Development of Plasma Spray Coatings Using Linz-Donawitz (LD) Slag Particles

Author(s):  
Pravat Ranjan Pati ◽  
Alok Satapathy

LD slag (LDS) is a major solid waste generated in huge quantities during steel making. It comes from slag formers such as burned lime/dolomite and from oxidising of silica, iron etc., while refining the iron into steel in the LD furnace. This work aims at utilization of waste LDS to develop surface coatings by plasma spraying technique. This technology has the advantage of being able to process various low-grade ore minerals to obtain value-added products and also to deposit materials, generating near homogeneous coatings with the desired microstructure. Coatings prepared for this investigation are characterized in terms of their thickness, hardness, adhesion strength and porosity. Coating deposition efficiency is calculated in order to assess the coatability of LDS and XRD is carried out in order to ascertain the various phases present in the coating. Premixing of TiO2 powder with LDS is found to substantially improve the interfacial adhesion. It is also found that the operating power levels of the plasma torch affect the adhesion strength, coating deposition efficiency and mean thickness of the coatings. This work reveals that LD slag is eminently coatable and can be gainfully used as a potential cost-effective material for deposition of plasma spray coatings on metallic substrates.

Author(s):  
L. Dekhtyar ◽  
A. Kleyman ◽  
V. Andreychuk ◽  
S. Berman

Abstract Residual stresses exert profound influence on the longevity of parts with thermal spray coatings. The distribution and value of the residual stresses depend on method of coating deposition, composition of the applied material, parameters of thermal spraying and methods of post-treatment. Therefore, the study of the influence of the various technological factors on the residual stresses in the plasma spray coatings is very important. Due to heterogeneity of the coating, residual stresses can be determined only by the experimentation by using new methods which take into consideration real values of elastic characteristics and density of elementary layers. Methods and formulas for the calculations of the residual stresses in coatings deposited on bars, rings, discs, cylinders are presented. Experimental results for the various thermal spray coatings are also shown. These results can be used for the optimization of coating deposition and would supplement the existing database.


2007 ◽  
Vol 534-536 ◽  
pp. 89-92 ◽  
Author(s):  
Hyun Kwang Seok ◽  
Yu Chan Kim ◽  
Frédéric Prima ◽  
Eric Fleury

This works deals with the deposition of Ti-Zr-Ni icosahedral quasicrystalline powders by low vacuum plasma spray technique and the performances of the resulting coating layers. The microstructure of the coatings, as analyzed by X-ray diffraction and TEM techniques, consisted of nanometer-sized W-Ti50Zr35Ni15 1/1 cubic approximant and TiZrNi Laves phases as well as a low volume fraction of submicrometer-sized ZrO2 phase. The absence of the icosahedral phase in the coating layers was explained by the loss of Ti during plasma spraying. The shift in the composition and the presence of the ZrO2 phase within the coating layers are believed to be responsible for the reduced microhardness and corrosion performances evaluated by electrochemical tests in a Hanks’ Balance Salt Solution at 37oC.


2011 ◽  
Vol 20 (4) ◽  
pp. 967-973 ◽  
Author(s):  
Elliot M. Cotler ◽  
Dianying Chen ◽  
Ronald J. Molz

Author(s):  
A.Ph. Ilyuschenko ◽  
N.I. Shipica ◽  
P.A. Vityaz ◽  
A.A. Yerstak ◽  
A.Y. Beliaev

Abstract This paper presents the results of a study on the wear resistance of plasma spray coatings made from Cr2O3-TiO2-CaF2 powders. The composite powders used were produced by self-propagating high temperature synthesis. They were then applied under various conditions in order to optimize the material system, spray process, and application procedures. Based on the results of microstructural examination and wear testing, the thermally sprayed composite coatings have excellent wear resistance, good adhesion, and are self-lubricating at high temperatures.


2011 ◽  
Vol 328-330 ◽  
pp. 853-856 ◽  
Author(s):  
Sun Hui Yao ◽  
Yan Liang Su ◽  
Wen Xian Kao

This study aimed to understand the effect of TiO2 content on the thermal shock performance of Al2O3/TiO2 air plasma spray coatings. Three kinds of commercial feedstock powders were used, i.e. Al2O3, Al2O3-13wt%TiO2 and Al2O3-40wt%TiO2. The resulting coatings were studied in terms of micro Vickers hardness test, XRD, SEM and thermal shock test. The last was conducted using a water quenching method. The results showed that both the coating hardness and thermal shock performance decreased with the TiO2 content.


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