Performance and Emissions of Drop-In Aviation Biofuels in a Lab-Scale Gas Turbine Combustor

2020 ◽  
Vol 143 (4) ◽  
Author(s):  
Joseph Feser ◽  
Ashwani Gupta

Abstract There is a growing need for drop-in biofuels for gas turbines for enhanced energy security and sustainability. Several fuels are currently being developed and tested to reduce dependency on fossil fuels while maintaining performance, particularly in the aviation industry. The transition from traditional fossil fuels to sustainable biofuels is much desired for reducing the rapidly rising CO2 levels in the environment. This requires biofuels to be drop-in ready, where there are no adverse effects on performance and emissions upon replacement. In this study, the performance and emissions of four different aviation drop-in biofuels were evaluated. They include UOP HEFA-SPK, Gevo ATJ, Amyris Farnesane, and SB-JP-8. These aviation biofuels are currently being produced and tested to be ready for full or partial drop-in fuels as the replacement of traditional jet fuels. The characteristic performance of each fuel from the prevaporized liquid fuels was performed in a high-intensity (20 MW/m3-atm) reverse flow combustor. The NO emissions showed near unity ppm levels for each of the fuels examined with a minimum at an equivalence ratio of ∼0.6, while CO levels were in the range of 1000–1300 ppm depending on the fuel at an equivalence ratio between 0.75 and 0.8. For an equivalence ratio range between 0.4 and 0.6, NO and CO emissions remained very low (between 1–2 ppm NO and 2400–2900 ppm CO) depending on the fuel. The examined biofuels did not show any instability over a wide range of equivalence ratios from lean to near stoichiometric condition. These results provide promising results on the behavior of these drop-in aviation biofuels for use in high-intensity gas turbine combustors providing stability and cleaner performance without any modification to the combustor design.

Author(s):  
Joseph S. Feser ◽  
Ashwani K. Gupta

Abstract There is a growing need for drop-in biofuels for gas turbines for enhanced energy security and sustainability. Several fuels are currently being developed and tested to reduce dependency on fossil fuels while maintaining performance, particularly in the aviation industry. The transition from traditional fossil fuels to sustainable biofuels is much desired for reducing the rapidly rising CO2 levels in the environment. This requires biofuels to be drop-in ready, where there are no adverse effects on performance and emissions upon replacement. In this study the performance and emissions of four different aviation drop-in biofuels was evaluated. They include: UOP HEFA-SPK, Gevo ATJ, Amyris Farnesane, and SB-JP-8. These aviation biofuels are currently being produced and tested to be ready for full or partial drop-in fuels as the replacement of traditional jet fuels. The characteristic performance of each fuel from the prevaporized liquid fuels was performed in a high intensity (20 MW/m3-atm) reverse flow combustor. The NO emissions showed near unity ppm levels for each of the fuels examined with a minimum at an equivalence ratio of ∼0.6, while CO levels were in the range of 1000–1300 ppm depending on the fuel at an equivalence ratio between 0.75–0.8. For an equivalence ratio range between 0.4 and 0.6, NO and CO emissions remained very low (between 1–2ppm NO and 2400–2900ppm CO) depending on the fuel. The examined biofuels did not show any instability over a wide range of equivalence ratios from lean to near stoichiometric condition. These results provide promising results on the behavior of these drop-in aviation biofuels for use in high intensity gas turbine combustors providing stability and cleaner performance without any modification to the combustor design.


Author(s):  
Roda Bounaceur ◽  
Pierre-Alexandre Glaude ◽  
Baptiste Sirjean ◽  
René Fournet ◽  
Pierre Montagne ◽  
...  

Gas turbines burn a large variety of gaseous fuels under elevated pressure and temperature conditions. During transient operations, variable gas/air mixtures are involved in the gas piping system. In order to predict the risk of auto-ignition events and ensure a safe operation of gas turbines, it is of the essence to know the lowest temperature at which spontaneous ignition of fuels may happen. Experimental auto-ignition data of hydrocarbon–air mixtures at elevated pressures are scarce and often not applicable in specific industrial conditions. Auto-ignition temperature (AIT) data correspond to temperature ranges in which fuels display an incipient reactivity, with timescales amounting in seconds or even in minutes instead of milliseconds in flames. In these conditions, the critical reactions are most often different from the ones governing the reactivity in a flame or in high temperature ignition. Some of the critical paths for AIT are similar to those encountered in slow oxidation. Therefore, the main available kinetic models that have been developed for fast combustion are unfortunately unable to represent properly these low temperature processes. A numerical approach addressing the influence of process conditions on the minimum AIT of different fuel/air mixtures has been developed. Several chemical models available in the literature have been tested, in order to identify the most robust ones. Based on previous works of our group, a model has been developed, which offers a fair reconciliation between experimental and calculated AIT data through a wide range of fuel compositions. This model has been validated against experimental auto-ignition delay times corresponding to high temperature in order to ensure its relevance not only for AIT aspects but also for the reactivity of gaseous fuels over the wide range of gas turbine operation conditions. In addition, the AITs of methane, of pure light alkanes, and of various blends representative of several natural gas and process-derived fuels were extensively covered. In particular, among alternative gas turbine fuels, hydrogen-rich gases are called to play an increasing part in the future so that their ignition characteristics have been addressed with particular care. Natural gas enriched with hydrogen, and different syngas fuels have been studied. AIT values have been evaluated in function of the equivalence ratio and pressure. All the results obtained have been fitted by means of a practical mathematical expression. The overall study leads to a simple correlation of AIT versus equivalence ratio/pressure.


Author(s):  
Roda Bounaceur ◽  
Pierre-Alexandre Glaude ◽  
Baptiste Sirjean ◽  
René Fournet ◽  
Pierre Montagne ◽  
...  

Gas turbines burn a large variety of gaseous fuels under elevated pressure and temperature conditions. During transient operations like maintenance, start-ups or fuel transfers, variable gas/air mixtures are involved in the gas piping system. Therefore, in order to predict the risk of auto-ignition events and ensure a safe and optimal operation of gas turbines, it is of the essence to know the lowest temperature at which spontaneous ignition of fuels may happen. Experimental auto-ignition data of hydrocarbon-air mixtures at elevated pressures are scarce and often not applicable in specific industrial conditions. AIT data correspond to temperature ranges in which fuels display an incipient reactivity, with time scales amounting in seconds or even in minutes instead of milliseconds in flames. In these conditions, the critical reactions are most often different from the ones governing the reactivity in a flame or in high temperature ignition. Some of the critical paths for AIT, especially those involving peroxy radicals, are similar to those encountered in slow oxidation. Therefore, the main available kinetic models that have been developed for fast combustion, are unfortunately unable to represent properly these low temperature processes. In this context, a numerical approach addressing the influence of process conditions on the minimum auto-ignition temperature of different fuel/air mixtures has been developed. For that purpose, several chemical models available in the literature have been tested, in order to identify the most robust ones. Based on previous works of our group, a model covering a large temperature range has been developed, which offers a fair reconciliation between experimental and calculated AIT data through a wide range of fuel compositions. This model has been validated against experimental auto-ignition delay times (AID) corresponding to high temperature in order to ensure its relevance not only for AIT aspects but also for the reactivity of gaseous fuels over the wide range of gas turbine operation conditions. In addition, the AITs of methane, of pure light alkanes and of various blends representative of several natural gas and process-derived fuels were extensively covered. In particular, among alternative gas turbine fuels, hydrogen-rich gases are called to play an increasing part in the future so that their ignition characteristics have been addressed with particular care. Natural gas enriched with hydrogen, and different CO/H2 syngas fuels originating from a blast furnace (BFG) have namely been studied. Globally, the individual species covered are: H2, CO, CO2, N2, CH4, C2H6, C3H8, C4H10, and C5H12. AIT values have been evaluated in function of the equivalence ratio and pressure. All the results obtained have been fitted by means of a practical mathematical expression. The overall study leads to a simple correlation of AIT versus equivalence ratio/pressure that may be of fruitful use for the engineering community.


Author(s):  
P. A. Phillips ◽  
Peter Spear

After briefly summarizing worldwide automotive gas turbine activity, the paper analyses the power plant requirements of a wide range of vehicle applications in order to formulate the design criteria for acceptable vehicle gas turbines. Ample data are available on the thermodynamic merits of various gas turbine cycles; however, the low cost of its piston engine competitor tends to eliminate all but the simplest cycles from vehicle gas turbine considerations. In order to improve the part load fuel economy, some complexity is inevitable, but this is limited to the addition of a glass ceramic regenerator in the 150 b.h.p. engine which is described in some detail. The alternative further complications necessary to achieve satisfactory vehicle response at various power/weight ratios are examined. Further improvement in engine performance will come by increasing the maximum cycle temperature. This can be achieved at lower cost by the extension of the use of ceramics. The paper is intended to stimulate the design application of the gas turbine engine.


Author(s):  
Dominik Ebi ◽  
Peter Jansohn

Abstract Operating stationary gas turbines on hydrogen-rich fuels offers a pathway to significantly reduce greenhouse gas emissions in the power generation sector. A key challenge in the design of lean-premixed burners, which are flexible in terms of the amount of hydrogen in the fuel across a wide range and still adhere to the required emissions levels, is to prevent flame flashback. However, systematic investigations on flashback at gas turbine relevant conditions to support combustor development are sparse. The current work addresses the need for an improved understanding with an experimental study on boundary layer flashback in a generic swirl burner up to 7.5 bar and 300° C preheat temperature. Methane-hydrogen-air flames with 50 to 85% hydrogen by volume were investigated. High-speed imaging was applied to reveal the flame propagation pathway during flashback events. Flashback limits are reported in terms of the equivalence ratio for a given pressure, preheat temperature, bulk flow velocity and hydrogen content. The wall temperature of the center body along which the flame propagated during flashback events has been controlled by an oil heating/cooling system. This way, the effect any of the control parameters, e.g. pressure, had on the flashback limit was de-coupled from the otherwise inherently associated change in heat load on the wall and thus change in wall temperature. The results show that the preheat temperature has a weaker effect on the flashback propensity than expected. Increasing the pressure from atmospheric conditions to 2.5 bar strongly increases the flashback risk, but hardly affects the flashback limit beyond 2.5 bar.


Author(s):  
Wyatt Culler ◽  
Janith Samarasinghe ◽  
Bryan D. Quay ◽  
Domenic A. Santavicca ◽  
Jacqueline O’Connor

Combustion instability in gas turbines can be mitigated using active techniques or passive techniques, but passive techniques are almost exclusively used in industrial settings. While fuel staging, a common passive technique, is effective in reducing the amplitude of self-excited instabilities in gas turbine combustors at steady-state conditions, the effect of transients in fuel staging on self-excited instabilities is not well understood. This paper examines the effect of fuel staging transients on a laboratory-scale five-nozzle can combustor undergoing self-excited instabilities. The five nozzles are arranged in a four-around-one configuration and fuel staging is accomplished by increasing the center nozzle equivalence ratio. When the global equivalence ratio is φ = 0.70 and all nozzles are fueled equally, the combustor undergoes self-excited oscillations. These oscillations are suppressed when the center nozzle equivalence ratio is increased to φ = 0.80 or φ = 0.85. Two transient staging schedules are used, resulting in transitions from unstable to stable operation, and vice-versa. It is found that the characteristic instability decay times are dependent on the amount of fuel staging in the center nozzle. It is also found that the decay time constants differ from the growth time constants, indicating hysteresis in stability transition points. High speed CH* chemiluminescence images in combination with dynamic pressure measurements are used to determine the instantaneous phase difference between the heat release rate fluctuation and the combustor pressure fluctuation throughout the combustor. This analysis shows that the instability onset process is different from the instability decay process.


Author(s):  
G. E. Parker

Controls for small lightweight gas turbines present some unique design problems. The requirements for small size, light weight, ability to rotate at high speeds to save reduction gearing, and low production cost conflict with the requirements for reasonably accurate control of very small fuel flows and the scheduling of a wide range of hydrocarbon fuels over a wide range of ambient temperatures. This paper discusses in some detail the design of such a control and the satisfactory results obtained.


Author(s):  
R. Friso ◽  
N. Casari ◽  
M. Pinelli ◽  
A. Suman ◽  
F. Montomoli

Abstract Gas turbines (GT) are often forced to operate in harsh environmental conditions. Therefore, the presence of particles in their flow-path is expected. With this regard, deposition is a problem that severely affects gas turbine operation. Components’ lifetime and performance can dramatically vary as a consequence of this phenomenon. Unfortunately, the operating conditions of the machine can vary in a wide range, and they cannot be treated as deterministic. Their stochastic variations greatly affect the forecasting of life and performance of the components. In this work, the main parameters considered affected by the uncertainty are the circumferential hot core location and the turbulence level at the inlet of the domain. A stochastic analysis is used to predict the degradation of a high-pressure-turbine (HPT) nozzle due to particulate ingestion. The GT’s component analyzed as a reference is the HPT nozzle of the Energy-Efficient Engine (E3). The uncertainty quantification technique used is the probabilistic collocation method (PCM). This work shows the impact of the operating conditions uncertainties on the performance and lifetime reduction due to deposition. Sobol indices are used to identify the most important parameter and its contribution to life. The present analysis enables to build confidence intervals on the deposit profile and on the residual creep-life of the vane.


Author(s):  
M. Huth ◽  
A. Heilos ◽  
G. Gaio ◽  
J. Karg

The Integrated Gasification Combined Cycle concept is an emerging technology that enables an efficient and clean use of coal as well as residuals in power generation. After several years of development and demonstration operation, now the technology has reached the status for commercial operation. SIEMENS is engaged in 3 IGCC plants in Europe which are currently in operation. Each of these plants has specific characteristics leading to a wide range of experiences in development and operation of IGCC gas turbines fired with low to medium LHV syngases. The worlds first IGCC plant of commercial size at Buggenum/Netherlands (Demkolec) has already demonstrated that IGCC is a very efficient power generation technology for a great variety of coals and with a great potential for future commercial market penetration. The end of the demonstration period of the Buggenum IGCC plant and the start of its commercial operation has been dated on January 1, 1998. After optimisations during the demonstration period the gas turbine is running with good performance and high availability and has exceeded 18000 hours of operation on coal gas. The air-side fully integrated Buggenum plant, equipped with a Siemens V94.2 gas turbine, has been the first field test for the Siemens syngas combustion concept, which enables operation with very low NOx emission levels between 120–600 g/MWh NOx corresponding to 6–30 ppm(v) (15%O2) and less than 5 ppm(v) CO at baseload. During early commissioning the syngas nozzle has been recognised as the most important part with strong impact on combustion behaviour. Consequently the burner design has been adjusted to enable quick and easy changes of the important syngas nozzle. This design feature enables fast and efficient optimisations of the combustion performance and the possibility for easy adjustments to different syngases with a large variation in composition and LHV. During several test runs the gas turbine proved the required degree of flexibility and the capability to handle transient operation conditions during emergency cases. The fully air-side integrated IGCC plant at Puertollano/Spain (Elcogas), using the advanced Siemens V94.3 gas turbine (enhanced efficiency), is now running successfully on coal gas. The coal gas composition at this plant is similar to the Buggenum example. The emission performance is comparable to Buggenum with its very low emission levels. Currently the gas turbine is running for the requirements of final optimization runs of the gasifier unit. The third IGCC plant (ISAB) equipped with Siemens gas turbine technology is located at Priolo near Siracusa at Sicilly/Italy. Two Siemens V94.2K (modified compressor) gas turbines are part of this “air side non-integrated” IGCC plant. The feedstock of the gasification process is a refinery residue (asphalt). The LHV is almost twice compared to the Buggenum or Puertollano case. For operation with this gas, the coal gas burner design was adjusted and extensively tested. IGCC operation without air extraction has been made possible by modifying the compressor, giving enhanced surge margins. Commissioning on syngas for the first of the two gas turbines started in mid of August 1999 and was almost finished at the end of August 1999. The second machine followed at the end of October 1999. Since this both machines are released for operation on syngas up to baseload.


Author(s):  
Marek Dzida ◽  
Krzysztof Kosowski

In bibliography we can find many methods of determining pressure drop in the combustion chambers of gas turbines, but there is only very few data of experimental results. This article presents the experimental investigations of pressure drop in the combustion chamber over a wide range of part-load performances (from minimal power up to take-off power). Our research was carried out on an aircraft gas turbine of small output. The experimental results have proved that relative pressure drop changes with respect to fuel flow over the whole range of operating conditions. The results were then compared with theoretical methods.


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