In-Line Testing of Novel Filter Media for Oil-Water Mixtures

Author(s):  
Anisha Mule ◽  
Ramin Dabirian ◽  
Srinivas Swaroop Kolla ◽  
Ram Mohan ◽  
Ovadia Shoham

Abstract A novel non-fibrous filter media is evaluated for in-line oil-water separation. Outside-in-crossflow configuration incorporating the filter media is utilized in order to test the filter. All experiments are conducted with a hydrophilic-olephobic filter for water-continuous flow with low oil concentrations. The collected experimental data include permeate flow rate and purity as well as pressure drop. Values of permeate flow rate and pressure drop are averaged over the duration of the experiments, which is about 5 minutes, constituting the “initial average” of the permeate flow rate and the corresponding pressure drop. Totally twelve experimental runs are conducted for mixture velocities of 0.038 m/s, 0.055 m/s and 0.066 m/s, and oil concentrations of 0.6%, 0.83%, 1.1%, 7.9% and 9.1%. Permeate samples are analyzed for oil content, demonstrating a high separation efficiency of 98 ± 2%. The permeate flux across the filter cartridge ranges between 0.0739 (L/h)/cm2 to 0.216 (L/h)/cm2 owing to the low pressure drop across to filter. Oil concentration in to permeate water samples shows consistently increasing trend with an increase in inlet oil content, while maintaining high separation efficiency for all runs. The pressure drop across the membrane under flowing conditions ranges from 0.35 psid to 0.6 psid for flow rates between 0.1 L/min and 0.29 L/min, respectively. Also the data confirm that the filter membrane breakthrough pressure is 0.35 psid.

RSC Advances ◽  
2019 ◽  
Vol 9 (29) ◽  
pp. 16296-16304 ◽  
Author(s):  
Jayaprakash Saththasivam ◽  
Kui Wang ◽  
Wubulikasimu Yiming ◽  
Zhaoyang Liu ◽  
Khaled A. Mahmoud

A highly hydrophilic and oleophobic membrane based on Ti3C2Tx (MXene) coated paper demonstrated high separation efficiency for oil/water emulsions with excellent antifouling properties.


RSC Advances ◽  
2016 ◽  
Vol 6 (69) ◽  
pp. 65171-65178 ◽  
Author(s):  
Zhe-Qin Dong ◽  
Bao-Juan Wang ◽  
Min Liu ◽  
Xiao-hua Ma ◽  
Zhen-Liang Xu

A TiO2 coated mesh with self-cleaning property, robust underwater superoleophobicity and high separation efficiency was fabricated by sol–gel method.


2021 ◽  
Vol 8 ◽  
Author(s):  
Min Zhan ◽  
Wanyou Yang ◽  
Fenghui Zhang ◽  
Changhua Luo ◽  
Huaxiao Wu ◽  
...  

To reduce the cost of oil exploitation, it is necessary to promote the development of cyclones for oil-water separation due to the increase of the water content in produced fluids. However, there are some limitations and disadvantages for the conventional separation device including bulky settling tanks and hydrocyclones. In this paper, a new axial inlet separator with two reverse flow outlets and a downstream flow outlet is introduced. In addition, an experimental system was designed and fabricated to investigate the effects of inlet flow rate, oil fraction, and a controlled split ratio on separation performance. The separator maintains high separation efficiency within the experimental range, namely water flow rate (4–7 m3/h), and oil fraction (1%–10%). Furthermore, the results show that a higher water flow rate and oil fraction will affect the separation efficiency. The change of a pressure drop in the separator was analyzed as well. Moreover, the controlled split ratio is a serious operating parameter, and a larger controlled split ratio is conducive to the separation performance.


Author(s):  
Maryam Ibrahim Chasib ◽  
Raghad Fareed Qasim

This research presents the design procedure for liquid – liquid hydrocyclone to separate kerosene – water emulsion. It studies the effects of varying feed flow rate (6, 8, 10, and 12 l/min), inlet kerosene concentration (250, 500, 750, 1000, and 1250 ppm) , and split ratio (0.1, 0.3, 0.5, 0.7, and 0.9) on the outcomes; separation efficiency and pressure drop ratio . This study used factorial experimental design assisted with Minitab program to obtain the optimum operating conditions. It was shown that inlet concentration of 250 ppm, 12 l/min inlet flow rate, and 0.9 split ratio gave 94.78 % as maximum separation efficiency and 0.895 as minimum pressure drop ratio.


RSC Advances ◽  
2017 ◽  
Vol 7 (33) ◽  
pp. 20147-20151 ◽  
Author(s):  
Zhenzhen Wu ◽  
Yingzhan Li ◽  
Linping Zhang ◽  
Yi Zhong ◽  
Hong Xu ◽  
...  

Thiol–ene click reaction was employed to synthesize a flexible hydrophilic cellulose sponge. The sponge can be circular used in oil/water mixture (emulsion) separation and hold separation efficiency high separation efficiency.


2004 ◽  
Vol 126 (4) ◽  
pp. 553-564 ◽  
Author(s):  
C. Oropeza-Vazquez ◽  
E. Afanador ◽  
L. Gomez ◽  
S. Wang ◽  
R. Mohan ◽  
...  

The hydrodynamics of multiphase flow in a Liquid-Liquid Cylindrical Cyclone (LLCC) compact separator have been studied experimentally and theoretically for evaluation of its performance as a free water knockout device. In the LLCC, no complete oil-water separation occurs. Rather, it performs as a free-water knockout, delivering a clean water stream in the underflow and an oil rich stream in the overflow. A total of 260 runs have been conducted, measuring the LLCC separation efficiency for water-dominated flow conditions. For all runs, an optimal split-ratio (underflow to inlet flow rate ratio) exists, where the flow rate in the water stream is maximum, with 100% watercut. The value of the optimal split-ratio depends upon the existing inlet flow pattern, and varies between 60% and 20%. For split-ratios higher than the optimal one, the watercut in the underflow stream decreases as the split-ratio increases. A novel mechanistic model has been developed for the prediction of the complex flow behavior and the separation efficiency in the LLCC. Comparisons between the experimental data and the LLCC model predictions show excellent agreement. The model is capable of predicting both the trend of the experimental data as well as the absolute measured values. The developed model can be utilized for the design and performance analysis of the LLCC.


2021 ◽  
Vol 18 (4) ◽  
pp. 887-899
Author(s):  
Yanling Tian ◽  
Jiekai Feng ◽  
Zexin Cai ◽  
Jiaqi Chao ◽  
Dawei Zhang ◽  
...  

AbstractReckless discharge of industrial wastewater and domestic sewage as well as frequent leakage of crude oil have caused serious environmental problems and posed severe threat to human survival. Various nature inspired superhy-drophobic surfaces have been successfully applied in oily water remediation. However, further improvements are still urgently needed for practical application in terms of facile synthesis process and long-term durability towards harsh environment. Herein, we propose a simple one-step dodecyl mercaptan functionalization method to fabricate Super-hydrophobic-Superoleophilic Copper Mesh (SSCM). The prepared SSCM possesses excellent water repellence and oil affinity, enabling it to successfully separate various oil-water mixtures with high separation efficiency (e.g., > 99% for hexadecane-water mixture). The SSCM retains high separating ability when hot water and strong corrosive aqueous solutions are used to simulate oil-water mixtures, indicating remarkable chemical durability of the dodecyl mercaptan functionalized copper mesh. Additionally, the efficiency can be well maintained during 50 cycles of separation, and the water repellence is even stable after storage in air for 120 days, demonstrating the reusability and long-term stability of the SSCM. Furthermore, the functionalized mesh also shows good mechanical robustness towards abrasion by sandpaper, and oil-water separation efficiency of > 96% can be obtained after 10 cycles of abrasion. The reported one-step dodecyl mercaptan functionalization could be a simple method for increasing the water repellence of copper mesh, and thereby be a great candidate for treating large-scale oily wastewater in harsh environments.


Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 248
Author(s):  
Saad A. Aljlil

In this study, a red clay/nano-activated carbon membrane was investigated for the removal of oil from industrial wastewater. The sintering temperature was minimized using CaF2 powder as a binder. The fabricated membrane was characterized by its mechanical properties, average pore size, and hydrophilicity. A contact angle of 67.3° and membrane spore size of 95.46 nm were obtained. The prepared membrane was tested by a cross-flow filtration process using an oil-water emulsion, and showed a promising permeate flux and oil rejection results. During the separation of oil from water, the flux increased from 191.38 to 284.99 L/m2 on increasing the applied pressure from 3 to 6 bar. In addition, high water permeability was obtained for the fabricated membrane at low operating pressure. However, the membrane flux decreased from 490.28 to 367.32 L/m2·h due to oil deposition on the membrane surface; regardless, the maximum oil rejection was 99.96% at an oil concentration of 80 NTU and a pressure of 5 bar. The fabricated membrane was negatively charged, as were the oil droplets, thereby facilitating membrane purification through backwashing. The obtained ceramic membrane functioned well as a hydrophilic membrane and showed potential for use in oil wastewater treatment.


Open Physics ◽  
2021 ◽  
Vol 19 (1) ◽  
pp. 486-493
Author(s):  
Ting Liang ◽  
Biao Wang ◽  
Zhenzhong Fan ◽  
Qingwang Liu

Abstract A facile method for fabricating superhydrophobic and superoleophilic powder with 5A zeolite and stearic acid (SA) is reported in this study. The effect of different contents of SA on contact angle (CA) was investigated. The maximum water CA was 156.2°, corresponding to the optimum SA content of 1.5 wt%. The effects of SA and the mechanism of modified 5A zeolite powder by SA were analyzed by sedimentation analysis experiment, FTIR analysis, particle size analysis, and SEM characterization. The SA-modified 5A zeolite was used as an oil sorbent to separate oil–water mixture with potential use in floating oil. The separation efficiency was above 98%.


Author(s):  
Sina Jahangiri Mamouri ◽  
Volodymyr V. Tarabara ◽  
André Bénard

Deoiling of produced or impaired waters associated with oil and gas production represents a significant challenge for many companies. Centrifugation, air flotation, and hydrocyclone separation are the current methods of oil removal from produced water [1], however the efficiency of these methods decreases dramatically for droplets smaller than approximately 15–20 μm. More effective separation of oil-water mixtures into water and oil phases has the potential to both decrease the environmental footprint of the oil and gas industry and improve human well-being in regions such as the Gulf of Mexico. New membrane separation processes and design of systems with advanced flow management offer tremendous potential for improving oil-water separation efficacy. However, fouling is a major challenge in membrane separation [2]. In this study, the behavior of oil droplets and their interaction with crossflow filtration (CFF) membranes (including membrane fouling) is studied using computational fluid dynamics (CFD) simulations. A model for film formation on a membrane surface is proposed for the first time to simulate film formation on membrane surfaces. The bulk multiphase flow is modeled using an Eulerian-Eulerian multiphase flow model. A wall film is developed from mass and momentum balances [3] and implemented to model droplet deposition and membrane surface blockage. The model is used to predict film formation and subsequent membrane fouling, and allow to estimate the actual permeate flux. The results are validated using available experimental data.


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