact ◽  
Earth’S Mantle ◽  
The Earth ◽  
Differentiation Event

We examine the implications of new 182 W and 142 Nd data for Mars and the Moon for the early evolution of the Earth. The similarity of 182 W in the terrestrial and lunar mantles and their apparently differing Hf/W ratios indicate that the Moon-forming giant impact most probably took place more than 60 Ma after the formation of calcium-aluminium-rich inclusions (4.568 Gyr). This is not inconsistent with the apparent U–Pb age of the Earth. The new 142 Nd data for Martian meteorites show that Mars probably has a super-chondritic Sm/Nd that could coincide with that of the Earth and the Moon. If this is interpreted by an early mantle differentiation event, this requires a buried enriched reservoir for the three objects. This is highly unlikely. For the Earth, we show, based on new mass-balance calculations for Nd isotopes, that the presence of a hidden reservoir is difficult to reconcile with the combined 142 Nd– 143 Nd systematics of the Earth's mantle. We argue that a likely possibility is that the missing component was lost during or prior to accretion. Furthermore, the 142 Nd data for the Moon that were used to argue for the solidification of the magma ocean at ca 200 Myr are reinterpreted. Cumulate overturn, magma mixing and melting following lunar magma ocean crystallization at 50–100 Myr could have yielded the 200 Myr model age.

scholarly journals Conditions and extent of volatile loss from the Moon during formation of the Procellarum basin

2021 ◽  
Vol 118 (12) ◽  
pp. e2023023118
Author(s):  
Romain Tartèse ◽  
Paolo A. Sossi ◽  
Frédéric Moynier
Keyword(s):  
Isotopic Fractionation ◽  
The Moon ◽  
Magma Ocean ◽  
Heavy Isotope ◽  
Volatile Elements ◽  
Lunar Interior ◽  
Primitive Atmosphere ◽  
Evaporative Loss ◽  
Volatile Loss ◽  
Elemental Depletion

Rocks from the lunar interior are depleted in moderately volatile elements (MVEs) compared to terrestrial rocks. Most MVEs are also enriched in their heavier isotopes compared to those in terrestrial rocks. Such elemental depletion and heavy isotope enrichments have been attributed to liquid–vapor exchange and vapor loss from the protolunar disk, incomplete accretion of MVEs during condensation of the Moon, and degassing of MVEs during lunar magma ocean crystallization. New Monte Carlo simulation results suggest that the lunar MVE depletion is consistent with evaporative loss at 1,670 ± 129 K and an oxygen fugacity +2.3 ± 2.1 log units above the fayalite-magnetite-quartz buffer. Here, we propose that these chemical and isotopic features could have resulted from the formation of the putative Procellarum basin early in the Moon’s history, during which nearside magma ocean melts would have been exposed at the surface, allowing equilibration with any primitive atmosphere together with MVE loss and isotopic fractionation.

scholarly journals Present and Future Observations of the Earthshine from Antarctica

2012 ◽  
Vol 8 (S288) ◽  
pp. 214-217 ◽  
Author(s):  
Danielle Briot ◽  
Luc Arnold ◽  
Stéphane Jacquemoud
Keyword(s):  
Global Scale ◽  
Spectral Signature ◽  
Research Station ◽  
The Moon ◽  
Spectral Signatures ◽  
The Earth ◽  
Earth Like Planets ◽  
Elementary Mapping ◽  
Absorption Features

AbstractIt is likely that images of Earth-like planets will be obtained in the next years. The first images will actually come down to single dots, in which biomarkers can be searched. Taking the Earth as a example of planet providing life, Earthshine observations showed that the spectral signature of photosynthetic pigments and atmospheric biogenic molecules was detectable, suggesting that, in principle, life on other planets could be detected on a global scale, if it is widely spread and distinguishable from known abiotic spectral signatures. As for the Earth, we already showed that the Vegetation Red Edge which is related to chlorophyll absorption features was larger when continents, versus oceans, were facing the Moon. It proved that an elementary mapping of a planet was even possible. In the frame of the LUCAS (LUmière Cendrée en Antarctique par Spectroscopie) project, the Earthshine has been measured in the Concordia Research Station (Dome C, Antarctica) long enough to observe variations corresponding to different parts of the Earth facing the Moon. An extension of this project, called LUCAS II, would allow long-term observations to detect seasonal variations in the vegetation signal. These data, together with precise measurements of the Earth's albedo, will help to validate a model of global and spectral albedo of our planet.

scholarly journals Isotopic evidence for the formation of the Moon in a canonical giant impact

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Sune G. Nielsen ◽  
David V. Bekaert ◽  
Maureen Auro
Keyword(s):  
Solar System ◽  
Isotope Fractionation ◽  
Main Stage ◽  
The Moon ◽  
Giant Impact ◽  
Bulk Silicate Earth ◽  
The Earth ◽  
The Standard Model ◽  
Isotopic Measurements ◽  
Origin Of The Moon

AbstractIsotopic measurements of lunar and terrestrial rocks have revealed that, unlike any other body in the solar system, the Moon is indistinguishable from the Earth for nearly every isotopic system. This observation, however, contradicts predictions by the standard model for the origin of the Moon, the canonical giant impact. Here we show that the vanadium isotopic composition of the Moon is offset from that of the bulk silicate Earth by 0.18 ± 0.04 parts per thousand towards the chondritic value. This offset most likely results from isotope fractionation on proto-Earth during the main stage of terrestrial core formation (pre-giant impact), followed by a canonical giant impact where ~80% of the Moon originates from the impactor of chondritic composition. Our data refute the possibility of post-giant impact equilibration between the Earth and Moon, and implies that the impactor and proto-Earth mainly accreted from a common isotopic reservoir in the inner solar system.

Late Accretion and the Origin of Water on Terrestrial Planets in the Solar System

2021 ◽  
Author(s):  
Cédric Gillmann ◽  
Gregor Golabek ◽  
Sean Raymond ◽  
Paul Tackley ◽  
Maria Schonbachler ◽  
...  
Keyword(s):  
Solar System ◽  
Long Term Evolution ◽  
Terrestrial Planets ◽  
Evolutionary Pathway ◽  
Giant Impact ◽  
The Earth ◽  
Term Evolution ◽  
Surface Liquid ◽  
Venus Atmosphere

<p>Terrestrial planets in the Solar system generally lack surface liquid water. Earth is at odd with this observation and with the idea of the giant Moon-forming impact that should have vaporized any pre-existing water, leaving behind a dry Earth. Given the evidence available, this means that either water was brought back later or the giant impact could not vaporize all the water.</p><p>We have looked at Venus for answers. Indeed, it is an example of an active planet that may have followed a radically different evolutionary pathway despite the similar mechanisms at work and probably comparable initial conditions. However, due to the lack of present-day plate tectonics, volatile recycling, and any surface liquid oceans, the evolution of Venus has likely been more straightforward than that of the Earth, making it easier to understand and model over its long term evolution.</p><p>Here, we investigate the long-term evolution of Venus using self-consistent numerical models of global thermochemical mantle convection coupled with both an atmospheric evolution model and a late accretion N-body delivery model. We test implications of wet and dry late accretion compositions, using present-day Venus atmosphere measurements. Atmospheric losses are only able to remove a limited amount of water over the history of the planet. We show that late accretion of wet material exceeds this sink. CO<sub>2</sub> and N<sub>2</sub> contributions serve as additional constraints.</p><p>Water-rich asteroids colliding with Venus and releasing their water as vapor cannot explain the composition of Venus atmosphere as we measure it today. It means that the asteroidal material that came to Venus, and thus to Earth, after the giant impact must have been dry (enstatite chondrites), therefore preventing the replenishment of the Earth in water. Because water can obviously be found on our planet today, it means that the water we are now enjoying on Earth has been there since its formation, likely buried deep in the Earth so it could survive the giant impact. This in turn suggests that suggests that planets likely formed with their near-full budget in water, and slowly lost it with time.</p>

scholarly journals Volatile loss following cooling and accretion of the Moon revealed by chromium isotopes

2018 ◽  
Vol 115 (43) ◽  
pp. 10920-10925 ◽  
Author(s):  
Paolo A. Sossi ◽  
Frédéric Moynier ◽  
Kirsten van Zuilen
Keyword(s):  
Atomic Mass Unit ◽  
The Moon ◽  
Volatile Elements ◽  
Mass Unit ◽  
Earth’S Mantle ◽  
Refractory Elements ◽  
Common Precursor ◽  
Lunar Rocks ◽  
Evaporative Loss ◽  
Volatile Loss

Terrestrial and lunar rocks share chemical and isotopic similarities in refractory elements, suggestive of a common precursor. By contrast, the marked depletion of volatile elements in lunar rocks together with their enrichment in heavy isotopes compared with Earth’s mantle suggests that the Moon underwent evaporative loss of volatiles. However, whether equilibrium prevailed during evaporation and, if so, at what conditions (temperature, pressure, and oxygen fugacity) remain unconstrained. Chromium may shed light on this question, as it has several thermodynamically stable, oxidized gas species that can distinguish between kinetic and equilibrium regimes. Here, we present high-precision Cr isotope measurements in terrestrial and lunar rocks that reveal an enrichment in the lighter isotopes of Cr in the Moon compared with Earth’s mantle by 100 ± 40 ppm per atomic mass unit. This observation is consistent with Cr partitioning into an oxygen-rich vapor phase in equilibrium with the proto-Moon, thereby stabilizing the CrO2 species that is isotopically heavy compared with CrO in a lunar melt. Temperatures of 1,600–1,800 K and oxygen fugacities near the fayalite–magnetite–quartz buffer are required to explain the elemental and isotopic difference of Cr between Earth’s mantle and the Moon. These temperatures are far lower than modeled in the aftermath of a giant impact, implying that volatile loss did not occur contemporaneously with impact but following cooling and accretion of the Moon.

scholarly journals Boundary conditions for the formation of the Moon

2015 ◽  
Vol 95 (2) ◽  
pp. 131-139 ◽  
Author(s):  
M. Reuver ◽  
R.J. de Meijer ◽  
I.L. ten Kate ◽  
W. van Westrenen
Keyword(s):  
Angular Momentum ◽  
Boundary Conditions ◽  
Total Angular Momentum ◽  
Nuclear Explosion ◽  
Moment Of Inertia ◽  
The Moon ◽  
Moon System ◽  
Giant Impact ◽  
The Earth ◽  
The Impact

AbstractRecent measurements of the chemical and isotopic composition of lunar samples indicate that the Moon's bulk composition shows great similarities with the composition of the silicate Earth. Moon formation models that attempt to explain these similarities make a wide variety of assumptions about the properties of the Earth prior to the formation of the Moon (the proto-Earth), and about the necessity and properties of an impactor colliding with the proto-Earth. This paper investigates the effects of the proto-Earth's mass, oblateness and internal core-mantle differentiation on its moment of inertia. The ratio of angular momentum and moment of inertia determines the stability of the proto-Earth and the binding energy, i.e. the energy needed to make the transition from an initial state in which the system is a rotating single body with a certain angular momentum to a final state with two bodies (Earth and Moon) with the same total angular momentum, redistributed between Earth and Moon. For the initial state two scenarios are being investigated: a homogeneous (undifferentiated) proto-Earth and a proto-Earth differentiated in a central metallic and an outer silicate shell; for both scenarios a range of oblateness values is investigated. Calculations indicate that a differentiated proto-Earth would become unstable at an angular momentum L that exceeds the total angular momentum of the present-day Earth–Moon system (L0) by factors of 2.5–2.9, with the precise maximum dependent on the proto-Earth's oblateness. Further limitations are imposed by the Roche limit and the logical condition that the separated Earth–Moon system should be formed outside the proto-Earth. This further limits the L values of the Earth–Moon system to a maximum of about L/L0 = 1.5, at a minimum oblateness (a/c ratio) of 1.2. These calculations provide boundary conditions for the main classes of Moon-forming models. Our results show that at the high values of L used in recent giant impact models (1.8 < L/L0 < 3.1), the proposed proto-Earths are unstable before (Cuk & Stewart, 2012) or immediately after (Canup, 2012) the impact, even at a high oblateness (the most favourable condition for stability). We conclude that the recent attempts to improve the classic giant impact hypothesis by studying systems with very high values of L are not supported by the boundary condition calculations in this work. In contrast, this work indicates that the nuclear explosion model for Moon formation (De Meijer et al., 2013) fulfills the boundary conditions and requires approximately one order of magnitude less energy than originally estimated. Hence in our view the nuclear explosion model is presently the model that best explains the formation of the Moon from predominantly terrestrial silicate material.

Low selenocentric orbits stability analysis

2020 ◽  
Author(s):  
Chongrui Du ◽  
O.L. Starinova
Keyword(s):  
Rate Of Change ◽  
The Sun ◽  
Space Systems ◽  
The Moon ◽  
Orbital Structure ◽  
Motion Modeling ◽  
The Earth ◽  
Long Time ◽  
The Stability

The tasks of studying the Moon require long-term functioning space systems. Most of the low selenocentric orbits are known to be unstable, which requires a propellant to maintain the orbital structure. For these orbits, the main disturbing factors are the off-center gravitational field of the Moon and the gravity of the Earth and the Sun. This paper analyzes the stability of low selenocentric orbits according to passive motion modeling and takes into account these main disturbing factors. We put forward a criterion for determining the stability of the orbit and used it to analyze the circular orbit of the Moon at an altitude of 100 kilometers. According to different initial data and different dates, we obtained ranges of the Moon’s orbits with good stability. At the same time, we analyzed the rate of change in the longitude of the ascending node, and found a stable low lunar orbit which can operate for a long time.

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