Long-term behavior of IMCs in lead-free solder joints

Author(s):  
Tomas Novak ◽  
Tomas Hujer ◽  
Frantisek Steiner
Author(s):  
Jing Wu ◽  
Mohammad S. Alam ◽  
Jeffrey C. Suhling ◽  
Pradeep Lall

Abstract Aging effects are common in lead free solder joints within electronic assemblies that are exposed to isothermal environments for extended periods. Such exposures lead to evolution of the solder microstructure, which results in changes in the mechanical properties and creep behavior of the solder joints. In our recent investigations, we have been utilizing Scanning Electron Microscopy (SEM) to better understand aging induced degradations. The microstructural evolutions were observed in SAC305 and SAC_Q (SAC+Bi) alloys exposed to isothermal conditions at T = 125 °C for several different regions from several different joints. The microstructures in several fixed regions of interest were recorded after predetermined time intervals of aging, which were 1 hour (up to 24 hours) and 10 hours (up to 150 hours) for the short term aging samples; and 250 hours (up to 2500 hours) for the long term aging samples. Using the recorded images and imaging processing software, the area and diameter of each IMC particle was tracked during the aging process. As expected, the quantitative analysis of the evolving SAC_Q microstructure showed that the particles coalesced during aging leading to a decrease in the number of particles. This caused an increase in the average diameter of the particles of slightly more than 100% for long term aging of 2500 hours. For SAC305, the average particle diameter was found to increase at three times the rate (increase of 200% after 2500 hours of aging). Thus, coarsening of IMC particles was greatly mitigated in the SAC_Q alloy relative to that observed in SAC305. Immediately after reflow solidification, Bismuth rich phases were present in the SAC_Q joints. During aging at T = 125 °C, the bismuth was observed to quickly go into solution both within the beta-Sn dendrites and in the intermetallic rich regions between dendrites. This resulted in solid solution strengthening of the lead free solder. It was also found that the aging-induced presence of bismuth in solution within the beta-Sn matrix provided an increased resistance to the Ostwald ripening diffusion process that coarsens the Ag3Sn IMC particles. The combination of these two effects in the SAC+Bi alloy lead to greatly improved resistance to aging induced effects relative to the SAC305 solder alloy. Finally, we have compared the time dependent evolution of microstructure with the degradation in strength during aging for of the two solder alloys, and good correlations were observed.


2010 ◽  
Vol 7 (2) ◽  
pp. 1
Author(s):  
Ramani Mayappan ◽  
Zainal Arifin Ahmad

Replacing Sn-Pb solder with lead-free solder is a great challenge in the electronics industry. The presented lead-free solder is Sn based and forms two intermetallic species upon reaction with the Cu substrate, namely Cu6Sn5 and Cu3Sn. The growth of Cu6Sn5 and Cu3Sn intermetallics have been investigated with respect to Sn-40Pb/Cu solder joints. The joints were aged under long-term thermal exposure using single shear lap joints and the intermetallics were observed using scanning electron microscopy. As-soldered solder joints exhibit a single Cu6Sn5 phase, however after aging a Cu3Sn layer below the Cu6Sn5 is observed to manifest. The Cu6Sn5 layer develops with a scalloped morphology, whereas the Cu in layer always develops an undulating planar shape in phase with the Cu6Sn5. The Cu6Sn5 layer begins to transform from a scalloped- to a planar-shape as aging progresses in order to minimize the interfacial energy. The intermetallic layers exhibit a linear dependence on the square root of aging time, which corresponds to diffusion-controlled growth. The activation energy for the growth of the Cu6Sn5 intermetallic layer has been determined to be 56.16 kJ/mol.


2018 ◽  
Vol 140 (3) ◽  
Author(s):  
Sinan Su ◽  
Nianjun Fu ◽  
Francy John Akkara ◽  
Sa'd Hamasha

Solder joints in electronic assemblies are subjected to mechanical and thermal cycling. These cyclic loadings lead to the fatigue failure of solder joints involving damage accumulation, crack initiation, crack propagation, and failure. Aging leads to significant changes on the microstructure and mechanical behavior of solder joints. While the effect of thermal aging on solder behavior has been examined, no prior studies have focused on the effect of long-term room temperature aging (25 °C) on the solder failure and fatigue behavior. In this paper, the effects of long-term room temperature aging on the fatigue behavior of five common lead-free solder alloys, i.e., SAC305, SAC105, SAC-Ni, SAC-X-Plus, and Innolot, have been investigated. Several individual lead-free solder joints on printed circuited boards with two aging conditions (no aging and 4 years of aging) have been prepared and subjected to shear cyclic stress–strain loadings until the complete failure. Fatigue life was recorded for each solder alloy. From the stress–strain hysteresis loop, inelastic work and plastic strain ranges were measured and empirically modeled with the fatigue life. The results indicated that 4 years of room temperature aging significantly decreases the fatigue life of the solder joints. Also, inelastic work per cycle and plastic strain range are increased after 4 years of room temperature aging. The fatigue life degradation for the solder alloys with doped elements (Ni, Bi, Sb) was relatively less compared to the traditional SAC105 and SAC305.


2017 ◽  
Vol 66 (4) ◽  
pp. 1229-1237 ◽  
Author(s):  
P. Wild ◽  
T. Grozinger ◽  
D. Lorenz ◽  
A. Zimmermann

2015 ◽  
Vol 772 ◽  
pp. 284-289 ◽  
Author(s):  
Sabuj Mallik ◽  
Jude Njoku ◽  
Gabriel Takyi

Voiding in solder joints poses a serious reliability concern for electronic products. The aim of this research was to quantify the void formation in lead-free solder joints through X-ray inspections. Experiments were designed to investigate how void formation is affected by solder bump size and shape, differences in reflow time and temperature, and differences in solder paste formulation. Four different lead-free solder paste samples were used to produce solder bumps on a number of test boards, using surface mount reflow soldering process. Using an advanced X-ray inspection system void percentages were measured for three different size and shape solder bumps. Results indicate that the voiding in solder joint is strongly influenced by solder bump size and shape, with voids found to have increased when bump size decreased. A longer soaking period during reflow stage has negatively affectedsolder voids. Voiding was also accelerated with smaller solder particles in solder paste.


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