The Effect of Impurities in Fuel Grade Dimethyl-Ether on Combustion Characteristics

Author(s):  
Kimihito Narukawa ◽  
Hiromi Koizumi ◽  
Hiroshi Inoue ◽  
Nariyoshi Kobayashi

In order to investigate the effect of impurities contained in fuel grade dimethyl-ether on combustion characteristics, laminar burning velocity tests and diffusion flame combustor tests were carried out with various contents of impurities in fuel grade dimethyl-ether (with about 0–9wt% methanol and 0–10wt% moisture). From the laminar burning velocity tests, it was found that the burning velocity of fuel grade dimethyl-ether was slightly slower than that of high purity dimethyl-ether and it was faster than that of methane. This indicates that fuel grade dimethyl-ether has a high potential of flash back, like high purity dimethyl-ether. Moreover, the diffusion flame combustor tests showed that NOx emission decreased when the impurities contained in fuel grade dimethyl-ether were increased, however CO emissions were almost constant, irrespective of the content of impurities. Further, by comparing NOx emissions with various contents of impurities in fuel grade dimethyl-ether, it was clear that NOx emissions could be estimated from the adiabatic flame temperature. From these results, a lot of valuable data regarding impurities content has been obtained, which will assist in the development of a gas turbine combustor for fuel grade dimethyl-ether.

Author(s):  
Hong-Meng Li ◽  
Guo-Xiu Li ◽  
Zuo-Yu Sun ◽  
Zi-Hang Zhou ◽  
Yuan Li ◽  
...  

In this work, the laminar combustion characteristics of H2/N2/air (H2/CO2/air) were systematically investigated under different hydrogen ratios (40–100%) and equivalence ratios (0.4–1.0) in a closed combustion vessel using the spherical expanding flame method associated with Schlieren technology. The unstretched laminar burning velocities were compared with data from previous study, and the result indicates that excellent agreements are obtained. Numerical simulations were also conducted using GRI3.0 and USC II mechanisms to compare with the present experimental results. The Markstein length for H2/inert gas can be decreased by decreasing the equivalence ratio and hydrogen ratio. The results indicate that the H2/inert gas premixed flames tend to be more unstable with the decrease of equivalence ratio and hydrogen ratio. For H2/N2 mixture, the suppression effect on laminar burning velocity is caused by modified specific heat of mixtures and decreased heat release, which result in a decreased flame temperature. For H2/CO2 mixture, the carbon dioxide has stronger dilution effect than nitrogen in reducing laminar burning velocity owing to both thermal effect and chemical effect.


Fuel ◽  
2021 ◽  
Vol 284 ◽  
pp. 119017 ◽  
Author(s):  
Huaqiang Chu ◽  
Longkai Xiang ◽  
Shun Meng ◽  
Wenlong Dong ◽  
Mingyan Gu ◽  
...  

Author(s):  
Masato Hiramatsu ◽  
Yoshifumi Nakashima ◽  
Sadamasa Adachi ◽  
Yudai Yamasaki ◽  
Shigehiko Kaneko

One approach to achieving 99% combustion efficiency (C.E.) and 10 ppmV or lower NOx (at 15%O2) in a micro gas turbine (MGT) combustor fueled by biomass gas at a variety of operating conditions is with the use of flameless combustion (FLC). This paper compares experimentally obtained results and CHEMKIN analysis conducted for the developed combustor. As a result, increase the number of stage of FLC combustion enlarges the MGT operation range with low-NOx emissions and high-C.E. The composition of fuel has a small effect on the characteristics of ignition in FLC. In addition, NOx in the engine exhaust is reduced by higher levels of CO2 in the fuel.


Author(s):  
Nathan T. Weiland ◽  
Peter A. Strakey

Lean-Direct-Injection (LDI) combustion is being considered at NETL as a means to attain low NOx emissions in a high-hydrogen gas turbine combustor. Integrated Gasification Combined Cycle (IGCC) plant designs can create a high-hydrogen fuel using a water-gas shift reactor and subsequent CO2 separation. The IGCC’s air separation unit produces a volume of N2 roughly equivalent to the volume of H2 in the gasifier product stream, which can be used to help reduce peak flame temperatures and NOx in the diffusion flame combustor. Placement of this diluent in either the air or fuel streams is a matter of practical importance, and has not been studied to date for LDI combustion. The current work discusses how diluent placement affects diffusion flame temperatures, residence times, and stability limits, and their resulting effects on NOx emissions. From a peak flame temperature perspective, greater NOx reduction should be attainable with fuel dilution rather than air or independent dilution in any diffusion flame combustor with excess combustion air, due to the complete utilization of the diluent as a heat sink at the flame front, although the importance of this mechanism is shown to diminish as flow conditions approach stoichiometric proportions. For simple LDI combustor designs, residence time scaling relationships yield a lower NOx production potential for fuel-side dilution due to its smaller flame size, whereas air-dilution yields a larger air entrainment requirement and a subsequently larger flame, with longer residence times and higher thermal NOx generation. For more complex staged-air LDI combustor designs, dilution of the primary combustion air at fuel-rich conditions can result in full utilization of the diluent for reducing the peak flame temperature, while also controlling flame volume and residence time for NOx reduction purposes. However, differential diffusion of hydrogen out of a diluted hydrogen/nitrogen fuel jet can create regions of higher hydrogen content in the immediate vicinity of the fuel injection point than can be attained with dilution of the air stream, leading to increased flame stability. By this mechanism, fuel-side dilution extends the operating envelope to areas with higher velocities in the experimental configurations tested, where faster mixing rates further reduce flame residence times and NOx emissions. Strategies for accurate CFD modeling of LDI combustors’ stability characteristics are also discussed.


Author(s):  
Hui Wu ◽  
Wenxing Zhang ◽  
Kejin Mu ◽  
Yue Wang ◽  
Yunhan Xiao

As the development and increasingly widespread use of IGCC and zero emission energy system, the development of advanced combustion capabilities for gaseous hydrogen and hydrogen rich fuels in gas turbine applications is becoming an area of much great concern. The combustion characteristics of hydrogen rich fuel is very different from nature gas in aspects such as flame stability, flame temperature, combustor acoustics, pollutant emissions, combustor efficiency, and some other important quantities. However, few of these issues are clearly understood by far. The purpose of this paper is to compare in detail the combustion performance of hydrogen-methane hybrid fuels with various volumetric H2 fractions ranging from 0% to 100%. Meanwhile, the comparison of pure H2, pure CH4, and 80%H2+20%CH4 was the emphasis. 80%H2+20%CH4 hybrid gas is selected expressly because its component is approximately equal to the outcome of a hydrogen production test bed of our laboratory, and it is considered by the team to be a potential transition fuel of gas turbines between nature gas and pure hydrogen. Detailed experimental measurements and numerical simulations were conducted using a coflow jet diffusion burner. It was found that in the extent of experiments, when under equal general power, the flame length of hydrogen contained fuels wasn’t much shorter than methane, and didn’t get shorter with the increase of H2 fraction as expected. That was because the shortening tendency caused by the increase of H2 fraction was counteracted partially by the increase of fuel velocity, results of which was the extending of flame length. Maximum temperature of H2 flame was 1733K, which was 30K higher than 80%H2+20%CH4 and 120K higher than CH4. All of the highest temperatures of the three fuels were presented at the recirculation zone of the flame. Although it seemed that the flame of CH4 had the longest dimension compared with H2 contained fuels when observed through photos, the high temperature region of flames was getting longer when increasing H2 fractions. Curves of temperature distribution predicted by all the four combustion models in FLUENT investigated here had a departure away from the experimental data. Among the models, Flamelet model was the one whose prediction was comparatively close to the experimental results. Flame of H2 and 80%H2+20%CH4 had a much better stability than flame of CH4, they could reach a so called recirculating flame phase and never been blew out in the extent of experiments. On the contrary, CH4 flames were blew out easily soon after they were lifted up. Distribution of OH concentration at the root of flames showed that the flame boundary of H2 and 80%H2+20%CH4 was more clearly than CH4. That is to say, at the root of the flame, combustion of H2 was the most intensive one, 80%H2+20%CH4 took the second place, while CH4 was the least. NOx emissions didn’t show a linear relationship with the volumetric fraction of H2, but showed an exponential uptrend instead. It presented a fairly consistent tendency with flame temperature, which proved again there was a strong relationship between flame temperature and NOx emissions in the combustion of hydrogen contained fuels. If adding CH4 into pure H2, NOx concentration would have a 17.2ppm reduction with the first 20% accession, but only 11.1ppm with the later 80% accession. Hence, if NOx emission was the only aspect to be considered, 80%H2+20%CH4 seemed to be a better choice of transition fuel from pure CH4 to pure H2.


2021 ◽  
Vol 9 ◽  
Author(s):  
Jun Li ◽  
Shini Lai ◽  
Danan Chen ◽  
Rongjun Wu ◽  
Noriyuki Kobayashi ◽  
...  

A comprehensive review of combustion characteristics of ammonia (NH3) as a carbon free fuel is presented. NH3 is an attractive alternative fuel candidate to reduce the consumption of fossil fuel and the emission of CO2, soot, and hydrocarbon pollutants, due to its comparable combustion properties, productivities from renewable sources, and storage and transportation by current commercial infrastructure. However, the combustion properties of NH3 are quite different from conventional hydrocarbon fuels, which highlight the specific difficulties during the application of NH3. Therefore, this paper presents comparative experimental and numerical studies of the application of NH3 as a fuel during combustion process, including the combustion properties of laminar burning velocity, flame structures, pollutant emissions for the application of NH3 as a carbon free fuel. This paper presents the burning velocity and pollutant emissions of NH3 alone and mixtures with other fuels to improve the combustion properties. The aim of this paper is to review and describe the suitability of NH3 as a fuel, including the combustion and emission characteristics of NH3 during its combustion process.


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