Development of a Small-Scale Catalytic Gas Turbine Combustor

1982 ◽  
Vol 104 (1) ◽  
pp. 52-57 ◽  
Author(s):  
S. J. Anderson ◽  
M. A. Friedman ◽  
W. V. Krill ◽  
J. P. Kesselring

Catalytically supported thermal combustion can provide low NOx emissions with gaseous and distillate fuels while maintaining high combustion efficiency. For stationary gas turbines, catalytic combustion may be the only emerging technology that can cost effectively meet recent federal regulations for NOx emissions. Under EPA sponsorship, a small-scale, catalytic gas turbine combustor was developed to evaluate transient and steady state combustor performance. The combustor consisted of a multiple air-atomizing fuel injector, an opposed jet igniter, and a graded-cell monolithic reactor. System startup, including opposed jet ignition and catalyst stabilization, was achieved in 250 seconds. This time interval is comparable to conventional gas turbines. Steady state operation was performed at 0.505 MPa (5 atmospheres) pressure and 15.3 m/s (50 ft/s) reference velocities. Thermal NOx emissions were measured below 10 ppmv, while fuel NOx conversion ranged from 75 to 95 percent. At catalyst bed temperatures greater than 1422K (2100°F), total CO and UHC emissions were less than 50 ppmv indicating combustion efficiency greater than 99.9 percent. Compared with conventional gas turbine combustors, the catalytic reactor operates only within a relatively narrow range of fuel/air ratios. As a result, modified combustor air distribution or fuel staging will be required to achieve the wide turndown required in large stationary systems.

Author(s):  
William D. York ◽  
Willy S. Ziminsky ◽  
Ertan Yilmaz

Interest in hydrogen as a primary fuel stream in heavy-duty gas turbine engines has increased as precombustion carbon capture and sequestration (CCS) has become a viable option for integrated gasification combined cycle (IGCC) power plants. The U.S. Department of Energy has funded the Advanced IGCC/Hydrogen Gas Turbine Program since 2005 with an aggressive plant-level NOx target of 2 ppm at 15% O2 for an advanced gas turbine cycle. Approaching this NOx level with highly reactive hydrogen fuel at the conditions required is a formidable challenge that requires novel combustion technology. This study begins by measuring entitlement NOx emissions from perfectly premixed combustion of the high-hydrogen fuels of interest. A new premixing fuel injector for high-hydrogen fuels was designed to balance reliable flashback-free operation, reasonable pressure drop, and low emissions. The concept relies on small-scale jet-in-crossflow mixing that is a departure from traditional swirl-based premixing concepts. Single nozzle rig experiments were conducted at pressures of 10 atm and 17 atm, with air preheat temperatures of about 650 K. With nitrogen-diluted hydrogen fuel, characteristic of carbon-free syngas, stable operation without flashback was conducted up to flame temperatures of approximately 1850 K. In addition to the effects of pressure, the impacts of nitrogen dilution levels and amounts of minor constituents in the fuel—carbon monoxide, carbon dioxide, and methane—on flame holding in the premixer are presented. The new fuel injector concept has been incorporated into a full-scale, multinozzle combustor can with an energy conversion rate of more than 10 MW at F-class conditions. The full-can testing was conducted at full gas turbine conditions and various fuel compositions of hydrogen, natural gas, and nitrogen. This combustion system has accumulated over 100 h of fired testing at full load with hydrogen comprising over 90% of the reactants by volume. NOx emissions (ppm) have been measured in the single digits with hydrogen-nitrogen fuel at target gas turbine pressure and temperatures. Results of the testing show that small-scale fuel-air mixing can deliver a reliable, low-NOx solution to hydrogen combustion in advanced gas turbines.


Author(s):  
William D. York ◽  
Willy S. Ziminsky ◽  
Ertan Yilmaz

Interest in hydrogen as a primary fuel stream in heavy-duty gas turbine engines has increased as pre-combustion carbon capture and sequestration (CCS) has become a viable option for integrated gasification combined cycle (IGCC) power plants. The US Department of Energy has funded the Advanced IGCC/Hydrogen Gas Turbine Program since 2005 with an aggressive plant-level NOx target of 2 ppm @ 15% O2 for an advanced gas turbine cycle. Approaching this NOx level with highly-reactive hydrogen fuel at the conditions required is a formidable challenge that requires novel combustion technology. This study begins by measuring entitlement NOx emissions from perfectly-premixed combustion of the high-hydrogen fuels of interest. A new premixing fuel injector for high-hydrogen fuels was designed to balance reliable, flashback-free operation, reasonable pressure drop, and low emissions. The concept relies on distributed, small-scale jet-in-crossflow mixing that is a departure from traditional swirl-based premixing concepts. Single nozzle rig experiments were conducted at pressures of 10 atm and 17 atm, with air preheat temperatures of about 650K. With nitrogen-diluted hydrogen fuel, characteristic of carbon-free syngas, stable operation without flashback was conducted up to flame temperatures of approximately 1850K. In addition to the effects of operating pressure, the impact of minor constituents in the fuel — carbon monoxide, carbon dioxide, and methane — on flame holding in the premixer is presented. The new fuel injector concept has been incorporated into a full-scale, multi-nozzle combustor can with an energy conversion rate of more than 10 MW at F-class conditions. The full-can testing was conducted at full gas turbine conditions and various fuel compositions of hydrogen, natural gas, and nitrogen. This combustion system has accumulated over 100 hours of fired testing at full-load with hydrogen comprising over 90 percent of the reactants by volume. NOx emissions (ppm) have been measured in the single digits with hydrogen-nitrogen fuel at target gas turbine pressure and temperatures. Results of the testing show that small-scale fuel-air mixing can deliver a reliable, low-NOx solution to hydrogen combustion in advanced gas turbines.


Author(s):  
Masato Hiramatsu ◽  
Yoshifumi Nakashima ◽  
Sadamasa Adachi ◽  
Yudai Yamasaki ◽  
Shigehiko Kaneko

One approach to achieving 99% combustion efficiency (C.E.) and 10 ppmV or lower NOx (at 15%O2) in a micro gas turbine (MGT) combustor fueled by biomass gas at a variety of operating conditions is with the use of flameless combustion (FLC). This paper compares experimentally obtained results and CHEMKIN analysis conducted for the developed combustor. As a result, increase the number of stage of FLC combustion enlarges the MGT operation range with low-NOx emissions and high-C.E. The composition of fuel has a small effect on the characteristics of ignition in FLC. In addition, NOx in the engine exhaust is reduced by higher levels of CO2 in the fuel.


Author(s):  
Oanh Nguyen ◽  
Scott Samuelsen

In view of increasingly stringent NOx emissions regulations on stationary gas turbines, lean combustion offers an attractive option to reduce reaction temperatures and thereby decrease NOx production. Under lean operation, however, the reaction is vulnerable to blowout. It is herein postulated that pilot hydrogen dopant injection, discretely located, can enhance the lean blowout performance without sacrificing overall performance. The present study addresses this hypothesis in a research combustor assembly, operated at atmospheric pressure, and fired on natural gas using rapid mixing injection, typical of commercial units. Five hydrogen injector scenarios are investigated. The results show that (1) pilot hydrogen dopant injection, discretely located, leads to improved lean blowout performance and (2) the location of discrete injection has a significant impact on the effectiveness of the doping strategy.


Author(s):  
K. O. Smith ◽  
A. Fahme

Three subscale, cylindrical combustors were rig tested on natural gas at typical industrial gas turbine operating conditions. The intent of the testing was to determine the effect of combustor liner cooling on NOx and CO emissions. In order of decreasing liner cooling, a metal louvre-cooled combustor, a metal effusion-cooled combustor, and a backside-cooled ceramic (CFCC) combustor were evaluated. The three combustors were tested using the same lean-premixed fuel injector. Testing showed that reduced liner cooling produced lower CO emissions as reaction quenching near the liner wall was reduced. A reduction in CO emissions allows a reoptimization of the combustor air flow distribution to yield lower NOx emissions.


Author(s):  
D. P. Teixeira ◽  
D. J. White ◽  
M. E. Ward

Results of a series of tests on a prevaporized, premixed combustor to evaluate its emissions control potential while operating on No. 2 distillate oil are presented. The concept utilized the heat capacity of the combustor inlet air to absorb the heat of vaporization of the fuel. Tests were conducted at combustor inlet temperatures and pressures characteristic of current generation electric utility gas turbines (345 C and 10 atm). NOx emissions in excess of proposed EPA gas turbine standards (75 ppm at 15 percent O) were observed at the 10 atm pressure condition and are believed to be the result of incomplete evaporation of the fuel Attempts to increase vaporization rates by increasing inlet air temperature were limited by autoignition of the mixture in the fuel preparation ports.


Author(s):  
A. Okuto ◽  
T. Kimura ◽  
I. Takehara ◽  
T. Nakashima ◽  
Y. Ichikawa ◽  
...  

Research and development project of ceramic gas turbines (CGT) was started in 1988 promoted by the Ministry of International Trade and Industry (MITI) in Japan. The target of the CGT project is development of a 300kW-class ceramic gas turbine with a 42 % thermal efficiency and a turbine inlet temperature (TIT) of 1350°C. Three types of CGT engines are developed in this project. One of the CGT engines, which is called CGT302, is a recuperated two-shaft gas turbine for co-generation use. In this paper, we describe the research and development of a combustor for the CGT302. The project requires a combustor to exhaust lower pollutant emissions than the Japanese regulation level. In order to reduce NOx emissions and achieve high combustion efficiency, lean premixed combustion technology is adopted. Combustion rig tests were carried out using this combustor. In these tests we measured the combustor performance such as pollutant emissions, combustion efficiency, combustor inlet/outlet temperature, combustor inlet pressure and pressure loss through combustor. Of course air flow rate and fuel flow rate are controlled and measured, respectively. The targets for the combustor such as NOx emissions and combustion efficiency were accomplished with sufficient margin in these combustion rig tests. In addition, we report the results of the tests which were carried out to examine effects of inlet air pressure on NOx emissions here.


Author(s):  
Mohamed A. Altaher ◽  
Hu Li ◽  
Gordon E. Andrews

Biodiesels have advantages of low carbon footprint, reduced toxic emissions, improved energy supply security and sustainability and therefore attracted attentions in both industrial and aero gas turbines sectors. Industrial gas turbine applications are more practical biodiesels due to low temperature waxing and flow problems at altitude for aero gas turbine applications. This paper investigated the use of biodiesels in a low NOx radial swirler, as used in some industrial low NOx gas turbines. A waste cooking oil derived methyl ester biodiesel (WME) was tested on a radial swirler industrial low NOx gas turbine combustor under atmospheric pressure, 600K air inlet temperature and reference Mach number of 0.017&0.023. The pure WME, its blends with kerosene (B20 and B50) and pure kerosene were tested for gaseous emissions and lean extinction as a function of equivalence ratio for both Mach numbers. Sauter Mean Diameter (SMD) of the fuel spray droplets was calculated. The results showed that the WME and its blends had lower CO, UHC emissions and higher NOx emissions than the kerosene. The weak extinction limits were determined for all fuels and B100 has the lowest value. The higher air velocity (at Mach = 0.023) resulted in smaller SMDs which improved the mixing and atomizing of fuels and thus led to reductions in NOx emissions.


Author(s):  
Kenneth O. Smith ◽  
F. R. Kurzynske ◽  
Leonard C. Angello

The design and testing of three natural gas fuel injector configurations for a low emissions gas turbine combustor are described. The injectors provided varying degrees of fuel/air premixing and permitted an assessment of the degree of premixing necessary to achieve NOx emissions below the program goal of 10 ppm. The work described represents a preliminary step in an effort to develop production-level gas turbine combustor hardware with ultra-low NOx capabilities.


2014 ◽  
Vol 118 (1204) ◽  
pp. 557-599 ◽  
Author(s):  
J. J. McGuirk

Abstract The components of an aeroengine gas-turbine combustor have to perform multiple tasks – control of external and internal air distribution, fuel injector feed, fuel/air atomisation, evaporation, and mixing, flame stabilisation, wall cooling, etc. The ‘rich-burn’ concept has achieved great success in optimising combustion efficiency, combustor life, and operational stability over the whole engine cycle. This paper first illustrates the crucial role of aerodynamic processes in achieving these performance goals. Next, the extra aerodynamic challenges of the ‘lean-burn’ injectors required to meet the ever more stringent NO x emissions regulations are introduced, demonstrating that a new multi-disciplinary and ‘whole system’ approach is required. For example, high swirl causes complex unsteady injector aerodynamics; the threat of thermo-acoustic instabilities means both aerodynamic and aeroacoustic characteristics of injectors and other air admission features must be considered; and high injector mass flow means potentially strong compressor/combustor and combustor/turbine coupling. The paper illustrates how research at Loughborough University, based on complementary use of advanced experimental and computational methods, and applied to both isolated sub-components and fully annular combustion systems, has improved understanding and identified novel ideas for combustion system design.


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