Hyperbranched additive into a high solid acrylate coating for automotive application: impact on performance and emission of volatile organic content

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Botros Meglaa ◽  
Magda Tawfik ◽  
Fatma Morsy ◽  
Samya Elsherbiny ◽  
Hisham Essawy

Purpose Automotive coating materials are very important items for this industry. However, their performance is limited by the use of excessive amounts of solvents in their formulations, whereas the emission of volatile organic solvents is against the widely ascending principle of green chemistry. Thus, this study aims to overcome this global problem to save the environment without affecting the properties and performance of the coating. Design/methodology/approach High solid content paint formulation for automotive applications has been designed with low amount of volatile organic solvents with the aid of a functionalized hyperbranched modifier. Findings It was found that the presence of a hyperbranched additive allows a high solid content to be designed and facilitate the processing, which indicates its liability to compensate the role played by excessive solvents amounts. In addition, the mechanical properties and physical characteristics of the modified coatings showed outstanding performance and preservation of clarity in comparison with the commercial counterparts. Practical implications A high solid content coating with facile processing and improved performance leads to cheaper price beside the positive impact on the environment considering the limited emission of volatile organic contents. Social implications Limitation of the used volatile organic compounds in any industry helps to save the health of humans and keep the environment unaffected. Originality/value The use of functionalized hyperbranched additive to automotive coatings is a very promising additive for automotive coatings with optimized characteristics.

2017 ◽  
Vol 31 (9) ◽  
pp. 1149-1160 ◽  
Author(s):  
Keyi Ding ◽  
Jun Liu ◽  
Hualin Chen ◽  
Hongdan Wang

A novel high solids acrylic resin (HSARs) with high solid content (78%) was synthesized from co-polymerization of the methyl methacrylate, butyl acrylate, acrylate acid, hydroxyl propyl acrylate, and hyper-branched macromonomer (HBM) in this study. The HBM was prepared by an “A2 + B3 + CA2” reaction system that covers four steps. The progress of each step of the reaction was monitored by real-time analysis for acid value and hydroxyl value of the reactants. Fourier transform infrared spectroscopy (FTIR) and 1H nuclear magnetic resonance (NMR) was employed to characterize the structure of HBM. The viscosity, mechanical properties, solvent resistance, and volatile organic compounds (VOC) of the HSARs were also assessed. Compared with conventional commercial polyacrylate resin with a 42% solid content, solid content of HSARs was increased by 78% and VOC was decreased by 40% due to the addition of HBM. Moreover, the HSARs resin possesses good solvent resistance and lower viscosity, which provides the possibility of decreasing the organic solvent when using them to make operational coatings.


2021 ◽  
Vol 28 (7) ◽  
Author(s):  
Wenqi Xian ◽  
Jie Yuan ◽  
Zhengbin Xie ◽  
Wei Ou ◽  
Xiaoxuan Liu ◽  
...  

Author(s):  
Haomiao Yu ◽  
Sensen Sun ◽  
Jianbing Gao ◽  
Xiaoxun Jin ◽  
Jie Liu ◽  
...  

2021 ◽  
Vol 164 ◽  
pp. 113396
Author(s):  
Xiaojuan Chen ◽  
Zhonghua Li ◽  
Lidan Zhang ◽  
Haoran Wang ◽  
Congzhi Qiu ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document