Development of thermo-regulating fabrics using PCM microcapsules with poly(methyl methacrylate-co-2-hydroxy ethyl methacrylate) shell and n-alkane core

2019 ◽  
Vol 31 (1) ◽  
pp. 65-79 ◽  
Author(s):  
Ruhan Altun-Anayurt ◽  
Sennur Alay-Aksoy ◽  
Cemil Alkan ◽  
Sena Demirbag ◽  
M. Selda Tözüm
Keyword(s):  
Thermal Stability ◽  
Latent Heat ◽  
Phase Change Materials ◽  
Polarized Light ◽  
Water Emulsion ◽  
Content Type ◽  
Ethyl Methacrylate ◽  
Energy Storage Properties ◽  
Oil In Water Emulsion ◽  
History Test

Purpose The purpose of this paper is to prepare microencapsulated phase change materials (PCMs) and apply them to cotton and wool fabrics for developing thermo-regulating fabrics. Design/methodology/approach Microencapsulated n-hexadecane and n-octadecane with poly(methylmethacrylate-co-2-hydroxy ethyl methacrylate) shell was prepared. Microcapsules were fabricated using oil-in-water emulsion polymerization method. Their chemical structure, microstructure, thermal energy storage properties and thermal stability were analyzed by Fourier-transform infrared spectroscopy, polarized light microscope, differential scanning calorimeter and thermogravimetric analyzer, respectively. The mean particle size was tested by a particle sized instrument. The microcapsules were applied to the wool and cotton fabrics using pad-dry-cure method. The thermo-regulating property of the fabrics was evaluated using the T-History test. The distribution and durability of the microcapsules on the fabrics was investigated with scanning electron microscopy. Findings Spherical microcapsules with p(MMA-co-HEMA) shell and n-alkane core have been produced successfully. n-hexadecane in microcapsule solidifies at 14.8−15.6°C with the latent heat of 65.6−129.8 J/g and melts at 16.7−16.9°C with the latent heat of 67.6−136.9 J/g. Microencapsulated n-octadecane solidifies at 25.8−26.3°C with the latent heat of 74.1−106.2 J/g and melts at 26.8−27.4°C with the latent heat of 80.3−113.4 J/g. The microcapsules have enough thermal stability to the temperature of 150°C that was applied during the fixation of microcapsules on the fabric. The thermo-regulating effect of the microcapsule-incorporated fabrics has been proved by the T-history test. Originality/value PCM microcapsules with p(MMA-co-HEMA) shell and n-hexadecane and n-octadecane core have been produced and their usage to produce thermo-regulating textiles have been proved. To determine the thermo-regulating property of the fabrics treated with these new PCM microcapsules, a T-History system has been designed.

scholarly journals Alga-Produced Malaria Transmission-Blocking Vaccine Candidate Pfs25 Formulated with a Human Use-Compatible Potent Adjuvant Induces High-Affinity Antibodies That Block Plasmodium falciparum Infection of Mosquitoes

2015 ◽  
Vol 83 (5) ◽  
pp. 1799-1808 ◽  
Author(s):  
Kailash P. Patra ◽  
Fengwu Li ◽  
Darrick Carter ◽  
James A. Gregory ◽  
Sheyenne Baga ◽  
...  
Keyword(s):  
Plasmodium Falciparum ◽  
Malaria Vaccine ◽  
Vaccine Development ◽  
Vaccine Candidate ◽  
Water Emulsion ◽  
Transmission Blocking ◽  
Content Type ◽  
Oil In Water ◽  
Oil In Water Emulsion ◽  
Transmission Blocking Vaccine

A vaccine to prevent the transmission of malaria parasites from infected humans to mosquitoes is an important component for the elimination of malaria in the 21st century, yet it remains neglected as a priority of malaria vaccine development. The lead candidate forPlasmodium falciparumtransmission-blocking vaccine development, Pfs25, is a sexual stage surface protein that has been produced for vaccine testing in a variety of heterologous expression systems. Any realistic malaria vaccine will need to optimize proper folding balanced against cost of production, yield, and potentially reactogenic contaminants. HereChlamydomonas reinhardtiimicroalga-produced recombinant Pfs25 protein was formulated with four different human-compatible adjuvants (alum, Toll-like receptor 4 [TLR-4] agonist glucopyranosal lipid A [GLA] plus alum, squalene–oil-in-water emulsion, and GLA plus squalene–oil-in-water emulsion) and compared for their ability to induce malaria transmission-blocking antibodies. Alga-produced recombinant Pfs25 plus GLA plus squalene–oil-in-water adjuvant induced the highest titer and avidity in IgG antibodies, measured using alga-produced recombinant Pfs25 as the enzyme-linked immunosorbent assay (ELISA) antigen. These antibodies specifically reacted with the surface ofP. falciparummacrogametes and zygotes and effectively prevented parasites from developing within the mosquito vector in standard membrane feeding assays. Alga-produced Pfs25 in combination with a human-compatible adjuvant composed of a TLR-4 agonist in a squalene–oil-in-water emulsion is an attractive new vaccine candidate that merits head-to-head comparison with other modalities of vaccine production and administration.

Studies on preparation of Bio-Paints using fungal bio-colors

2016 ◽  
Vol 45 (2) ◽  
pp. 79-85 ◽  
Author(s):  
D. Nithyananda Sastry ◽  
T. Prabhakar ◽  
M. Lakshmi Narasu
Keyword(s):  
Scientific Information ◽  
Research Work ◽  
Cost Effective ◽  
Animal Origin ◽  
Synthetic Dyes ◽  
Water Emulsion ◽  
Content Type ◽  
Fungal Strains ◽  
Oil In Water Emulsion ◽  
Significant Opportunity

Purpose – This paper aims to isolate fungal strains producing natural colours, explore their application as colourant in paints and develop cost-effective durable natural paints. Design/methodology/approach – Fungal strains producing natural colours of different shades were isolated. Colourant production was carried out by fermentation method. Natural lime, milk, oil-in-water emulsion paints using natural microbial colours and eco-friendly ingredients were prepared. Bio-paint applications were carried out and evaluated. Findings – Our results indicate that microbes in general and fungi in specific represent dependable source of variety of natural colours, and cost-effective durable natural paints can be prepared with commonly available natural ingredients using scientific information based on history of paints. Research limitations/implications – Natural colours are gaining importance because of their use in health, nutrition, pharmaceutical, textile and environmental applications. Nature is quite rich in several types of colourants. Chemical synthesis of synthetic dyes is complex and not environmental friendly. Microbial dyes manufactured can evade inherent environmental problems of synthetic dyes and offer significant opportunity as a colourant in paints. However, only generally regarded as safe microbial strains are to be considered for colour production. Practical implications – Choosing natural alternatives to protect the health and environment is the need of hour. Fungal colourants are relatively more stable and robust and offer significant opportunity as a colourant in paints. Cost-effective durable natural paints can be prepared using selected stable fungal colourants with commonly available natural ingredients. High diversity of rich and complex natural colourants can be obtained from microorganisms. With the available techniques of fermentation, natural colours can be produced in large quantities of on an economically viable scale and explored for their applications. Social implications – Bio-paints are eco-friendly natural paints, low volatile organic compounds (VOC) paints or organic paints alternate to conventional paints. Most of these natural paints are durable, breathable, prevent moisture problems, contribute to a positive room climate, use safer technology and are less energy-intensive than conventional latex paints to produce. These paints improve indoor air quality and reduce urban smog and offer beneficial characteristics such as low odour, excellent durability and a washable finish. Originality/value – Many of the old art works that still survive today are a tangible proof and evidence of beauty and durability of natural paints. Organic materials used in these paints include natural pigments of mineral, plant and animal origin and other raw biodegradable ingredients. Successful commercialisation of many microbial pigments for food and textile applications is reported in literature. Therefore, present research work aims at developing natural paints using microbial pigments and recipes that have been successfully used by people for years.

Selection of Phase Change Materials for Latent Heat Storage

2017 ◽  
Vol 13 (1) ◽  
Author(s):  
J. Martínez-Gómez ◽  
E. Urresta ◽  
D. Gaona ◽  
G. Guerrón
Keyword(s):  
Phase Change ◽  
Latent Heat ◽  
Phase Change Materials ◽  
Heat Storage ◽  
Latent Heat Storage ◽  
Toma De Decisiones ◽  
Selection Of

Esta investigación tiene como objetivo seleccionar un material de cambio de fase (PCM) que cumplen mejor la solución del almacenamiento de energía térmica entre 200-400 ° C y reducir el costo de producción. El uso de métodos multicriterios de toma de decisiones (MCMD) para la evaluación fueron proporcionales implementados como COPRAS-G, TOPSIS y VIKOR. La ponderación de los criterios se realizó por el método AHP (proceso analítico jerárquico) y los métodos de entropía. La correlación de los resultados entre los tres métodos de clasificación ha sido desarrollada por el coeficiente de correlación de Spearman. Los resultados ilustran el mejor y la segundo mejor opción para los tres MCDM fueron NaOH y KNO3. Además, tenía valores de correlación de Spearman entre los métodos excede de 0.714.

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