SEPARATION OF XYLOSE FROM GLUCOSE USING PILOT SCALE SPIRAL WOUND COMMERCIAL MEMBRANE

2016 ◽  
Vol 78 (12) ◽  
Author(s):  
N. Fatihah M. Roli ◽  
Hafizuddin W. Yussof ◽  
Syed M. Saufi ◽  
Mazrul N. Abu Seman ◽  
Abdul W. Mohammad
Keyword(s):  
High Performance ◽  
Flow System ◽  
Pure Water ◽  
Cross Flow ◽  
Cost Effective ◽  
Pilot Scale ◽  
Nanofiltration Membrane ◽  
Ultrapure Water ◽  
Selective Membrane ◽  
Spiral Wound

Xylose is an intermediate product in xylitol production and glucose interferes in the process of separation. Thus the aim of this study is to investigate the performance of pilot scale commercial spiral wound NF membrane namely Desal-5 DK, Desal-5 DL and NF90 for separation of xylose from glucose. Separation of xylose and glucose model solutions was done in a pilot scale cross-flow system, using a commercial nanofiltration (NF) membrane with molecular weight cut off (MWCO) ranging from 150 to 1000 g/mol. The model solution consists of 1:1 ratio of xylose to glucose at 10 g/L each diluted in ultrapure water. The filtration was operated in total recycled mode at 10 bar. The sugar concentration was analyzed using high performance liquid chromatography (HPLC). From this study, the pure water permeability (PWPs) of the Desal-5 DK membrane was considerably higher at 6.78 ± 0.06 than PWPs of the Desal-5 DL and NF90 membranes at 1.28 ± 0.24 and 1.33 ± 0.05, respectively. The Desal-5 DK also gave the higher xylose separation factor at 1.17 as compare to Desal-5 DL (0.81) and NF90 membranes (0.84). This indicates that membrane Desal-5 DK was the most selective membrane to separate xylose form glucose. Overall, it can be concluded that the spiral wound nanofiltration membrane offers cost-effective and easy-maintenance, which has a potential in xylose-glucose separation.

scholarly journals Influences of Technological Parameters on Cross-Flow Nanofiltration of Cranberry Juice

Membranes ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 329
Author(s):  
Dat Quoc Lai ◽  
Nobuhiro Tagashira ◽  
Shoji Hagiwara ◽  
Mitsutoshi Nakajima ◽  
Toshinori Kimura ◽  
...  
Keyword(s):  
Benzoic Acid ◽  
Cross Flow ◽  
Pilot Scale ◽  
Nanofiltration Membrane ◽  
Feed Flow Rate ◽  
Permeate Flux ◽  
Cranberry Juice ◽  
Technological Parameters ◽  
Optimum Ph ◽  
Module Type

The paper focused on the influence of operative conditions on the separation of benzoic acid from 10 °Brix cranberry juice by cross-flow nanofiltration with a plate and frame pilot scale (DDS Lab Module Type 20 system). Six kinds of commercial nanofiltration membrane were investigated. The results showed that the rejection of benzoic acid was significantly lower than that of other components in cranberry juice, including sugars and other organic acids. In a range of 2–7.5 L/min, feed flow rate slightly affected the performance of nanofiltration. Higher temperatures resulted in higher permeate flux and lower rejection of benzoic acid, whereas rejection of sugar and organic acid was stable at a high value. In a range of 2.5–5.5, pH also significantly affected the separation of benzoic acid and negative rejection against benzoic acid was observed at pH 4.5 with some of the membranes. This implies that pH 4.5 is considered as an optimum pH for benzoic acid separation from cranberry juice. The lower permeate flux caused a lower rejection of benzoic acid and negative rejection of benzoic acid was observed at the low permeate flux. Pretreatment by ultrafiltration with CR61PP membranes could improve the permeate flux but insignificantly influenced the efficiency of separation. The results also indicated that NF99 and DK membranes can be effectively used to separate benzoic acid from cranberry juice.

scholarly journals Separation of Fructose and Glucose via Nanofiltration in Presence of Fructooligosaccharides

Membranes ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 298
Author(s):  
Zulhaj Rizki ◽  
Anja E. M. Janssen ◽  
Albert van der Padt ◽  
Remko M. Boom
Keyword(s):  
Molecular Weight ◽  
Cost Effective ◽  
Pilot Scale ◽  
Nanofiltration Membrane ◽  
Selective Transport ◽  
Rejection Ratio ◽  
Molecular Weight Cutoff ◽  
Cost Effective Method ◽  
Glucose Ratio ◽  
Preferential Binding

Fructose and glucose are commonly present together in mixtures and may need to be separated. Current separation methods for these isomers are complex and costly. Nanofiltration is a cost-effective method that has been widely used for separating carbohydrates of different sizes; however, it is not commonly used for such similar molecules. Here, we report the separation of fructose and glucose in a nanofiltration system in the presence of fructooligosaccharides (FOS). Experiments were performed using a pilot-scale filtration setup using a spiral wound nanofiltration membrane with molecular weight cutoff of 1 kDa. We observed three important factors that affected the separation: (1) separation of monosaccharides only occurred in the presence of FOS and became more effective when FOS dominated the solution; (2) better separation was achieved when the monosaccharides were mainly fructose; and (3) the presence of salt improved the separation only moderately. The rejection ratio (Rf/Rg) in a fructose/glucose mixture is 0.92. We reported a rejection ratio of 0.69, which was observed in a mixture of 50 g/L FOS with a fructose to glucose ratio of 4.43. The separation is hypothesized to occur due to selective transport in the FOS layer, resulting in a preferential binding towards fructose.

scholarly journals Color Removal from Wastewater using a Synthetic High Performance Antifouling GO-CPTMS@Pd-TKHPP/Polyether Sulfone Nanofiltration Membrane

2021 ◽  
Author(s):  
foad gholami ◽  
sirus zinadini ◽  
Soheila Nakhjiri Kamrani ◽  
ali akbar zinatizadeh ◽  
Kiumars Bahrami
Keyword(s):  
Graphene Oxide ◽  
High Performance ◽  
Pure Water ◽  
Water Flux ◽  
Nanofiltration Membrane ◽  
Powdered Milk ◽  
Water Contact ◽  
Polyether Sulfone ◽  
Modified Graphene Oxide ◽  
Modified Graphene

Abstract Modified graphene oxide with 5,10,15,20-tetrakis‐(4‐hexyloxyphenyl) ‐porphyrin and palladium (II) (signified by GO-CPTMS@Pd-TKHPP) prepared as a novel antifouling polyether sulfone (PES) blended nanofiller membrane. The membrane efficiency has been analyzed such as pure water flux (PWF), hydrophilicity and antifouling features. By increasing of modified graphene oxide percentage from 0 to 0.1 wt.% in polymer matrix the PWF was incremented from 14.35 to 37.33 kg/m2.h at 4bar. The membrane flux recovery ratio (FRR) has been investigated by applying powdered milk solution, the FRR results indicated that the 0.1 wt.% modified graphene oxide membrane showed the positive effect on fouling behavior with Rir and FRR value 8.24 and 91.73% respectively. The nanofiltration membrane performance was assessed applying the Direct Red 16 dye rejection. It was demonstrated that the optimal membranes (0.1 wt.% modified graphene oxide) had notable dye removal (99.58 % rejection). The results are also verified by measuring the scanning electron microscopy (SEM), water contact angle (WCA) and atomic microscopy analysis (AFM).

Mineral/microfibrillated cellulose composite materials: High performance products, applications, and product forms

TAPPI Journal ◽  
2018 ◽  
Vol 17 (09) ◽  
pp. 507-515 ◽  
Author(s):  
David Skuse ◽  
Mark Windebank ◽  
Tafadzwa Motsi ◽  
Guillaume Tellier
Keyword(s):  
Composite Materials ◽  
High Performance ◽  
Aqueous Suspension ◽  
Production Capacity ◽  
Cost Savings ◽  
Cost Effective ◽  
New Materials ◽  
Wet Strength ◽  
Product Forms ◽  
Cellulose Composite

When pulp and minerals are co-processed in aqueous suspension, the mineral acts as a grinding aid, facilitating the cost-effective production of fibrils. Furthermore, this processing allows the utilization of robust industrial milling equipment. There are 40000 dry metric tons of mineral/microfbrillated (MFC) cellulose composite production capacity in operation across three continents. These mineral/MFC products have been cleared by the FDA for use as a dry and wet strength agent in coated and uncoated food contact paper and paperboard applications. We have previously reported that use of these mineral/MFC composite materials in fiber-based applications allows generally improved wet and dry mechanical properties with concomitant opportunities for cost savings, property improvements, or grade developments and that the materials can be prepared using a range of fibers and minerals. Here, we: (1) report the development of new products that offer improved performance, (2) compare the performance of these new materials with that of a range of other nanocellulosic material types, (3) illustrate the performance of these new materials in reinforcement (paper and board) and viscosification applications, and (4) discuss product form requirements for different applications.

Parallel Computing for Tire Simulations

2011 ◽  
Vol 39 (3) ◽  
pp. 193-209 ◽  
Author(s):  
H. Surendranath ◽  
M. Dunbar
Keyword(s):  
High Performance ◽  
Effective Means ◽  
Cost Effective ◽  
Turnaround Time ◽  
Careful Consideration ◽  
Rolling Contact ◽  
Element Analysis ◽  
Parallel Solvers ◽  
Design Changes ◽  
Highly Nonlinear

Abstract Over the last few decades, finite element analysis has become an integral part of the overall tire design process. Engineers need to perform a number of different simulations to evaluate new designs and study the effect of proposed design changes. However, tires pose formidable simulation challenges due to the presence of highly nonlinear rubber compounds, embedded reinforcements, complex tread geometries, rolling contact, and large deformations. Accurate simulation requires careful consideration of these factors, resulting in the extensive turnaround time, often times prolonging the design cycle. Therefore, it is extremely critical to explore means to reduce the turnaround time while producing reliable results. Compute clusters have recently become a cost effective means to perform high performance computing (HPC). Distributed memory parallel solvers designed to take advantage of compute clusters have become increasingly popular. In this paper, we examine the use of HPC for various tire simulations and demonstrate how it can significantly reduce simulation turnaround time. Abaqus/Standard is used for routine tire simulations like footprint and steady state rolling. Abaqus/Explicit is used for transient rolling and hydroplaning simulations. The run times and scaling data corresponding to models of various sizes and complexity are presented.

Modern opportunities for preparation of ultra-pure water for feeding high-performance boiler plants

2020 ◽  
pp. 74-84
Author(s):  
A.A. Filimonova ◽  
◽  
N.D. Chichirova ◽  
A.A. Chichirov ◽  
A.A. Batalova ◽  
...  
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
High Performance ◽  
Waste Heat ◽  
Pure Water ◽  
Combined Cycle ◽  
Feed Water ◽  
Operational Characteristics ◽  
Treatment Equipment

The article provides an overview of modern high-performance combined-cycle plants and gas turbine plants with waste heat boilers. The forecast for the introduction of gas turbine equipment at TPPs in the world and in Russia is presented. The classification of gas turbines according to the degree of energy efficiency and operational characteristics is given. Waste heat boilers are characterized in terms of design and associated performance and efficiency. To achieve high operating parameters of gas turbine and boiler equipment, it is necessary to use, among other things, modern water treatment equipment. The article discusses modern effective technologies, the leading place among which is occupied by membrane, and especially baromembrane methods of preparing feed water-waste heat boilers. At the same time, the ion exchange technology remains one of the most demanded at TPPs in the Russian Federation.

Azo (Hydrazone) pigments: general principles

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Robert Christie
Keyword(s):  
High Performance ◽  
Metal Salt ◽  
Low Cost ◽  
Cost Effective ◽  
Precipitation Process ◽  
Ambient Temperatures ◽  
Technical Performance ◽  
Chemical Structures ◽  
General Chemical ◽  
Physical Form

Abstract This paper presents an overview of the general chemical principles underlying the structures, synthesis and technical performance of azo pigments, the dominant chemical class of industrial organic pigments in the yellow, orange, and red shade areas, both numerically and in terms of tonnage manufactured. A description of the most significant historical features in this group of pigments is provided, starting from the discovery of the chemistry on which azo colorants are based by Griess in the mid-nineteenth century, through the commercial introduction of the most important classical azo pigments in the early twentieth century, including products known as the Hansa Yellows, β-naphthol reds, including metal salt pigments, and the diarylide yellows and oranges, to the development in the 1950s and 1960s of two classes of azo pigments that exhibit high performance, disazo condensation pigments and benzimidazolone-based azo pigments. A feature that complicates the description of the chemical structures of azo pigments is that they exist in the solid state as the ketohydrazone rather than the hydroxyazo form, in which they have been traditionally been illustrated. Numerous structural studies conducted over the years on an extensive range of azo pigments have demonstrated this feature. In this text, they are referred to throughout as azo (hydrazone) pigments. Since a common synthetic procedure is used in the manufacture of virtually all azo (hydrazone) pigments, this is discussed in some detail, including practical aspects. The procedure brings together two organic components as the fundamental starting materials, a diazo component and a coupling component. An important reason for the dominance of azo (hydrazone) pigments is that they are highly cost-effective. The syntheses generally involve low cost, commodity organic starting materials and are carried out in water as the reaction solvent, which offers obvious economic and environmental advantages. The versatility of the approach means that an immense number of products may be prepared, so that they have been adapted structurally to meet the requirements of many applications. On an industrial scale, the processes are straightforward, making use of simple, multi-purpose chemical plant. Azo pigments may be produced in virtually quantitative yields and the processes are carried out at or below ambient temperatures, thus presenting low energy requirements. Finally, provided that careful control of the reaction conditions is maintained, azo pigments may be prepared directly by an aqueous precipitation process that can optimise physical form, with control of particle size distribution, crystalline structure, and surface character. The applications of azo pigments are outlined, with more detail reserved for subsequent papers on individual products.

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