scholarly journals Separation of Fructose and Glucose via Nanofiltration in Presence of Fructooligosaccharides

Membranes ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 298
Author(s):  
Zulhaj Rizki ◽  
Anja E. M. Janssen ◽  
Albert van der Padt ◽  
Remko M. Boom

Fructose and glucose are commonly present together in mixtures and may need to be separated. Current separation methods for these isomers are complex and costly. Nanofiltration is a cost-effective method that has been widely used for separating carbohydrates of different sizes; however, it is not commonly used for such similar molecules. Here, we report the separation of fructose and glucose in a nanofiltration system in the presence of fructooligosaccharides (FOS). Experiments were performed using a pilot-scale filtration setup using a spiral wound nanofiltration membrane with molecular weight cutoff of 1 kDa. We observed three important factors that affected the separation: (1) separation of monosaccharides only occurred in the presence of FOS and became more effective when FOS dominated the solution; (2) better separation was achieved when the monosaccharides were mainly fructose; and (3) the presence of salt improved the separation only moderately. The rejection ratio (Rf/Rg) in a fructose/glucose mixture is 0.92. We reported a rejection ratio of 0.69, which was observed in a mixture of 50 g/L FOS with a fructose to glucose ratio of 4.43. The separation is hypothesized to occur due to selective transport in the FOS layer, resulting in a preferential binding towards fructose.

1992 ◽  
Vol 26 (5-6) ◽  
pp. 1097-1104 ◽  
Author(s):  
A. Lyngå ◽  
P. Balmér

Post-nitrification and recycling of the nitrified effluent to an anoxic zone in an activated sludge system for denitrification is proposed as a potentially cost-effective method for nitrogen removal in existing activated sludge treatment plants. Denitrification in a non-nitrifying activated sludge system with a SRT of 3-4 days has been studied in pilot scale. The results show that denitrification rates of at least 10 g N03-N/(kgVSS h) can be achieved. At COD/NO3-N ratios above 15, nitrate supply appears to control the denitrification rate while at COD/NO3-N ratios below 15 the rate appears to be controlled by the supply of easily biodegradable organic matter.


2016 ◽  
Vol 78 (12) ◽  
Author(s):  
N. Fatihah M. Roli ◽  
Hafizuddin W. Yussof ◽  
Syed M. Saufi ◽  
Mazrul N. Abu Seman ◽  
Abdul W. Mohammad

Xylose is an intermediate product in xylitol production and glucose interferes in the process of separation. Thus the aim of this study is to investigate the performance of pilot scale commercial spiral wound NF membrane namely Desal-5 DK, Desal-5 DL and NF90 for separation of xylose from glucose. Separation of xylose and glucose model solutions was done in a pilot scale cross-flow system, using a commercial nanofiltration (NF) membrane with molecular weight cut off (MWCO) ranging from 150 to 1000 g/mol. The model solution consists of 1:1 ratio of xylose to glucose at 10 g/L each diluted in ultrapure water. The filtration was operated in total recycled mode at 10 bar. The sugar concentration was analyzed using high performance liquid chromatography (HPLC). From this study, the pure water permeability (PWPs) of the Desal-5 DK membrane was considerably higher at 6.78 ± 0.06 than PWPs of the Desal-5 DL and NF90 membranes at 1.28 ± 0.24 and 1.33 ± 0.05, respectively. The Desal-5 DK also gave the higher xylose separation factor at 1.17 as compare to Desal-5 DL (0.81) and NF90 membranes (0.84). This indicates that membrane Desal-5 DK was the most selective membrane to separate xylose form glucose. Overall, it can be concluded that the spiral wound nanofiltration membrane offers cost-effective and easy-maintenance, which has a potential in xylose-glucose separation.


2003 ◽  
Vol 47 (12) ◽  
pp. 247-254
Author(s):  
K. Banerjee ◽  
C.D. Blumenschein

The industrial wastewater treatment plant discussed in this paper generates sludge containing heavy metals, including lead. Occasionally, the concentration of lead in the Toxic Characteristics Leaching Procedure (TCLP) extract from the sludge exceeded the U.S. Environmental Protection Agency (EPA) regulatory limit of 5 mg/l and resulted in the solid waste exhibiting the characteristics of toxicity. The technical and economic feasibility of a process for conditioning the lead-containing sludge was investigated. The results revealed that the lead-laden sludge could be made non-hazardous by chemical conditioning. The lead reduction efficiency of triple super phosphate (TSP) is higher than that of either calcium carbonate or magnesium hydroxide. The laboratory and pilot-scale tests indicated that the conditioning system consistently reduced the lead in the TCLP extract below the regulatory limit of 5 mg/l. The economic feasibility evaluation demonstrated that more than US$450,000 could be saved annually by conditioning the sludge with TSP and disposing it as a non-hazardous material in a landfill. The results obtained from the laboratory as well as from the pilot-scale operation are described and discussed in this paper.


2002 ◽  
Vol 46 (9) ◽  
pp. 279-286 ◽  
Author(s):  
A. Idris ◽  
O.B. Yen ◽  
M.H.A. Hamid ◽  
A.M. Baki

A sludge lagoon has been adopted as a simple and cost effective method for dewatering of sludge. The processes occurring in a sludge lagoon include thickening, dewatering, storage and stabilization; all happening simultaneously. The objective of this study is to determine the dewatering and drying rates at pilot-scale which occur in a lagoon having different design configurations. Two types of sludge lagoons with different initial sludge depth (0.75 m and 0.375 m) were investigated to measure the drying behavior and drying efficiency. The first design is a sludge lagoon with a clay bottom where the dewatering mechanisms are decanting supernatant and evaporation. The second design is a sludge lagoon installed with a sand and underdrains system, where the dewatering mechanisms are filtration or draining and evaporation. Sludge drying kinetic models with high fitness were plotted to describe the sludge drying behavior. Drying of sludge in a sludge lagoon with a clay bottom can best be described by an exponential function. Whereas, drying of sludge in a sludge lagoon with sand and underdrains system followed a logarithmic function. A lagoon designed with sand and underdrains system and having shallower sludge depth was the most efficient. The reduction in volatile solids was lower than 4% during the study period. The drying process proceeded with an increase in dryness and decline in pH value.


1997 ◽  
Vol 17 (03) ◽  
pp. 161-162
Author(s):  
Thomas Hyers

SummaryProblems with unfractionated heparin as an antithrombotic have led to the development of new therapeutic agents. Of these, low molecular weight heparin shows great promise and has led to out-patient therapy of DVT/PE in selected patients. Oral anticoagulants remain the choice for long-term therapy. More cost-effective ways to give oral anticoagulants are needed.


The choice of cost-effective method of anticorrosive protection of steel structures is an urgent and time consuming task, considering the significant number of protection ways, differing from each other in the complex of technological, physical, chemical and economic characteristics. To reduce the complexity of solving this problem, the author proposes a computational tool that can be considered as a subsystem of computer-aided design and used at the stage of variant and detailed design of steel structures. As a criterion of the effectiveness of the anti-corrosion protection method, the cost of the protective coating during the service life is accepted. The analysis of existing methods of steel protection against corrosion is performed, the possibility of their use for the protection of the most common steel structures is established, as well as the estimated period of effective operation of the coating. The developed computational tool makes it possible to choose the best method of protection of steel structures against corrosion, taking into account the operating conditions of the protected structure and the possibility of using a protective coating.


1996 ◽  
Vol 33 (8) ◽  
pp. 23-29 ◽  
Author(s):  
I. Dor ◽  
N. Ben-Yosef

About one hundred and fifty wastewater reservoirs store effluents for irrigation in Israel. Effluent qualities differ according to the inflowing wastewater quality, the degree of pretreatment and the operational parameters. Certain aspects of water quality like concentration of organic matter, suspended solids and chlorophyll are significantly correlated with the water column transparency and colour. Accordingly optical images of the reservoirs obtained from the SPOT satellite demonstrate pronounced differences correlated with the water quality. The analysis of satellite multispectral images is based on a theoretical model. The model calculates, using the radiation transfer equation, the volume reflectance of the water body. Satellite images of 99 reservoirs were analyzed in the chromacity space in order to classify them according to water quality. Principal Component Analysis backed by the theoretical model increases the method sensitivity. Further elaboration of this approach will lead to the establishment of a time and cost effective method for the routine monitoring of these hypertrophic wastewater reservoirs.


2013 ◽  
Vol 10 (3) ◽  
pp. 159-163 ◽  
Author(s):  
Jun Peng ◽  
Yue Feng ◽  
Zhu Tao ◽  
Yingjie Chen ◽  
Xiangnan Hu

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