Numerical Study on NOx Reduction in Pulse Detonation Combustion by Using Steam Injection Decoupled From Detonation Development

Author(s):  
Niclas Hanraths ◽  
Fabian Tolkmitt ◽  
Phillip Berndt ◽  
Neda Djordjevic

Recently, the focus has been laid on the characteristics of pollutant emissions from pulse detonation combustion (PDC). Initial studies indicate possibly high nitrogen oxides (NOx) emissions, so the assessment of potential primary reduction methods is advisable. The present work considers the following reduction methods: lean combustion, nitrogen and steam dilution, as well as flue gas recirculation. Since such changes in the combustion mixture reduce its reactivity and thus detonability, they can impair a reliable operation in technical systems. In order to explore the potential and limitations of each of these reduction methods, they are compared for mixtures featuring an identical characteristic detonation cell size at given initial conditions. Furthermore, building upon the use of steam dilution, a modified method to add steam to the combustible mixture is investigated. In order to avoid the strong reduction of mixture detonability by steam addition and ensure a robust detonation formation, steam is injected into the already developed detonation front. It was found that, for sufficiently even steam distribution, NOx reduction comparable to a premixed dilution could be achieved. This approach enables the realization of NOx reduction in PDC also for such conditions, for which premix dilution is not feasible. Therefore, combining the premix dilution with postshock injection offers a promising strategy to substantially reduce NOx emissions from PDC, while at the same time ensuring its reliable operation.

Author(s):  
Niclas Hanraths ◽  
Fabian Tolkmitt ◽  
Phillip Berndt ◽  
Neda Djordjevic

Recently, the focus has been laid on the characteristics of pollutant emissions from pulse detonation combustion. Initial studies indicate possibly high nitrogen oxides (NOx) emissions, so the assessment of potential primary reduction methods is advisable. The present work considers the following reduction methods: lean combustion, nitrogen and steam dilution as well as flue gas recirculation. Since such changes in the combustion mixture reduce its reactivity and thus detonability, they can impair a reliable operation in technical systems. In order to explore the potential and limitations of each of these reduction methods, they are compared for mixtures featuring an identical characteristic detonation cell size at given initial conditions. Furthermore, building upon the use of steam dilution, a modified method to add steam to the combustible mixture is investigated. In order to avoid the strong reduction of mixture detonability by steam addition and ensure a robust detonation formation, steam is injected into the already developed detonation front. It was found that, for sufficiently even steam distribution, NOx reduction comparable to a premixed dilution could be achieved. This approach enables the realization of NOx reduction in pulse detonation combustion also for such conditions, for which premix dilution is not feasible. Therefore, combining the premix dilution with post-shock injection offers a promising strategy to substantially reduce NOx emissions from pulse detonation combustion, while at the same time ensuring its reliable operation.


Author(s):  
Neda Djordjevic ◽  
Niclas Hanraths ◽  
Joshua Gray ◽  
Phillip Berndt ◽  
Jonas Moeck

A change in the combustion concept of gas turbines from conventional isobaric to constant volume combustion, such as in pulse detonation combustion (PDC), promises a significant increase in gas turbine efficiency. Current research focuses on the realization of reliable PDC operation and its challenging integration into a gas turbine. The topic of pollutant emissions from such systems has so far received very little attention. Few rare studies indicate that the extreme combustion conditions in PDC systems can lead to high emissions of nitrogen oxides (NOx). Therefore, it is essential already at this stage of development to begin working on primary measures for NOx emissions reduction if commercialization is to be feasible. The present study evaluates the potential of different primary methods for reducing NOx emissions produced during PDC of hydrogen. The considered primary methods involve utilization of lean combustion mixtures or its dilution by steam injection or exhaust gas recirculation. The influence of such measures on the detonability of the combustion mixture has been evaluated based on detonation cell sizes modeled with detailed chemistry. For the mixtures and operating conditions featuring promising detonability, NOx formation in the detonation wave has been simulated by solving the one-dimensional (1D) reacting Euler equations. The study enables an insight into the potential and limitations of considered measures for NOx emissions reduction and lays the groundwork for optimized operation of PDC systems.


Author(s):  
Neda Djordjevic ◽  
Niclas Hanraths ◽  
Joshua Gray ◽  
Phillip Berndt ◽  
Jonas Moeck

A change in the combustion concept of gas turbines from conventional isobaric to constant volume combustion (CVC), such as in pulse detonation combustion (PDC), promises a significant increase in gas turbine efficiency. Current research focuses on the realization of reliable PDC operation and its challenging integration into a gas turbine. The topic of pollutant emissions from such systems has so far received very little attention. Few rare studies indicate that the extreme combustion conditions in PDC systems can lead to high emissions of nitrogen oxides (NOx). Therefore, it is essential already at this stage of development to begin working on primary measures for NOx emissions reduction, if commercialization is to be feasible. The present study evaluates the potential of different primary methods for reducing NOx emissions produced during pulsed detonation combustion of hydrogen. The considered primary methods involve utilization of lean combustion mixtures or its dilution by steam injection or exhaust gas recirculation. The influence of such measures on the detonability of the combustion mixture has been evaluated based on detonation cell sizes modelled with detailed chemistry. For the mixtures and operating conditions featuring promising detonability, NOx formation in the detonation wave has been simulated by solving the one-dimensional reacting Euler equations. The study enables an insight into the potential and limitations of considered measures for NOx emissions reduction and lays the groundwork for optimized operation of pulse detonation combustion systems.


2012 ◽  
Vol 602-604 ◽  
pp. 1317-1324
Author(s):  
Yao Xun Feng ◽  
Xiao Feng Zheng ◽  
Ming Sheng Jia

In this study, a methane/oxygen-enriched air counterflow diffusion flame was analyzed numerically using detailed chemical kinetics, on the condition that the oxygen mass fraction in the oxidizer stream varied from 21% to 99%. The obtained results show that as the oxygen concentration in air increases, the maximum temperature increases; the region of combustion reaction is gradually divided into two parts, and the total NO production rate and especially the thermal NO production rate increase greatly. With consideration of the possibility of gas recirculation to minimize NOX in the industrial combustor, the usefulness of NOX reduction in combustion was analyzed numerically when the methane stream was diluted with the inert gases N2 or CO2. The obtained results show that the flame structure and dominant mechanism of NO formation change greatly with the concentration of diluents in fuel; the emission index of NO decreases gradually when the concentration of diluent CO2 increases.


2019 ◽  
Author(s):  
Niclas Hanraths ◽  
Myles D. Bohon ◽  
Christian O. Paschereit ◽  
Neda Djordjevic

Author(s):  
Titas Sereika ◽  
Kęstutis Buinevičius ◽  
Adolfas Jančauskas

The main idea of research is to figure out the emissions of nitrogen oxides reduction using various type of reduction methods. In experiments were used NOx reduction methods: high CO emissions generation, flue gas recirculation, water and water vapor supply, selective non-catalytic reduction (SNCR), and SNCR with flammable additive. This study presents emission and combustion results obtained burning furniture production waste which generates higher rate of NOx emissions. The result of research shows, that CO emission has the biggest impact factor -on reducing NOx emission. Burning fuel in combustion zone with first and secondary air ratio (40/60) and using methods for higher generation CO emissions reached 3.000 mg/m3 which reduces NOx emissions up to 83%. Using selective non-catalytic reduction with traditional and flammable additives reduction of NOx emissions reached up to 55%.


Author(s):  
Nevin Selc¸uk ◽  
Aykan Batu ◽  
Olcay Oymak

NOx emissions from fluidized bed combustion of various coals have extensively been investigated and well documented. However, NOx emissions from combustion of Turkish lignites with high ash, volatile matter and sulfur contents have not drawn much attention to date. Recent trend in utilization of indigenous lignites in fluidized bed boilers necessitated investigation of pollutant emissions and adaptation of fluidized bed combustion technology to these lignites. In this study, experimental results of various runs pertaining to the formation and emission of NOx from METU 0.3 MWt Atmospheric Bubbling Fluidized Bed Combustor (ABFBC) test rig burning typical indigenous lignites; Aydin without limestone addition and Beypazari with and without limestone addition are presented. NOx profiles along the combustor show that concentrations are higher in bed compared to those in freeboard and that conditions leading to higher unburned volatiles in freeboard enhances NOx reduction in that region. Limestone addition results in higher concentrations of NOx in bed but lower concentrations in freeboard, albeit insignificantly.


2021 ◽  
pp. 146808742199335
Author(s):  
Raouf Mobasheri ◽  
Abdel Aitouche ◽  
Zhijun Peng ◽  
Xiang Li

The European Union (EU) has recently adopted new directives to reduce the level of pollutant emissions from non-road mobile machinery engines. The main scope of project RIVER for which this study is relating is to develop possible solutions to achieve nitrogen-free combustion and zero-carbon emissions in diesel engines. RIVER aims to apply oxy-fuel combustion with Carbon Capture and Storage (CCS) technology to eliminate NOx emissions and to capture and store carbon emissions. As part of this project, a computational fluid dynamic (CFD) analysis has been performed to investigate the effects of oxy-fuel combustion on combustion characteristics and engine operating conditions in a diesel engine under Homogenous Charge Compression Ignition (HCCI) mode. A reduced chemical n-heptane-n-butanol-PAH mechanism which consists of 76 species and 349 reactions has been applied for oxy-fuel HCCI combustion modeling. Different diluent strategies based on the volume fraction of oxygen and a diluent gas has been considered over a wide range of air-fuel equivalence ratios. Variation in the diluent ratio has been achieved by adding different percentages of carbon dioxide for a range from 77 to 83 vol.% in the intake charge. Results show that indicated thermal efficiency (ITE) has reduced from 32.7% to 20.9% as the CO2 concentration has increased from 77% to 83% at low engine loads while it doesn’t bring any remarkable change at high engine loads. It has also found that this technology has brought CO and PM emissions to a very ultra-low level (near zero) while NOx emissions have been completely eliminated.


Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1036 ◽  
Author(s):  
Xinying Xu ◽  
Qi Chen ◽  
Mifeng Ren ◽  
Lan Cheng ◽  
Jun Xie

Increasing the combustion efficiency of power plant boilers and reducing pollutant emissions are important for energy conservation and environmental protection. The power plant boiler combustion process is a complex multi-input/multi-output system, with a high degree of nonlinearity and strong coupling characteristics. It is necessary to optimize the boiler combustion model by means of artificial intelligence methods. However, the traditional intelligent algorithms cannot deal effectively with the massive and high dimensional power station data. In this paper, a distributed combustion optimization method for boilers is proposed. The MapReduce programming framework is used to parallelize the proposed algorithm model and improve its ability to deal with big data. An improved distributed extreme learning machine is used to establish the combustion system model aiming at boiler combustion efficiency and NOx emission. The distributed particle swarm optimization algorithm based on MapReduce is used to optimize the input parameters of boiler combustion model, and weighted coefficient method is used to solve the multi-objective optimization problem (boiler combustion efficiency and NOx emissions). According to the experimental analysis, the results show that the method can optimize the boiler combustion efficiency and NOx emissions by combining different weight coefficients as needed.


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