Temperature dependences of the dielectric permittivity and dissipation factor for nanocomposites metal-polymer

Author(s):  
Yuriy Didenko ◽  
Dmitry Tatarchuk ◽  
Ievgen Kharabet ◽  
Anton Franchuk ◽  
Yuriy Yakimenko
2013 ◽  
Vol 58 (4) ◽  
pp. 1401-1403 ◽  
Author(s):  
J.A. Bartkowska ◽  
R. Zachariasz ◽  
D. Bochenek ◽  
J. Ilczuk

Abstract In the present work, the magnetoelectric coupling coefficient, from the temperature dependences of the dielectric permittivity for the multiferroic composite was determined. The research material was ferroelectric-ferromagnetic composite on the based PZT and ferrite. We investigated the temperature dependences of the dielectric permittivity (") for the different frequency of measurement’s field. From the dielectric measurements we determined the temperature of phase transition from ferroelectric to paraelectric phase. For the theoretical description of the temperature dependence of the dielectric constant, the Hamiltonian of Alcantara, Gehring and Janssen was used. To investigate the dielectric properties of the multiferroic composite this Hamiltonian was expressed under the mean-field approximation. Based on dielectric measurements and theoretical considerations, the values of the magnetoelectric coupling coefficient were specified.


2003 ◽  
Vol 58 (9-10) ◽  
pp. 541-545 ◽  
Author(s):  
P. Malik ◽  
S. J. Rzoska ◽  
A. Drozd-Rzoska ◽  
W. W. Sułkowskia ◽  
J. Jadzynb

The dielectric properties of a homogenous critical mixture of nitrobenzene-decane were studied in the range 1 Hz< f1 Mz. The temperature dependences of the “static” dielectric permittivity ε’ (1 MHz) and the electric conductivity σ(1 Hz) exhibit pretransitional anomalies which may be associated with the same critical exponent ø = 1−α ≈ 0.88, where α is the critical exponent of the specific heat. The same data were analyzed using the dielectric modulus representation. They show loss curves for the imaginary part of the modulus M ̋( f ). It was found that the temperature evolutions of the peak frequency τ = 1/2π fp and the peak maximum of M ̋ =M ̋( fp) also exhibit critical anomalies. Their forms resemble anomalies obtained for the imaginary part of the dielectric permittivity ε̋( f ), carried out for 40 MHz < f <1 GHz, in an ethanol-dodecane critical mixture [S. J. Rzoska, K. Orzechowski, and A. Drozd-Rzoska, Phys. Rev. E 65, 042501 (2002)]. - PACS: 64.70.Ja, 77.20.+y , 64.60.Fr


2014 ◽  
Vol 633 ◽  
pp. 362-365
Author(s):  
Min Chen ◽  
X.A. Mei ◽  
C.Q. Huang

Bi3.25Ho0.75Ti2.97V0.03O12(BHTV) ceramics was prepared by solid state reaction. This sample had polycrystalline Bi-layered perovskite structure without preferred orientation, and consisted of well developed plate-like grains with random orientation. BHTV caused a large shift of the Curie temperature ( TC) of Bi4Ti3O12(BIT) from 675 °C to 398 °C. The remanent polarization and the coercive field of the BHTV ceramics were 28μC/cm2and 56kV/cm at an electric field of 90kV/cm, respectively. Furthermore, the dielectric permittivity and dissipation factor were 298 and 2.8×10-3at 1MHz, respectively. These ferroelectric properties of BHTV ceramics are superior to V-doped Bi4Ti3O12(~20μC/cm2and 80kV/cm) and (Sr, Ta)-doped Bi4Ti3O12(~12μC/cm2and 71kV/cm) ceramics. In addition, the dense ceramics of BHTV could be obtained by sintering at temperatures 100─200 °C lower than those of the SrBi2Ta2O9system.


2015 ◽  
Vol 1107 ◽  
pp. 217-222 ◽  
Author(s):  
Ahmad Fairoz Aziz ◽  
Khuzaimah Nazir ◽  
Siti Fadzilah Ayub ◽  
Rosnah Zakaria ◽  
Muhd Zu Azhan Yahya ◽  
...  

Methyl-grafted natural rubber (MG30) was treated with N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine (6PPD) to enhance it anti-aging properties. The treated MG30 was used as polymer electrolyte by incorporating lithium trifluoromethane sulfonate (LiTF) through solution-cast technique. The impedance behavior of the sample has been carried out by analyzing the dielectric permittivity, dissipation factor, dielectric modulus and ionic conductivity as a function of temperature at different frequencies through impedance spectroscopy. Keywords: Methyl-grafted natural rubber, polymer electrolyte, N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine, ionic conductivity, dielectric.


2011 ◽  
Vol 412 ◽  
pp. 310-313
Author(s):  
J. Liu ◽  
Min Chen ◽  
X.A. Mei ◽  
Y.H. Sun ◽  
Chong Qing Huang

Bi3.25La0.75Ti2.97V0.03O12(BLTV) ceramic were prepared by solid state reaction. These samples had polycrystalline Bi-layered perovskite structure without preferred orientation, and consisted of well developed plate-like grains with random orientation. BLTV caused a large shift of the Curie temperature ( TC) of Bi4Ti3O12(BIT) from 675°C to 395°C. The remanent polarization and the coercive field of the BLTV were 31μC/cm2and 54kV/cm at an electric field of 90kV/cm, respectively. Furthermore, the dielectric permittivity and dissipation factor were 300 and 3×10-3at 1MHz, at 1V and at room temperature, respectively. These ferroelectric properties of BLTV are superior to V-doped Bi4Ti3O12(~20μC/cm2and 80kV/cm) and (Sr, Ta)-doped Bi4Ti3O12(~12μC/cm2and 71kV/cm) ceramics. In addition, the dense ceramics of BLTV could be obtained by sintering at temperatures 100─200°C lower than those of the SrBi2Ta2O9system.


2021 ◽  
Author(s):  
N. Kanwal ◽  
S. Pervaiz ◽  
A. Rasheed ◽  
M. Saleem ◽  
Ijaz Ahmad Khan

Abstract Polymer-based ZnO/TiO2 NCs flexible sheets with high dielectric permittivity and low loss factor have numerous applications in light emitting and energy storage devices. In this work, polymer-based ZnO/TiO2 NCs are synthesized by co-precipitation technique. The development of various diffraction planes (X-rays diffraction analysis) related to TiO2 and ZnO phases confirms the synthesis of polycrystalline polymer-based ZnO/TiO2 NCs. The crystallinity of various phases is associated with increasing ZnO nanofillers. The surface morphology (scanning electron microscopic analysis) comprising of nanoparticles of different shapes is associated with increasing amount of nanofillers. The EDX analysis confirms the presence of Zn, O and Ti in the synthesized polymer-based ZnO/TiO2 NCs. Dielectric measurements demonstrating the sharp increase in dielectric permittivity with relatively low dissipation factor of synthesized polymer-based ZnO/TiO2 NCs are associated with increasing amount of ZnO nanofillers. The static value of dielectric constant (e’) at low frequency (100 Hz) is found to be 14.56 for sample having 10% ZnO nanofillers that is 2.11 times greater than pure PVDF and it shows relatively low value of dissipation factor. The observed σac of synthesized polymer-based ZnO/TiO2 NCs at 3.0×105 Hz and 1.0×106 Hz are ranged from 3.75-9.79 and 15.61-42.72 mS/m respectively. The decreasing complex impedance and increasing electric modulus further confirm that the synthesized polymer-based ZnO/TiO2 NCs flexible sheets are the promising candidate for better capacitive performance showing high strength and flexibility.


1999 ◽  
Vol 574 ◽  
Author(s):  
Choong-Rae Cho ◽  
S. I. Khartsev ◽  
A. M. Grishin ◽  
Ture Lindbäick

AbstractWe report on ferroelectric/giant magnetoresistive Na0.5K0.5NbO3/La0.6Sr0.2Mn1.2O3 (NKN/LSMO) heterostructures grown onto LaAlO3 (001) single crystal using KrF pulsed laser ablation of stoichiometric ceramic target. Main processing parameters have been optimized to obtain smooth LSMO template layer, avoid NKN-LSMO interdiffusion, preserve NKN stoichiometry against the lost of volatile potassium and sodium and achieve reasonable reliability of NKN film performance. X-ray diffraction θ- 2θ scans and rocking curves evidence for single-phase content and high c-axis orientation both in template LSMO and top NKN layers. Ferroelectric measurements yield remnant polarization Pr of 1.5 [C/cm2 and spontaneous polarization Ps of 7 μC/cm2 at electric field strength of 130 kV/cm. At room temperature, dielectric permittivity ε′ and dissipation factor tan δ have been found to vary from 595 to 555 and 0.046 to 0.029 respectively in the frequency range of 0.4 to 20 kHz. At 10 kHz dielectric permittivity linearly increases from 410 to 650 in the temperature range 77 K to 415 K while the dissipation factor below 320 K does not exceed 3%.


2011 ◽  
Vol 492 ◽  
pp. 214-217
Author(s):  
Chong Qing Huang ◽  
M. Chen ◽  
X.A. Mei ◽  
Y.H. Sun ◽  
J. Liu

Bi3.25Gd0.75Ti2.97V0.03O12(BGTV)ceramic were prepared by solid state reaction. These samples had polycrystalline Bi-layered perovskite structure without preferred orientation, and consisted of well developed plate-like grains with random orientation. BGTV caused a large shift of the Curie temperature ( TC) of Bi4Ti3O12(BIT) from 675°C to 398°C. The remanent polarization and the coercive field of the BGTV were 30μC/cm2and 52kV/cm at an electric field of 87kV/cm, respectively. Furthermore, the dielectric permittivity and dissipation factor were 300 and 0.003 at 1MHz, at 1V and at room temperature, respectively. These ferroelectric properties of BGTV are superior to V-doped Bi4Ti3O12(~20μC/cm2and 80kV/cm) and (Sr, Ta)-doped Bi4Ti3O12(~12μC/cm2and 71kV/cm) ceramics. In addition, the dense ceramics of BGTV could be obtained by sintering at temperatures 100─200°C lower than those of the SrBi2Ta2O9system.


2009 ◽  
Vol 3 (1) ◽  
pp. 47-51
Author(s):  
Shilpa Pande ◽  
◽  
Deepali Kelkar ◽  
Dilip Peshwe ◽  
◽  
...  

The dielectric studies of semi-crystalline Nylon 11 filled with a conducting polymer (PANI) were investigated in a wide range of frequency and temperature by using Impedance Analyzer. The main focus was on the effects of conducting filler content on dielectric properties of Nylon 11. The prominent factors such as dielectric permittivity, loss factor, and loss tangent were studied at high frequency. Two different concentrations (1 % and 5 % w/w) of the conducting filler were used. It was observed that with the increase of fillers concentration, the value of dielectric permittivity (ε’)б The dissipation factor (ε’’) and loss (tan ) decrease compared to pure Nylon 11.


Sign in / Sign up

Export Citation Format

Share Document