Ignition Studies of C1-C7 Natural Gas Blends At Gas-Turbine Relevant Conditions

2021 ◽  
Author(s):  
Amrit Sahu ◽  
A.A.E.S Mohamed ◽  
Snehashish Panigrahy ◽  
Gilles Bourque ◽  
Henry Curran
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Gas Mixtures ◽  
Rapid Compression Machine ◽  
Temperature Range ◽  
Auto Ignition ◽  
Wide Range ◽  
Model Predictions ◽  
Detailed Kinetic Model ◽  
Sensitization Effect

Abstract New ignition delay time measurements (IDT) of natural gas mixtures enriched with small amounts of n-hexane and n-heptane were performed in a rapid compression machine to interpret the sensitization effect of heavier hydrocarbons on auto-ignition at gas-turbine relevant conditions. The experimental data of natural gas mixtures containing alkanes from methane to n-heptane were carried out over a wide range of temperatures (840-1050 K), pressures (20-30 bar), and equivalence ratios (f = 0.5 and 1.5). The experiments were complemented with numerical simulations using a detailed kinetic model developed to investigate the effect of n-hexane and n-heptane additions. Model predictions show that the addition of even small amounts (1-2%) of n-hexane and n-heptane can lead to an increase in reactivity by ~40-60 ms at a temperature of 700 K. The IDTs of these mixtures decrease rapidly with an increase in the concentration of up to 7.5% but becomes almost independent of the C6/C7 concentration >10%. This sensitization effect of C6 and C7 is also found to be more pronounced in the temperature range 700-900 K compared to that at higher temperatures (>900 K). The reason is attributed to the dependence of IDT primarily on H2O2(+M)??H+?H (+M) at higher temperatures while the fuel-dependent reactions such as H-atom abstraction, RO2 dissociation, or Q OOH+O2 reactions are less important compared to the temperature range 700-900 K, where they are very important.

Ignition Studies of C1–C7 Natural Gas Blends at Gas-Turbine Relevant Conditions

2020 ◽  
Author(s):  
Amrit Bikram Sahu ◽  
A. Abd El-Sabor Mohamed ◽  
Snehasish Panigrahy ◽  
Gilles Bourque ◽  
Henry Curran
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Ignition Delay ◽  
Delay Time ◽  
Ignition Delay Time ◽  
Gas Mixtures ◽  
Auto Ignition ◽  
Wide Range ◽  
Detailed Kinetic Model ◽  
Sensitization Effect

Abstract New ignition delay time measurements of natural gas mixtures enriched with small amounts of n-hexane and n-heptane were performed in a rapid compression machine to interpret the sensitization effect of heavier hydrocarbons on auto-ignition at gas-turbine relevant conditions. The experimental data of natural gas mixtures containing alkanes from methane to n-heptane were carried out over a wide range of temperatures (840–1050 K), pressures (20–30 bar), and equivalence ratios (φ = 0.5 and 1.5). The experiments were complimented with numerical simulations using a detailed kinetic model developed to investigate the effect of n-hexane and n-heptane additions. Model predictions show that the addition of even small amounts (1–2%) of n-hexane and n-heptane can lead to increase in reactivity by ∼40–60 ms at compressed temperature (TC) = 700 K. The ignition delay time (IDT) of these mixtures decrease rapidly with an increase in concentration of up to 7.5% but becomes almost independent of the C6/C7 concentration beyond 10%. This sensitization effect of C6 and C7 is also found to be more pronounced in the temperature range 700–900 K compared to that at higher temperatures (> 900 K). The reason is attributed to the dependence of IDT primarily on H2O2(+M) ↔ 2ȮH(+M) at higher temperatures while the fuel dependent reactions such as H-atom abstraction, RȮ2 dissociation or Q.OOH + O2 reactions are less important compared to 700–900 K, where they are very important.

Operability Limits of Tubular Injectors With Vortex Generators for a Hydrogen Fuelled Recuperated 100kW Class Gas Turbine

2016 ◽  
Author(s):  
Stefan Bauer ◽  
Balbina Hampel ◽  
Thomas Sattelmayer
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Operating Conditions ◽  
Bulk Flow ◽  
Vortex Generators ◽  
Test Rig ◽  
Temperature Range ◽  
Auto Ignition ◽  
Wide Range

Vortex generators are known to be effective in augmenting the mixing of fuel jets with air. The configuration investgated in this study is a tubular air passage with fuel injection from one single orifice placed in the side wall. In the range of typical gas turbine combustor inlet temperatures, the performance vortex generator premixers (VGPs) have already been investigated for natural gas as well as for blends of natural gas and hydrogen. However, for highly reactive fuels, the application of VGPs in recuperated gas turbines is particularly challenging because the high combustor inlet temperature leads to potential risk with regard to premature self-ignition and flame flashback. As the current knowledge does not cover the temperature range far above the self-ignition temperature, an experimental investigation of the operational limits of VGPs is currently being conducted at the Thermodynamics Institute of the Technical University of Munich, which is particularly focused on reactive fuels and the thermodynamic conditions present in recuperated gas turbines with pressure ratios of 4–5. For the study presented in the paper, an atmospheric combustion VGP test rig has been designed, which facilitates investigations in a wide range of operating conditions in order to comply with the situation in recuperated micro gas turbines, namely global equivalence ratios between 0.2 and 0.7, air preheating temperatures between 288K and 1100K, and air bulk flow rates between 6–16 g/s. Both the entire mixing zone in the VGP and the primary combustion zone of the test rig are optically accessible. High speed OH* chemiluminescence imaging is used for the detection of the flashback and blow-off limits of the investigated VGPs. Flashback and blow-off limits of hydrogen in a wide temperature range covering the auto-ignition regime are presented, addressing the influences of equivalence ratio, air preheating temperature and momentum ratio between air and hydrogen on the operational limits in terms of bulk flow velocity. It is shown that flashback and blow-off limits are increasingly influenced by auto-ignition in the ultra-high temperature regime.

scholarly journals Prediction of Auto-Ignition Temperatures and Delays for Gas Turbine Applications

2015 ◽  
Vol 138 (2) ◽  
Author(s):  
Roda Bounaceur ◽  
Pierre-Alexandre Glaude ◽  
Baptiste Sirjean ◽  
René Fournet ◽  
Pierre Montagne ◽  
...  
Keyword(s):  
High Temperature ◽  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Equivalence Ratio ◽  
Process Conditions ◽  
Piping System ◽  
Gaseous Fuels ◽  
Auto Ignition ◽  
Wide Range

Gas turbines burn a large variety of gaseous fuels under elevated pressure and temperature conditions. During transient operations, variable gas/air mixtures are involved in the gas piping system. In order to predict the risk of auto-ignition events and ensure a safe operation of gas turbines, it is of the essence to know the lowest temperature at which spontaneous ignition of fuels may happen. Experimental auto-ignition data of hydrocarbon–air mixtures at elevated pressures are scarce and often not applicable in specific industrial conditions. Auto-ignition temperature (AIT) data correspond to temperature ranges in which fuels display an incipient reactivity, with timescales amounting in seconds or even in minutes instead of milliseconds in flames. In these conditions, the critical reactions are most often different from the ones governing the reactivity in a flame or in high temperature ignition. Some of the critical paths for AIT are similar to those encountered in slow oxidation. Therefore, the main available kinetic models that have been developed for fast combustion are unfortunately unable to represent properly these low temperature processes. A numerical approach addressing the influence of process conditions on the minimum AIT of different fuel/air mixtures has been developed. Several chemical models available in the literature have been tested, in order to identify the most robust ones. Based on previous works of our group, a model has been developed, which offers a fair reconciliation between experimental and calculated AIT data through a wide range of fuel compositions. This model has been validated against experimental auto-ignition delay times corresponding to high temperature in order to ensure its relevance not only for AIT aspects but also for the reactivity of gaseous fuels over the wide range of gas turbine operation conditions. In addition, the AITs of methane, of pure light alkanes, and of various blends representative of several natural gas and process-derived fuels were extensively covered. In particular, among alternative gas turbine fuels, hydrogen-rich gases are called to play an increasing part in the future so that their ignition characteristics have been addressed with particular care. Natural gas enriched with hydrogen, and different syngas fuels have been studied. AIT values have been evaluated in function of the equivalence ratio and pressure. All the results obtained have been fitted by means of a practical mathematical expression. The overall study leads to a simple correlation of AIT versus equivalence ratio/pressure.

Operability Limits of Tubular Injectors With Vortex Generators for a Hydrogen-Fueled Recuperated 100 kW Class Gas Turbine

2017 ◽  
Vol 139 (8) ◽  
Author(s):  
Stefan Bauer ◽  
Balbina Hampel ◽  
Thomas Sattelmayer
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Operating Conditions ◽  
Bulk Flow ◽  
Vortex Generators ◽  
Inlet Temperature ◽  
Test Rig ◽  
Temperature Range ◽  
Wide Range

Abstract Vortex generators are known to be effective in augmenting the mixing of fuel jets with air. The configuration investigated in this study is a tubular air passage with fuel injection from one single orifice placed in the side wall. In the range of typical gas turbine combustor inlet temperatures, the performance vortex generator premixers (VGPs) have already been investigated for natural gas as well as for blends of natural gas and hydrogen. However, for highly reactive fuels, the application of VGPs in recuperated gas turbines is particularly challenging because the high combustor inlet temperature leads to potential risk with regard to premature self-ignition and flame flashback. As the current knowledge does not cover the temperature range far above the self-ignition temperature, an experimental investigation of the operational limits of VGPs is currently being conducted at the Thermodynamics Institute of the Technical University of Munich, Garching, Germany, which is particularly focused on reactive fuels and the thermodynamic conditions present in recuperated gas turbines with pressure ratios of 4–5. For the study presented in this paper, an atmospheric combustion VGP test rig has been designed, which facilitates investigations in a wide range of operating conditions in order to comply with the situation in recuperated microgas turbines (MGT), namely, global equivalence ratios between 0.2 and 0.7, air preheating temperatures between 288 K and 1100 K, and air bulk flow rates between 6 and 16 g/s. Both the entire mixing zone in the VGP and the primary combustion zone of the test rig are optically accessible. High-speed OH* chemiluminescence imaging is used for the detection of the flashback and blow-off limits of the investigated VGPs. Flashback and blow-off limits of hydrogen in a wide temperature range covering the autoignition regime are presented, addressing the influences of equivalence ratio, air preheating temperature, and momentum ratio between air and hydrogen on the operational limits in terms of bulk flow velocity. It is shown that flashback and blow-off limits are increasingly influenced by autoignition in the ultrahigh temperature regime.

scholarly journals Prediction of Auto-Ignition Temperatures and Delays for Gas Turbine Applications

2015 ◽  
Author(s):  
Roda Bounaceur ◽  
Pierre-Alexandre Glaude ◽  
Baptiste Sirjean ◽  
René Fournet ◽  
Pierre Montagne ◽  
...  
Keyword(s):  
High Temperature ◽  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Equivalence Ratio ◽  
Large Temperature ◽  
Individual Species ◽  
Gaseous Fuels ◽  
Auto Ignition ◽  
Wide Range

Gas turbines burn a large variety of gaseous fuels under elevated pressure and temperature conditions. During transient operations like maintenance, start-ups or fuel transfers, variable gas/air mixtures are involved in the gas piping system. Therefore, in order to predict the risk of auto-ignition events and ensure a safe and optimal operation of gas turbines, it is of the essence to know the lowest temperature at which spontaneous ignition of fuels may happen. Experimental auto-ignition data of hydrocarbon-air mixtures at elevated pressures are scarce and often not applicable in specific industrial conditions. AIT data correspond to temperature ranges in which fuels display an incipient reactivity, with time scales amounting in seconds or even in minutes instead of milliseconds in flames. In these conditions, the critical reactions are most often different from the ones governing the reactivity in a flame or in high temperature ignition. Some of the critical paths for AIT, especially those involving peroxy radicals, are similar to those encountered in slow oxidation. Therefore, the main available kinetic models that have been developed for fast combustion, are unfortunately unable to represent properly these low temperature processes. In this context, a numerical approach addressing the influence of process conditions on the minimum auto-ignition temperature of different fuel/air mixtures has been developed. For that purpose, several chemical models available in the literature have been tested, in order to identify the most robust ones. Based on previous works of our group, a model covering a large temperature range has been developed, which offers a fair reconciliation between experimental and calculated AIT data through a wide range of fuel compositions. This model has been validated against experimental auto-ignition delay times (AID) corresponding to high temperature in order to ensure its relevance not only for AIT aspects but also for the reactivity of gaseous fuels over the wide range of gas turbine operation conditions. In addition, the AITs of methane, of pure light alkanes and of various blends representative of several natural gas and process-derived fuels were extensively covered. In particular, among alternative gas turbine fuels, hydrogen-rich gases are called to play an increasing part in the future so that their ignition characteristics have been addressed with particular care. Natural gas enriched with hydrogen, and different CO/H2 syngas fuels originating from a blast furnace (BFG) have namely been studied. Globally, the individual species covered are: H2, CO, CO2, N2, CH4, C2H6, C3H8, C4H10, and C5H12. AIT values have been evaluated in function of the equivalence ratio and pressure. All the results obtained have been fitted by means of a practical mathematical expression. The overall study leads to a simple correlation of AIT versus equivalence ratio/pressure that may be of fruitful use for the engineering community.

Predicting Flameholding for Hydrogen and Natural Gas Flames at Gas Turbine Premixer Conditions

2016 ◽  
Vol 138 (12) ◽  
Author(s):  
Elliot Sullivan-Lewis ◽  
Vincent McDonell
Keyword(s):  
Power Generation ◽  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Experimental Studies ◽  
Temperature Variations ◽  
Auto Ignition ◽  
Chamber Temperature ◽  
Transient Events ◽  
Significant Effort

Lean-premixed gas turbines are now common devices for low emissions stationary power generation. By creating a homogeneous mixture of fuel and air upstream of the combustion chamber, temperature variations are reduced within the combustor, which reduces emissions of nitrogen oxides. However, by premixing fuel and air, a potentially flammable mixture is established in a part of the engine not designed to contain a flame. If the flame propagates upstream from the combustor (flashback), significant engine damage can result. While significant effort has been put into developing flashback resistant combustors, these combustors are only capable of preventing flashback during steady operation of the engine. Transient events (e.g., auto-ignition within the premixer and pressure spikes during ignition) can trigger flashback that cannot be prevented with even the best combustor design. In these cases, preventing engine damage requires designing premixers that will not allow a flame to be sustained. Experimental studies were conducted to determine under what conditions premixed flames of hydrogen and natural gas can be anchored in a simulated gas turbine premixer. Tests have been conducted at pressures up to 9 atm, temperatures up to 750 K, and freestream velocities between 20 and 100 m/s. Flames were anchored in the wakes of features typical of premixer passageways, including cylinders, steps, and airfoils. The results of this study have been used to develop an engineering tool that predicts under what conditions a flame will anchor, and can be used for development of flame anchoring resistant gas turbine premixers.

Study of a Rich/Lean Staged Combustion Concept for Hydrogen at Gas Turbine Relevant Conditions

2013 ◽  
Author(s):  
Felipe Bolaños ◽  
Dieter Winkler ◽  
Felipe Piringer ◽  
Timothy Griffin ◽  
Rolf Bombach ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Carbon Capture ◽  
Flame Temperature ◽  
Nox Emissions ◽  
Hydrogen Fuel ◽  
Auto Ignition ◽  
Wide Range ◽  
The Rich

The combustion of hydrogen-rich fuels (> 80 % vol. H2), relevant for gas turbine cycles with “pre-combustion” carbon capture, creates great challenges in the application of standard lean premix combustion technology. The significant higher flame speed and drastically reduced auto-ignition delay time of hydrogen compared to those of natural gas, which is normally burned in gas turbines, increase the risk of higher NOX emissions and material damage due to flashback. Combustion concepts for gas turbines operating on hydrogen fuel need to be adapted to assure safe and low-emission combustion. A rich/lean (R/L) combustion concept with integrated heat transfer that addresses the challenges of hydrogen combustion has been investigated. A sub-scale, staged burner with full optical access has been designed and tested at gas turbine relevant conditions (flame temperature of 1750 K, preheat temperature of 400 °C and a pressure of 8 bar). Results of the burner tests have confirmed the capability of the rich/lean staged concept to reduce the NOx emissions for undiluted hydrogen fuel. The NOx emissions were reduced from 165 ppm measured without staging (fuel pre-conversion) to 23 ppm for an R/L design having a fuel-rich hydrogen pre-conversion of 50 % at a constant power of 8.7 kW. In the realized R/L concept the products of the first rich stage, which is ignited by a Pt/Pd catalyst (under a laminar flow, Re ≈ 1900) are combusted in a diffusion-flame-like lean stage (turbulent flow Re ≈ 18500) without any flashback risk. The optical accessibility of the reactor has allowed insight into the combustion processes of both stages. Applying OH-LIF and OH*-chemiluminescence optical techniques, it was shown that mainly homogeneous reactions at rich conditions take place in the first stage, questioning the importance of a catalyst in the system, and opening a wide range of optimization possibilities. The promising results obtained in this study suggest that such a rich/lean staged burner with integrated heat transfer could help to develop a new generation of gas turbine burners for safe and clean combustion of H2-rich fuels.

DME as a Potential Alternative Fuel for Gas Turbines: A Numerical Approach to Combustion and Oxidation Kinetics

2011 ◽  
Author(s):  
Pierre A. Glaude ◽  
Rene´ Fournet ◽  
Roda Bounaceur ◽  
Michel Molie`re
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Heat Input ◽  
Ignition Delay ◽  
Gas Turbines ◽  
Ignition Temperature ◽  
Alternative Fuels ◽  
Ignition Delay Times ◽  
Auto Ignition ◽  
Delay Times

Many investigations are currently carried out in order to reduce CO2 emissions in power generation. Among alternative fuels to natural gas and gasoil in gas turbine applications, dimethyl ether (DME; formula: CH3-O-CH3) represents a possible candidate in the next years. This chemical compound can be produced from natural gas or coal/biomass gasification. DME is a good substitute for gasoil in diesel engine. Its Lower Heating Value is close to that of ethanol but it offers some advantages compared to alcohols in terms of stability and miscibility with hydrocarbons. While numerous studies have been devoted to the combustion of DME in diesel engines, results are scarce as far as boilers and gas turbines are concerned. Some safety aspects must be addressed before feeding a combustion device with DME because of its low flash point (as low as −83°C), its low auto-ignition temperature and large domain of explosivity in air. As far as emissions are concerned, the existing literature shows that in non premixed flames, DME produces less NOx than ethane taken as parent molecular structure, based on an equivalent heat input to the burner. During a field test performed in a gas turbine, a change-over from methane to DME led to a higher fuel nozzle temperature but to a lower exhaust gas temperature. NOx emissions decreased over the whole range of heat input studied but a dramatic increase of CO emissions was observed. This work aims to study the combustion behavior of DME in gas turbine conditions with the help of a detailed kinetic modeling. Several important combustion parameters, such as the auto-ignition temperature (AIT), ignition delay times, laminar burning velocities of premixed flames, adiabatic flame temperatures, and the formation of pollutants like CO and NOx have been investigated. These data have been compared with those calculated in the case of methane combustion. The model was built starting from a well validated mechanism taken from the literature and already used to predict the behavior of other alternative fuels. In flame conditions, DME forms formaldehyde as the major intermediate, the consumption of which leads in few steps to CO then CO2. The lower amount of CH2 radicals in comparison with methane flames seems to decrease the possibility of prompt-NO formation. This paper covers the low temperature oxidation chemistry of DME which is necessary to properly predict ignition temperatures and auto-ignition delay times that are important parameters for safety.

Hydrogen Combustion Within a Gas Turbine Reheat Combustor

2012 ◽  
Author(s):  
Madhavan Poyyapakkam ◽  
John Wood ◽  
Steven Mayers ◽  
Andrea Ciani ◽  
Felix Guethe ◽  
...  
Keyword(s):  
Pressure Drop ◽  
Natural Gas ◽  
Gas Turbine ◽  
Dynamic Properties ◽  
Fluid Dynamic ◽  
Fold Increase ◽  
Inlet Temperature ◽  
Turbine Performance ◽  
Auto Ignition ◽  
Operating Window

This paper describes a novel lean premixed reheat burner technology suitable for Hydrogen-rich fuels. The inlet temperature for such a combustor is very high and reaction of the fuel/oxidant mixture is initiated through auto-ignition, the delay time for which reduces significantly for Hydrogen-rich fuels in comparison to natural gases. Therefore the residence time available for premixing within the burner is reduced. The new reheat burner concept has been optimized to allow rapid fuel/oxidant mixing, to have a high flashback margin and to limit the pressure drop penalty. The performance of the burner is described, initially in terms of its fluid dynamic properties and then its combustion characteristics. The latter are based upon full-scale high-pressure tests, where results are shown for two variants of the concept, one with a pressure drop comparable to today’s natural gas burners, and the other with a two-fold increase in pressure drop. Both burners indicated that Low NOx emissions, comparable to today’s natural gas burners, were feasible at reheat engine conditions (ca. 20 Bars and ca. 1000C inlet temperature). The higher pressure drop variant allowed a wider operating window. However the achievement of the lower pressure drop burner shows that the targeted Hydrogen-rich fuel (70/30 H2/N2 by volume) can be used within a reheat combustor without any penalty on gas turbine performance.

scholarly journals High Efficiency-Coal and Gas (HE-C&G): An Advanced Hybrid Power Plant Concept With Sequential Combustion Gas Turbines GT24/GT26

1997 ◽  
Author(s):  
Mircea Fetescu
Keyword(s):  
Power Plant ◽  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
High Efficiency ◽  
Combustion Gas ◽  
Hybrid Power ◽  
Wide Range ◽  
Hybrid Power Plant ◽  
Very High

The High Efficiency-Coal and Gas (HE-C&G) is a hybrid power plant concept integrating Conventional Steam Power Plants (CSPP) and gas turbine / combined cycle plants. The gas turbine exhaust gas energy is recovered in the HRSG providing partial condensate and feedwater preheating and generating steam corresponding to the main boiler live steam conditions (second steam source for the ST). The concept, exhibiting very high design flexibility, integrates the high performance Sequential Combustion gas turbines GT24/GT26 technology into a wide range of existing or new CSPP. Although HE-C&G refers to coal as the most abundant fossil fuel resource, oil or natural gas fired steam plants could be also designed or converted following the same principle. The HE-C&G provides very high marginal efficiencies on natural gas, up to and above 60%, very high operating and dispatching flexibility and on-line optimization of fuel and O&M costs at low capital investment. This paper emphasizes the operating flexibility and resulting benefits, recommending the HE-C&G as one of the most profitable options for generating power especially for conversion of existing CSPP with gas turbines.

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