scholarly journals XXII. On the thermal resistance of liquids

1869 ◽  
Vol 159 ◽  
pp. 637-660 ◽  

§ 1. The passage of heat through matter has been mainly examined in reference to the diathermancy of solids, liquids, and gases to radiant heat, and to the conduction of contact-heat through solids and gases. The conduction of contact-heat through liquids forms a chapter in heat transference which has not hitherto received as much attention from experimental physicists as it merits. § 2. In the following pages I have the honor of submitting to the Royal Society certain experimental results and considerations to which I have been led during an investigation of this subject. These results are necessarily incomplete. The inquiry is fraught with very numerous and considerable experimental difficulties; but I venture to hope that such as the results are, they may be found useful to those who shall hereafter pursue the subject with greater skill and more perfect appliances.

There are a number of references in the scientific literature to a burning mirror designed by Sir Isaac Newton (1). Together, they record that it was made from seven separate concave glasses, each about a foot in diameter, that Newton demonstrated its effects at several meetings of the Royal Society and that he presented it to the Society. Nonetheless, neither the earliest published list of instruments possessed by the Royal Society nor the most recent one mentions the burning mirror; the latest compiler does not even include it amongst those items, once owned, now lost. No reference to the instrument apparently survives in the Society’s main records. It is not listed by the author of the recent compendium on Newton’s life and work (2). There is, however, some contemporary information still extant (Appendix 1). Notes of the principles of its design and some of its effects are to be found in the Society’s Journal Book for 1704; some of the dimensions and the arrangement of the mirrors are given in a Lexicon published by John Harris which he donated to the Royal Society at the same meeting, 12 July 1704, at which Newton gave the Society the speculum. The last reference in the Journal Book is dated 15 November that year, when Mr Halley, the then secretary to the Society, was desired to draw up an account of the speculum and its effects (3). No such account appears to have been presented to the Royal Society. There is no reference in Newton’s published papers and letters of his chasing Halley to complete the task, nor is there any mention of it in the general references to Halley. The latter was, of course, quite accustomed to performing odd jobs for Newton; that same year he was to help the Opticks through the press. The only other contemporary reference to the burning mirror, though only hearsay evidence since Flamsteed was not present at the meeting, is in a letter the latter wrote to James Pound; this confirms that there were seven mirrors and that the aperture of each was near a foot in diameter (4). Because John Harris gave his Dictionary to the Royal Society in Newton’s presence, it is reasonable to assume that his description is accurate. As Newton would hardly have left an inaccurate one unchallenged, then, belatedly, the account desired of Mr Halley can be presented. In some respects, the delay is advantageous, since the subject of radiant heat and its effects, although already by Newton’s period an ancient one, is today rather better understood. On the other hand, some data has to be inferred, that could have been measured, and some assumptions made about Newton’s procedures and understanding that could have been checked (5).


1873 ◽  
Vol 163 ◽  
pp. 587-627 ◽  

In the years 1869 and 1870 I communicated to the Royal Society the results of a series of experiments made with the view of determining, if possible, the amount of radiant heat coming to the earth from the moon in various conditions of phase, and the nature of that heat as regards the average refrangibility of the rays. Though more successful than I had at first been led to expect, the imperfect accordance between many of the observations still left much to be desired, and the novelty and importance of the subject appeared sufficient to render it advisable to pursue the investigation with greater care and closer attention to details than had hitherto been deemed necessary. Since the conclusion of the series of observations which form the subject of the second paper above referred to, nothing (with the exception of a short series of observations in August and October 1870, of which mention is made towards the end of this paper) was done towards pursuing the subject till the spring of the following year (1871), when the series of observations which form the subject of the present paper were commenced, the same apparatus (only slightly modified) being used and the same method of observation adopted; but, with the view of obtaining an approximate value of the absorption of the moon’s heat in its passage through our atmosphere, and of rendering possible the satisfactory comparison of observations made at different zenith-distances of the moon, the observations were in many cases carried on at intervals at all possible zenith- distances on the same night, and the most favourable opportunities for observing the moon at very different zenith-distances in various conditions of the atmosphere were not lost.


1864 ◽  
Vol 154 ◽  
pp. 201-225 ◽  

The Royal Society has already done me the honour of publishing in the Philosophical Transactions three memoirs on the relations of radiant heat to the gaseous form of matter. In the first of these memoirs* it was shown that for heat emanating from the blackened surface of a cube filled with boiling water, a class of bodies which had been previously regarded as equally, and indeed, as far as laboratory experiments went, perfectly diathermic, exhibited vast differences both as regards radiation and absorption. At the common tension of one atmosphere the absorptive energy of olefiant gas, for example, was found to be 290 times that of air, while when lower pressures were employed the ratio was still greater. The reciprocity of absorption and radiation on the part of gases was also experimentally established in this first investigation. In the second inquiry† I employed a different and more powerful source of heat, my desire being to bring out with still greater decision the differences which revealed themselves in the first investigation. By carefully purifying the transparent elementary gases, and thus reducing the action upon radiant heat, the difference between them and the more strongly acting compound gases was greatly augmented. In this second inquiry, for example, olefiant gas at a pressure of one atmosphere was shown to possess 970 times the absorptive energy of atmospheric air, while it was shown to be probable that when pressures of 1/30th of an atmosphere were compared, the absorption of olefiant gas was nearly 8000 times that of air. A column of ammoniacal gas, moreover, 3 feet long, was found sensibly impervious to the heat employed in the inquiry, while the vapours of many of the volatile liquids were proved to be still more opaque to radiant heat than even the most powerfully acting permanent gases. In this second investigation, the discovery of dynamic radiation and absorption is also announced and illustrated, and the action of odours and of ozone on radiant heat is made the subject of experiment.


1826 ◽  
Vol 116 ◽  
pp. 372-382

(1) In a former Paper, communicated to the Royal Society, and which has been honoured with a place in the Philosophical Transactions for 1825, I attempted an investigation of the distinctive characters of two species of heating effect, in which particular reference was made to the action of transparent screens. In the present communication, my object is to examine a further point belonging to that part of the subject; and to which, as well as the former enquiry, I have been led, from considering the results obtained by M. De La Roche. The investigation given in my former paper proceeded upon the assumption, that simple radiant heat is incapable of permeating glass by direct transmission when the source is below luminosity: and the conclusion deduced from my experiments went to show, that that portion of the heat which is intercepted above luminosity, is simple heat, unaltered except in intensity, whilst that which is transmitted is of a different kind. That this assumption, at least under all ordinary circumstances, is warranted by most decisive experiments, I conceive sufficiently certain. It appears to me, however, that in reference to its strict universality, some further enquiry is necessary. The general inference respecting transmission, deduced from De La Roche's experiments, has, I conceive, been satisfactorily explained by mine; but there is one of his conclusions to which my principle does not apply (except in a particular case), and which might seem to afford considerable ground for the idea of an actual radiation through glass, under particular circumstances.


1861 ◽  
Vol 22 (1) ◽  
pp. 33-39
Author(s):  
William Swan

In 1849 I presented to the Royal Society of Edinburgh a paper “On the Gradual Production of Luminous Impressions on the Eye.” The object of that communication was to investigate the laws of the production of visual impressions. The subject was then new; for although the fact that light requires a certain time to produce its full effect on the eye had been noticed at comparatively early periods, yet no one, so far as I am aware, had attempted to measure that time; and the whole subject of the production of visual impressions, regarded as a branch of experimental science, was quite untouched. I have frequently wished to resume a subject of inquiry which seems to me to merit more attention than it has hitherto received, and which I have not as yet been able to discuss so completely as I could have desired. Various portions of it demand more extended experiments. Among these may be specified, the examination of isolated impressions of shorter duration than my limited instrumental means had enabled me to observe; a more careful determination of the time required for light to produce its complete effect on the eye; and a series of observations on the eyes of various individuals, so that any personal peculiarity of vision, which might affect results derived exclusively from experiments on my own eye, might be eliminated. These, and other subjects of inquiry, I hope sooner or later to overtake; and, indeed, I had anticipated before the end of the present session of the Society to have been able to obtain some experimental results. In this I have been disappointed, owing to the instruments required for my observations having taken a much longer time to make than I had expected.


The researches on glaciers which I have had the honour of submitting from time to time to the notice of the Royal Society, directed my attention in a special manner to the observations and speculations of De Saussure, Fourier, M. Pouillet, and Mr. Hopkins, on the transmission of solar and terrestrial heat through the earth’s atmosphere. This gave practical effect to a desire which I had previously entertained to make the mutual action of radiant heat and gases of all kinds the subject of an experimental inquiry. Our acquaintance with this department of Physics is exceedingly limited. So far as my knowledge extends, the literature of the subject may be stated in a few words.


1881 ◽  
Vol 31 (206-211) ◽  
pp. 307-317 ◽  

The Royal Society has already done me the honour of publishing a long series of memoirs on the interaction of radiant heat and gaseous matter. These memoirs did not escape criticism. Distinguished men, among whom the late Professor Magnus and the late Professor Buff may be more specially mentioned, examined my experiments, and arrived at results different from mine.


Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1348
Author(s):  
Pamela Miśkiewicz ◽  
Magdalena Tokarska ◽  
Iwona Frydrych ◽  
Marcin Makówka

Innovative textile materials can be obtained by depositing different coatings. To improve the thermal properties of textiles, aluminum and zirconium (IV) oxides were deposited on the Nomex® fabric, basalt fabric, and cotton fabric with flame-retardant finishing using the magnetron sputtering method. An assessment of coating quality was conducted. Evenly coated fabric ensures that there are no places on the sample surface where the values of thermal parameters such as resistance to contact heat and radiant heat deviate significantly from the specified ones. Energy-dispersive spectroscopy was used for the analysis of modified fabric surfaces. Non-contact digital color imaging system DigiEye was also used. The criterion allowing one to compare surfaces and find which surface is more evenly coated was proposed. The best fabrics from the point of view of coating quality were basalt and cotton fabrics coated with aluminum as well as basalt fabric coated with zirconia. The probability of occurrence of places on the indicated sample surfaces where the values of thermal parameters (i.e., resistance to contact heat and radiant heat) deviated significantly from the specified ones was smaller for Nomex® and cotton fabrics coated with zirconia and Nomex® fabric coated with aluminum.


1881 ◽  
Vol 32 (212-215) ◽  
pp. 407-408

During the progress of the investigations which I have from time to time had the honour of bringing under the notice of the Royal Society, I have again and again noticed the apparent disappearance of gases inclosed in vessels of various materials when the disappearance could not be accounted for upon the assumption of ordinary leakage. After a careful examination of the subject I found that the solids absorbed or dissolved the gases, giving rise to a striking example of the fixation of a gas in a solid without chemical action. In carrying out that most troublesome investigation, the crystalline separation of carbon from its compounds, the tubes used for experiment have been in nine cases out of ten found to be empty on opening them, and in most cases a careful testing by hydraulic press showed no leakage. The gases seemed to go through the solid iron, although it was 2 inches thick. A series of experiments with various linings were tried. The tube was electro-plated with copper, silver, and gold, but with no greater success. Siliceous linings were tried fusible enamels and glass—but still the' tubes refused to hold the contents. Out of thirty-four experiments made since my last results were published, only four contained any liquid or condensed gaseous matter after the furnacing. I became convinced that the solid matter at the very high pressure and temperature used must be pervious to gases.


The papers in this symposium form the proceeding of the Royal Society’s Discussion Meeting held in March 1993. As co-organizers and editors, we trust that we have put together a timely, enterprising and enlightening volume which provides a fitting tribute to Alan Williams. It was Alan who first promoted to the Royal Society the subject of CD4 as a topic for one of the Society’s Discussion Meetings and who agreed to be cast in the role of organizer. After Alan’s untimely death, as coorganizers we were given the choice of proceeding with the meeting or not, and it was decided to proceed as a memorial to Alan. We are certain that it was exactly what Alan would have wanted us to do.


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