A fivefold interpenetrating diamondoid three-dimensional metal–organic framework constructed from benzene-1,4-diacetic acid and flexible triazole derivatives: poly[[(μ2-benzene-1,4-diacetato-κ2O:O){μ2-1,4-bis[(1H-1,2,4-triazol-1-yl)methyl]benzene-κ2N4:N4′}zinc(II)] monohydrate]
2013 ◽
Vol 70
(1)
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pp. 28-30
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Keyword(s):
X Ray
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In the title mixed-ligand metal–organic polymeric compound, {[Zn(C10H8O4)(C12H14N6)]·H2O}n, the asymmetric unit contains a divalent ZnIIcation lying on a twofold axis, one half of a fully deprotonated benzene-1,4-diacetate (PBEA) ligand, one half of a 1,4-bis[(1H-1,2,4-triazol-1-yl)methyl]benzene (BTX) ligand and a water molecule, also lying on a twofold axis. Each ZnIIcentre is surrounded by two O-donor atoms from monodentate carboxylate groups belonging to two different PBEA2−ligands and by two triazole N-donor atoms from two different BTX ligands. Single-crystal X-ray diffraction analysis revealed that the compound has a fivefold interpenetrating diamondoid three-dimensional metal–organic framework.
2021 ◽
Vol 77
(11)
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2013 ◽
Vol 68
(4)
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pp. 351-356
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