High-Speed Spectrally Resolved Imaging Studies of Spherically Expanding Natural Gas Flames Under Gas Turbine Operating Conditions

2019 ◽  
Author(s):  
Pradeep Parajuli ◽  
Tyler Paschal ◽  
Mattias A. Turner ◽  
Eric L. Petersen ◽  
Waruna D. Kulatilaka
Keyword(s):  
Natural Gas ◽  
Flame Front ◽  
Gas Turbines ◽  
High Speed ◽  
Laminar Flame ◽  
Turbulent Flame ◽  
Initial Pressure ◽  
Flame Speed ◽  
Operating Conditions ◽  
Important Species

Abstract Natural gas is a major fuel source for many industrial and power-generation applications. The primary constituent of natural gas is methane (CH4), while smaller quantities of higher order hydrocarbons such as ethane (C2H6) and propane (C3H8) can also be present. Detailed understanding of natural gas combustion is important to obtain the highest possible combustion efficiency with minimal environmental impact in devices such as gas turbines and industrial furnaces. For a better understanding the combustion performance of natural gas, several important parameters to study are the flame temperature, heat release zone, flame front evolution, and laminar flame speed as a function of flame equivalence ratio. Spectrally and temporally resolved, high-speed chemiluminescence imaging can provide direct measurements of some of these parameters under controlled laboratory conditions. A series of experiments were performed on premixed methane/ethane-air flames at different equivalence ratios inside a closed flame speed vessel that allows the direct observation of the spherically expanding flame front. The vessel was filled with the mixtures of CH4 and C2H6 along with respective partial pressures of O2 and N2, to obtain the desired equivalence ratios at 1 atm initial pressure. A high-speed camera coupled with an image intensifier system was used to capture the chemiluminescence emitted by the excited hydroxyl (OH*) and methylidyne (CH*) radicals, which are two of the most important species present in the natural gas flames. The calculated laminar flame speeds for an 80/20 methane/ethane blend based on high-speed chemiluminescence images agreed well with the previously conducted Z-type schlieren imaging-based measurements. A high-pressure test, conducted at 5 atm initial pressure, produced wrinkles in the flame and decreased flame propagation rate. In comparison to the spherically expanding laminar flames, subsequent turbulent flame studies showed the sporadic nature of the flame resulting from multiple flame fronts that were evolved discontinuously and independently with the time. This paper documents some of the first results of quantitative spherical flame speed experiments using high-speed chemiluminescence imaging.

Flame Characteristics and Turbulent Flame Speeds of Turbulent, High-Pressure, Lean Premixed Methane/Air Flames

2005 ◽  
Author(s):  
P. Griebel ◽  
R. Bombach ◽  
A. Inauen ◽  
R. Scha¨ren ◽  
S. Schenker ◽  
...  
Keyword(s):  
Flame Front ◽  
Gas Turbines ◽  
Equivalence Ratio ◽  
Turbulent Flame ◽  
Flame Speed ◽  
Operating Conditions ◽  
Turbulent Flame Speed ◽  
Front Position ◽  
Preheating Temperature ◽  
Lean Premixed

The present experimental study focuses on flame characteristics and turbulent flame speeds of lean premixed flames typical for stationary gas turbines. Measurements were performed in a generic combustor at a preheating temperature of 673 K, pressures up to 14.4 bars (absolute), a bulk velocity of 40 m/s, and an equivalence ratio in the range of 0.43–0.56. Turbulence intensities and integral length scales were measured in an isothermal flow field with Particle Image Velocimetry (PIV). The turbulence intensity (u′) and the integral length scale (LT) at the combustor inlet were varied using turbulence grids with different blockage ratios and different hole diameters. The position, shape, and fluctuation of the flame front were characterized by a statistical analysis of Planar Laser Induced Fluorescence images of the OH radical (OH-PLIF). Turbulent flame speeds were calculated and their dependence on operating conditions (p, φ) and turbulence quantities (u′, LT) are discussed and compared to correlations from literature. No influence of pressure on the most probable flame front position or on the turbulent flame speed was observed. As expected, the equivalence ratio had a strong influence on the most probable flame front position, the spatial flame front fluctuation, and the turbulent flame speed. Decreasing the equivalence ratio results in a shift of the flame front position farther downstream due to the lower fuel concentration and the lower adiabatic flame temperature and subsequently lower turbulent flame speed. Flames operated at leaner equivalence ratios show a broader spatial fluctuation as the lean blow-out limit is approached and therefore are more susceptible to flow disturbances. In addition, because of a lower turbulent flame speed these flames stabilize farther downstream in a region with higher velocity fluctuations. This increases the fluctuation of the flame front. Flames with higher turbulence quantities (u′, LT) in the vicinity of the combustor inlet exhibited a shorter length and a higher calculated flame speed. An enhanced turbulent heat and mass transport from the recirculation zone to the flame root location due to an intensified mixing which might increase the preheating temperature or the radical concentration is believed to be the reason for that.

Laminar and Turbulent Flame Speeds for Natural Gas/Hydrogen Blends

2014 ◽  
Author(s):  
A. Morones ◽  
S. Ravi ◽  
D. Plichta ◽  
E. L. Petersen ◽  
N. Donohoe ◽  
...  
Keyword(s):  
Natural Gas ◽  
Laminar Flame ◽  
Turbulent Flame ◽  
Initial Pressure ◽  
Chemical Kinetic ◽  
Flame Speed ◽  
Intensity Level ◽  
Chemical Kinetic Model ◽  
Turbulent Flame Speed ◽  
Reaction Zones

Hydrogen-based fuels have become a primary interest in the gas turbine market. To better predict the reactivity of mixtures containing different levels of hydrogen, laminar and turbulent flame speed experiments have been conducted. The laminar flame speed measurements were performed for various methane and natural gas surrogate blends with significant amounts of hydrogen at elevated pressures (up to 5 atm) and temperatures (up to 450 K) using a heated, high-pressure, cylindrical, constant-volume vessel. The hydrogen content ranged from 50% to 90% by volume. All measurements were compared to a chemical kinetic model, and good agreement within experimental measurement uncertainty was observed over most conditions. Turbulent combustion experiments were also performed for pure H2 and 50:50 H2:CH4 mixtures using a fan-stirred flame speed vessel. All tests were made with a fixed integral length scale of 27 mm and with a turbulent intensity level of 1.5 m/s at 1 atm initial pressure. Most of the turbulent flame speed results were in either the corrugated or thin reaction zones when plotted on a Borghi diagram, with Damköhler numbers up to 100 and turbulent Reynolds numbers between about 100 and 450. Flame speeds for a 50:50 blend of H2:CH4 for both laminar and turbulent cases were about a factor of 1.8 higher than for pure methane.

Laminar flame speed correlations for methane, ethane, propane and their mixtures, and natural gas and gasoline for spark-ignition engine simulations

2017 ◽  
Vol 18 (9) ◽  
pp. 951-970 ◽  
Author(s):  
Riccardo Amirante ◽  
Elia Distaso ◽  
Paolo Tamburrano ◽  
Rolf D Reitz
Keyword(s):  
Natural Gas ◽  
Laminar Flame ◽  
Spark Ignition ◽  
Flame Speed ◽  
Operating Conditions ◽  
Spark Ignition Engine ◽  
Computational Time ◽  
Laminar Flame Speed ◽  
Spark Ignition Engines ◽  
Empirical Correlations

The laminar flame speed plays an important role in spark-ignition engines, as well as in many other combustion applications, such as in designing burners and predicting explosions. For this reason, it has been object of extensive research. Analytical correlations that allow it to be calculated have been developed and are used in engine simulations. They are usually preferred to detailed chemical kinetic models for saving computational time. Therefore, an accurate as possible formulation for such expressions is needed for successful simulations. However, many previous empirical correlations have been based on a limited set of experimental measurements, which have been often carried out over a limited range of operating conditions. Thus, it can result in low accuracy and usability. In this study, measurements of laminar flame speeds obtained by several workers are collected, compared and critically analyzed with the aim to develop more accurate empirical correlations for laminar flame speeds as a function of equivalence ratio and unburned mixture temperature and pressure over a wide range of operating conditions, namely [Formula: see text], [Formula: see text] and [Formula: see text]. The purpose is to provide simple and workable expressions for modeling the laminar flame speed of practical fuels used in spark-ignition engines. Pure compounds, such as methane and propane and binary mixtures of methane/ethane and methane/propane, as well as more complex fuels including natural gas and gasoline, are considered. A comparison with available empirical correlations in the literature is also provided.

The Effect of Lewis Number on Instantaneous Flamelet Speed and Position Statistics in Counter-Flow Flames With Increasing Turbulence

2017 ◽  
Author(s):  
Sean D. Salusbury ◽  
Ehsan Abbasi-Atibeh ◽  
Jeffrey M. Bergthorson
Keyword(s):  
Flame Front ◽  
Turbulence Intensity ◽  
High Speed ◽  
Rayleigh Scattering ◽  
Turbulent Flame ◽  
Lewis Number ◽  
Turbulent Flames ◽  
Flame Speed ◽  
Laminar Flames ◽  
Counter Flow

Differential diffusion effects in premixed combustion are studied in a counter-flow flame experiment for fuel-lean flames of three fuels with different Lewis numbers: methane, propane, and hydrogen. Previous studies of stretched laminar flames show that a maximum reference flame speed is observed for mixtures with Le ≳ 1 at lower flame-stretch values than at extinction, while the reference flame speed for Le ≪ 1 increases until extinction occurs when the flame is constrained by the stagnation point. In this work, counter-flow flame experiments are performed for these same mixtures, building upon the laminar results by using variable high-blockage turbulence-generating plates to generate turbulence intensities from the near-laminar u′/SLo=1 to the maximum u′/SLo achievable for each mixture, on the order of u′/SLo=10. Local, instantaneous reference flamelet speeds within the turbulent flame are extracted from high-speed PIV measurements. Instantaneous flame front positions are measured by Rayleigh scattering. The probability-density functions (PDFs) of instantaneous reference flamelet speeds for the Le ≳ 1 mixtures illustrate that the flamelet speeds are increasing with increasing turbulence intensity. However, at the highest turbulence intensities measured in these experiments, the probability seems to drop off at a velocity that matches experimentally-measured maximum reference flame speeds in previous work. In contrast, in the Le ≪ 1 turbulent flames, the most-probable instantaneous reference flamelet speed increases with increasing turbulence intensity and can, significantly, exceed the maximum reference flame speed measured in counter-flow laminar flames at extinction, with the PDF remaining near symmetric for the highest turbulence intensities. These results are reinforced by instantaneous flame position measurements. Flame-front location PDFs show the most probable flame location is linked both to the bulk flow velocity and to the instantaneous velocity PDFs. Furthermore, hydrogen flame-location PDFs are recognizably skewed upstream as u′/SLo increases, indicating a tendency for the Le ≪ 1 flame brush to propagate farther into the unburned reactants against a steepening average velocity gradient.

Numerical Study on the Effect of Real Syngas Compositions on Ignition Delay Times and Laminar Flame Speeds at Gas Turbine Conditions

2013 ◽  
Author(s):  
Olivier Mathieu ◽  
Eric L. Petersen ◽  
Alexander Heufer ◽  
Nicola Donohoe ◽  
Wayne Metcalfe ◽  
...  
Keyword(s):  
Ignition Delay ◽  
Delay Time ◽  
Gas Turbines ◽  
Ignition Delay Time ◽  
Laminar Flame ◽  
Numerical Study ◽  
Fuel Mixture ◽  
Flame Speed ◽  
Operating Conditions ◽  
Combustion Properties

Depending on the feedstock and the production method, the composition of syngas can include (in addition to H2 and CO) small hydrocarbons, diluents (CO2, water, and N2), and impurities (H2S, NH3, NOx, etc.). Despite this fact, most of the studies on syngas combustion do not include hydrocarbons or impurities and in some cases not even diluents in the fuel mixture composition. Hence, studies with realistic syngas composition are necessary to help designing gas turbines. The aim of this work was to investigate numerically the effect of the variation in the syngas composition on some fundamental combustion properties of premixed systems such as laminar flame speed and ignition delay time at realistic engine operating conditions. Several pressures, temperatures, and equivalence ratios were investigated. To perform this parametric study, a state-of-the-art C0-C5 detailed kinetics mechanism was used. Results of this study showed that the addition of hydrocarbons generally reduces the reactivity of the mixture (longer ignition delay time, slower flame speed) due to chemical kinetic effects. The amplitude of this effect is however dependent on the nature and concentration of the hydrocarbon as well as the initial condition (pressure, temperature, and equivalence ratio).

Laminar Flame Speed Measurements and Modeling of Pure Alkanes and Alkane Blends at Elevated Pressures

2011 ◽  
Vol 133 (9) ◽  
Author(s):  
William Lowry ◽  
Jaap de Vries ◽  
Michael Krejci ◽  
Eric Petersen ◽  
Zeynep Serinyel ◽  
...  
Keyword(s):  
High Pressure ◽  
Natural Gas ◽  
Gas Turbines ◽  
Laminar Flame ◽  
Flame Speed ◽  
Published Data ◽  
Laminar Flame Speed ◽  
Binary Blends ◽  
Elevated Pressures ◽  
True Value

Alkanes such as methane, ethane, and propane make up a large portion of most natural gas fuels. Natural gas is the primary fuel used in industrial gas turbines for power generation. Because of this, a fundamental understanding of the physical characteristics such as the laminar flame speed is necessary. Most importantly, this information is needed at elevated pressures to have the most relevance to the gas turbine industry for engine design. This study includes experiments performed at elevated pressures, up to 10 atm initial pressure, and investigates the fuels in a pure form as well as in binary blends. Flame speed modeling was done using an improved version of the kinetics model that the authors have been developing over the past few years. Modeling was performed for a wide range of conditions, including elevated pressures. Experimental conditions include pure methane, pure ethane, 80/20 mixtures of methane/ethane, and 60/40 mixtures of methane/ethane at initial pressures of 1 atm, 5 atm, and 10 atm. Also included in this study are pure propane and 80/20 methane/propane mixtures at 1 atm and 5 atm. The laminar flame speed and Markstein length measurements were obtained from a high-pressure flame speed facility using a constant-volume vessel. The facility includes optical access, a high-speed camera, a schlieren optical setup, a mixing manifold, and an isolated control room. The experiments were performed at room temperature, and the resulting images were analyzed using linear regression. The experimental and modeling results are presented and compared with previously published data. The data herein agree well with the published data. In addition, a hybrid correlation was created to perform a rigorous uncertainty analysis. This correlation gives the total uncertainty of the experiment with respect to the true value rather than reporting the standard deviation of a repeated experiment. Included in the data set are high-pressure results at conditions where in many cases for the single-component fuels few data existed and for the binary blends no data existed prior to this study. Overall, the agreement between the model and data is excellent.

Fuel Variation Effects in Propagation and Stabilization of Turbulent Counter-Flow Premixed Flames

2018 ◽  
Author(s):  
Ehsan Abbasi-Atibeh ◽  
Sandeep Jella ◽  
Jeffrey M. Bergthorson
Keyword(s):  
High Speed ◽  
Laminar Flame ◽  
Turbulent Flame ◽  
Mass Diffusion ◽  
Flame Stabilization ◽  
Turbulent Flames ◽  
Flame Speed ◽  
Flame Surface ◽  
Differential Diffusion ◽  
Turbulent Flame Speed

Sensitivity to stretch and differential diffusion of chemical species are known to influence premixed flame propagation, even in the turbulent environment where mass diffusion can be greatly enhanced. In this context, it is convenient to characterize flames by their Lewis number (Le), a ratio of thermal-to-mass diffusion. The work reported in this paper describes a study of flame stabilization characteristics when the Le is varied. The test data is comprised of Le ≪ 1 (Hydrogen), Le ≈ 1 (Methane), and Le > 1 (Propane) flames stabilized at various turbulence levels. The experiments were carried out in a Hot exhaust Opposed-flow Turbulent Flame Rig (HOTFR), which consists of two axially-opposed, symmetric turbulent round jets. The stagnation plane between the two jets allows the aerodynamic stabilization of a flame, and clearly identifies fuel influences on turbulent flames. Furthermore, high-speed Particle Image Velocimetry (PIV), using oil droplet seeding, allowed simultaneous recordings of velocity (mean and rms) and flame surface position. These experiments, along with data processing tools developed through this study, illustrated that in the mixtures with Le ≪ 1, turbulent flame speed increases considerably compared to the laminar flame speed due to differential diffusion effects, where higher burning rates compensate for the steepening average velocity gradient, and keeps these flames almost stationary as bulk flow velocity increases. These experiments are suitable for validating the ability of turbulent combustion models to predict lifted, aerodynamically-stabilized flames. In the final part of this paper, we model the three fuels at two turbulence intensities using the FGM model in a RANS context. Computations reveal that the qualitative flame stabilization trends reproduce the effects of turbulence intensity, however, more accurate predictions are required to capture the influences of fuel variations and differential diffusion.

Boundary Layer Flashback Prediction for Turbulent Premixed Jet Flames: Comparison of Two Models

2019 ◽  
Author(s):  
Alireza Kalantari ◽  
Nicolas Auwaijan ◽  
Vincent McDonell
Keyword(s):  
Boundary Layer ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Turbulent Flame ◽  
Flame Speed ◽  
Operating Conditions ◽  
Pollutant Emissions ◽  
Jet Flames ◽  
Turbulent Flame Speed ◽  
Turbulent Premixed

Abstract Lean-premixed combustion is commonly used in gas turbines to achieve low pollutant emissions, in particular nitrogen oxides. But use of hydrogen-rich fuels in premixed systems can potentially lead to flashback. Adding significant amounts of hydrogen to fuel mixtures substantially impacts the operating range of the combustor. Hence, to incorporate high hydrogen content fuels into gas turbine power generation systems, flashback limits need to be determined at relevant conditions. The present work compares two boundary layer flashback prediction methods developed for turbulent premixed jet flames. The Damköhler model was developed at University of California Irvine (UCI) and evaluated against flashback data from literature including actual engines. The second model was developed at Paul Scherrer Institut (PSI) using data obtained at gas turbine premixer conditions and is based on turbulent flame speed. Despite different overall approaches used, both models characterize flashback in terms of similar parameters. The Damköhler model takes into account the effect of thermal coupling and predicts flashback limits within a reasonable range. But the turbulent flame speed model provides a good agreement for a cooled burner, but shows less agreement for uncooled burner conditions. The impact of hydrogen addition (0 to 100% by volume) to methane or carbon monoxide is also investigated at different operating conditions and flashback prediction trends are consistent with the existing data at atmospheric pressure.

Ignition Delay Time and Laminar Flame Speed Calculations for Natural Gas/Hydrogen Blends at Elevated Pressures

2012 ◽  
Author(s):  
Marissa Brower ◽  
Eric Petersen ◽  
Wayne Metcalfe ◽  
Henry J. Curran ◽  
Marc Füri ◽  
...  
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Chemical Kinetics ◽  
Ignition Delay ◽  
Ignition Delay Time ◽  
Laminar Flame ◽  
Turbulent Flame ◽  
Flame Speed ◽  
Laminar Flame Speed ◽  
Hydrogen Addition

Applications of natural gas and hydrogen co-firing have received increased attention in the gas turbine market, which aims at higher flexibility due to concerns over the availability of fuels. While much work has been done in the development of a fuels database and corresponding chemical kinetics mechanism for natural gas mixtures, there are nonetheless few if any data for mixtures with high levels of hydrogen at conditions of interest to gas turbines. The focus of the present paper is on gas turbine engines with primary and secondary reaction zones as represented in the Alstom and Rolls Royce product portfolio. The present effort includes a parametric study, a gas turbine model study, and turbulent flame speed predictions. Using a highly optimized chemical kinetics mechanism, ignition delay times and laminar burning velocities were calculated for fuels from pure methane to pure hydrogen and with natural gas/hydrogen mixtures. A wide range of engine-relevant conditions were studied: pressures from 1 to 30 atm, flame temperatures from 1600 to 2200 K, primary combustor inlet temperature from 300 to 900 K, and secondary combustor inlet temperatures from 900 to 1400 K. Hydrogen addition was found to increase the reactivity of hydrocarbon fuels at all conditions by increasing the laminar flame speed and decreasing the ignition delay time. Predictions of turbulent flame speeds from the laminar flame speeds show that hydrogen addition affects the reactivity more when turbulence is considered. This combined effort of industrial and university partners brings together the know-how of applied, as well as experimental and theoretical disciplines.

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